A Textbook Of Physical Chemistry Volume 1
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A Textbook Of Physical Chemistry Volume 1
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Author : Mandeep Dalal
language : en
Publisher: Dalal Institute
Release Date : 2018-01-01
A Textbook Of Physical Chemistry Volume 1 written by Mandeep Dalal and has been published by Dalal Institute this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-01-01 with Science categories.
An advanced-level textbook of physical chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Physical Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Quantum Mechanics – I: Postulates of quantum mechanics; Derivation of Schrodinger wave equation; Max-Born interpretation of wave functions; The Heisenberg’s uncertainty principle; Quantum mechanical operators and their commutation relations; Hermitian operators (elementary ideas, quantum mechanical operator for linear momentum, angular momentum and energy as Hermition operator); The average value of the square of Hermitian operators; Commuting operators and uncertainty principle(x & p; E & t); Schrodinger wave equation for a particle in one dimensional box; Evaluation of average position, average momentum and determination of uncertainty in position and momentum and hence Heisenberg’s uncertainty principle; Pictorial representation of the wave equation of a particle in one dimensional box and its influence on the kinetic energy of the particle in each successive quantum level; Lowest energy of the particle. Chapter 2. Thermodynamics – I: Brief resume of first and second Law of thermodynamics; Entropy changes in reversible and irreversible processes; Variation of entropy with temperature, pressure and volume; Entropy concept as a measure of unavailable energy and criteria for the spontaneity of reaction; Free energy, enthalpy functions and their significance, criteria for spontaneity of a process; Partial molar quantities (free energy, volume, heat concept); Gibb’s-Duhem equation. Chapter 3. Chemical Dynamics – I: Effect of temperature on reaction rates; Rate law for opposing reactions of Ist order and IInd order; Rate law for consecutive & parallel reactions of Ist order reactions; Collision theory of reaction rates and its limitations; Steric factor; Activated complex theory; Ionic reactions: single and double sphere models; Influence of solvent and ionic strength; The comparison of collision and activated complex theory. Chapter 4. Electrochemistry – I: Ion-Ion Interactions: The Debye-Huckel theory of ion- ion interactions; Potential and excess charge density as a function of distance from the central ion; Debye Huckel reciprocal length; Ionic cloud and its contribution to the total potential; Debye - Huckel limiting law of activity coefficients and its limitations; Ion-size effect on potential; Ion-size parameter and the theoretical mean-activity coefficient in the case of ionic clouds with finite-sized ions; Debye - Huckel-Onsager treatment for aqueous solutions and its limitations; Debye-Huckel-Onsager theory for non-aqueous solutions; The solvent effect on the mobality at infinite dilution; Equivalent conductivity (Λ) vs. concentration c 1/2 as a function of the solvent; Effect of ion association upon conductivity (Debye- Huckel - Bjerrum equation). Chapter 5. Quantum Mechanics – II: Schrodinger wave equation for a particle in a three dimensional box; The concept of degeneracy among energy levels for a particle in three dimensional box; Schrodinger wave equation for a linear harmonic oscillator & its solution by polynomial method; Zero point energy of a particle possessing harmonic motion and its consequence; Schrodinger wave equation for three dimensional Rigid rotator; Energy of rigid rotator; Space quantization; Schrodinger wave equation for hydrogen atom, separation of variable in polar spherical coordinates and its solution; Principle, azimuthal and magnetic quantum numbers and the magnitude of their values; Probability distribution function; Radial distribution function; Shape of atomic orbitals (s,p & d). Chapter 6. Thermodynamics – II: Classius-Clayperon equation; Law of mass action and its thermodynamic derivation; Third law of thermodynamics (Nernest heat theorem, determination of absolute entropy, unattainability of absolute zero) and its limitation; Phase diagram for two completely miscible components systems; Eutectic systems, Calculation of eutectic point; Systems forming solid compounds Ax By with congruent and incongruent melting points; Phase diagram and thermodynamic treatment of solid solutions. Chapter 7. Chemical Dynamics – II: Chain reactions: hydrogen-bromine reaction, pyrolysis of acetaldehyde, decomposition of ethane; Photochemical reactions (hydrogen - bromine & hydrogen -chlorine reactions); General treatment of chain reactions (ortho-para hydrogen conversion and hydrogen - bromine reactions); Apparent activation energy of chain reactions, Chain length; Rice-Herzfeld mechanism of organic molecules decomposition(acetaldehyde); Branching chain reactions and explosions ( H2-O2 reaction); Kinetics of (one intermediate) enzymatic reaction : Michaelis-Menton treatment; Evaluation of Michaelis 's constant for enzyme-substrate binding by Lineweaver-Burk plot and Eadie-Hofstae methods; Competitive and non-competitive inhibition. Chapter 8. Electrochemistry – II: Ion Transport in Solutions: Ionic movement under the influence of an electric field; Mobility of ions; Ionic drift velocity and its relation with current density; Einstein relation between the absolute mobility and diffusion coefficient; The Stokes- Einstein relation; The Nernst -Einstein equation; Walden’s rule; The Rate-process approach to ionic migration; The Rate process equation for equivalent conductivity; Total driving force for ionic transport, Nernst - Planck Flux equation; Ionic drift and diffusion potential; the Onsager phenomenological equations; The basic equation for the diffusion; Planck-Henderson equation for the diffusion potential.
Textbook Of Physical Chemistry
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Author :
language : en
Publisher:
Release Date : 2014
Textbook Of Physical Chemistry written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014 with Chemistry, Physical and theoretical categories.
A Textbook Of Physical Chemistry
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Author : K L Kapoor
language : en
Publisher: Macmillan
Release Date : 1999
A Textbook Of Physical Chemistry written by K L Kapoor and has been published by Macmillan this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999 with Chemistry, Physical and theoretical categories.
This is the first of four volumes that provide a thorough understanding of the principles and basic concepts of physical chemistry. Emphasis is placed on the application of the principles. This volume deals with states of matter and Ions in solution.
A Textbook Of Physical Chemistry
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Author : A. S. Negi
language : en
Publisher: New Age International
Release Date : 1985
A Textbook Of Physical Chemistry written by A. S. Negi and has been published by New Age International this book supported file pdf, txt, epub, kindle and other format this book has been release on 1985 with Chemistry, Physical and theoretical categories.
Written primarily to meet the requirements of students at the undergraduate level, this book aims for a self-learning approach. The fundamentals of physical chemistry have been explained with illustrations, diagrams, tables, experimental techniques and solved problems.
A Textbook Of Physical Chemistry Vol 1 4 E
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Author : Kl Kapoor
language : en
Publisher:
Release Date : 2011-02-01
A Textbook Of Physical Chemistry Vol 1 4 E written by Kl Kapoor and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-02-01 with categories.
A thorough understanding of the principles and basic concepts of physical chemistry is essential for a good grasp of the subject. This book is the sixth of the earlier five volume series, which provides an extensive coverage of the topics discussed focusi
Physical Chemistry Volume 1 Thermodynamics And Kinetics
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Author : Peter Atkins
language : en
Publisher: W. H. Freeman
Release Date : 2010-02-26
Physical Chemistry Volume 1 Thermodynamics And Kinetics written by Peter Atkins and has been published by W. H. Freeman this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010-02-26 with Science categories.
With its modern emphasis on the molecular view of physical chemistry, its wealth of contemporary applications, vivid full-color presentation, and dynamic new media tools, the thoroughly revised new edition is again the most modern, most effective full-length textbook available for the physical chemistry classroom. Volume 1 of Physical Chemistry, Ninth Edition, contains the new edition’s new Fundamentals chapters (Chapter 0), plus coverage of thermodynamics (Chapters 1-6) and kinetics (Chapters 20-23)
A Textbook Of Physical Chemistry
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Author : Arthur Adamson
language : en
Publisher: Elsevier
Release Date : 2012-12-02
A Textbook Of Physical Chemistry written by Arthur Adamson and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
A Textbook of Physical Chemistry, Second Edition serves as an introductory text to physical chemistry. Topics covered range from wave mechanics and chemical bonding to molecular spectroscopy and photochemistry; ideal and nonideal gases; the three laws of thermodynamics; thermochemistry; and solutions of nonelectrolytes. The kinetics of gas-phase reactions; colloids and macromolecules; and nuclear chemistry and radiochemistry are also discussed. This edition is comprised of 22 chapters; the first of which introduces the reader to the behavior of ideal and nonideal gases, with particular emphasis on the van der Waals equation. The discussion then turns to the kinetic molecular theory of gases and the application of the Boltzmann principle to the treatment of molar polarization; dipole and magnetic moments; the phenomenology of light absorption; and classical and statistical thermodynamics. The chapters that follow focus on the traditional sequence of chemical and phase equilibria, electrochemistry, and chemical kinetics in gas phase and solution phase. This book also considers wave mechanics and its applications; molecular spectroscopy and photochemistry; and the excited state, and then concludes with an analysis of crystal structure, colloid and polymer chemistry, and radio and nuclear chemistry. This reference material is intended primarily as an introductory text for students of physical chemistry.
A Textbook Of Physical Chemistry Volume 6
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Author : K L Kapoor
language : en
Publisher:
Release Date :
A Textbook Of Physical Chemistry Volume 6 written by K L Kapoor and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on with categories.
Atkins Physical Chemistry
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Author : Peter William Atkins
language : en
Publisher: Oxford University Press, USA
Release Date : 2002
Atkins Physical Chemistry written by Peter William Atkins and has been published by Oxford University Press, USA this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002 with Chemistry categories.
This major revision of the world's leading textbook of physical chemistry has maintained its tradition of accessibility but authority and has brought it thoroughly up to date. The new author team has introduced many innovations. There are new or rewritten chapters on the solid state, on molecular interactions, macromolecules, and electron transfer. Almost every chapter has at least one Box showing the relevance of the material to modern chemistry. All the chapters now conclude with a check list which includes definitions and key equations. The authors have paid special attention to the presentation of mathematical derivations and to the physical interpretation of equations. They have also ensured that the text is highly modular, so that it can be used in different sequences, either atoms first or thermodynamics first. The art program has been redrawn and extended, new Discussion questions have been added, and the Further Information sections have been recast to provide the necessary background in mathematics and physics. The text is fully geared to the web, with full media support. SUPPLEMENTS AND SUPPORT MATERIAL: 1. Web site featuring Living Graphs (about 150). Dynamic, interactive graphs that allow experimentation and hands-on learning. Web links to sources of data and other information, as referred to in the book. 2. Student's Solutions Manual containing worked solutions to half the end of chapter exercises and problems in the parenttext. 3. Instructor's Solutions Manual, FREE to adopters of the parent text, containing worked solutions to the other half of the end of chapter exercises and problems in the parent text. Contains a CD-ROM with all the illustrations from the text, for use in presentations. 4. MathCad/Mathematica supplement book with CD-ROM to take all living graphs further. NEW TO THIS EDITION: DT New co-author Julio de Paula, a biophysical chemist, strengthens the text's coverage of biologicalapplications. DT Margin notes provide help with mathematics just where it is needed. DT Boxes added to every chapter to cover biological applications, environmental, materials science and chemical engineering. Each box has two problems, and suggestions for further reading. DT Important equations and definitions added to the 'key concepts' section of every chapter. DT Microprojects used to be separate sections at end of every Part. These (most of them) have been integrated into the appropriate chapter's end-of-chapter exercises. DT More help with the mathematical development of derivations: marginal notes are provided, many derivations now include more steps (justifications), the section on mathematical techniques in Further Information sections has been rewritten, as has the Further Information section on concepts of physics. DT Fully integrated media support. The new feature of Living Graphs are flagged by an icon in the textbook, and marginal notes refer the reader to the weblinks to be found on the book's free web site. DT The chapters are modular so that they may be read in different orders for different courses. Road Maps are provided that suggest different routes through the text for the following types of course organizations: (a) thermodynamics first, (b) atoms first (quantum mechanics first). DT There is a separate section in of end-of-chapter exercises specifically for applications. DT End-of-chapter problems for which solutions are provided in the Student's Solutions Manual are now indicated by colour. MODERNIZATION DT More coverage of modern topics throughout the text. Some examples, by section of the book: PART 1: Illustrations of partial derivatives added Added Boxes, more practical and more biological applications PART 2: Chapter 14 includes computational chemistry Enhancements to quantum mechanics coverage: addition of materials science in Chapters 22 and 23 More modern spectroscopy, more computational chemistry Chapter 21: new chapter on molecular interactions Chapter 22 on macromolecules emphasizes polymers and biological polymers PART 3: Organized to make selective use easier (made more modular) Chapter 29: more modern treatment of electron transfer theory in solutions, biological systems, and solid state For a complete list of changes to the book since the last edition, see the web site at www.oup.com/pchem7
A Textbook Of Physical Chemistry
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Author : John Newton Friend
language : en
Publisher:
Release Date : 1932
A Textbook Of Physical Chemistry written by John Newton Friend and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1932 with Chemistry, Physical and theoretical categories.