Activation Of Alkenes And Alkynes


Activation Of Alkenes And Alkynes
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Activation Of Alkenes And Alkynes


Activation Of Alkenes And Alkynes
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Author : M.M. Taqui Khan
language : en
Publisher: Elsevier
Release Date : 2012-12-02

Activation Of Alkenes And Alkynes written by M.M. Taqui Khan and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.


Homogeneous Catalysis by Metal Complexes, Volume II: Activation of Alkenes and Alkynes reviews and systematizes the chemistry of metal ion activation of alkenes and alkynes. The book presents the migration of ? bonds; the oxo reaction; and the hydrosilation of alkenes and alkynes. The text also covers topics on the oxidation of alkenes and alkynes, as well as the multiple insertion reactions of alkenes and alkynes.



Activation Of Alkenes And Alkynes


Activation Of Alkenes And Alkynes
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Author : M.M. Taqui Khan
language : en
Publisher: Academic Press
Release Date : 1974-01-28

Activation Of Alkenes And Alkynes written by M.M. Taqui Khan and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1974-01-28 with Science categories.


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Alkynes In Cycloadditions


Alkynes In Cycloadditions
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Author : Irina A. Maretina
language : en
Publisher: John Wiley & Sons
Release Date : 2013-10-08

Alkynes In Cycloadditions written by Irina A. Maretina and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-08 with Science categories.


Acetylene systems present a new route to cyclic compounds as an alternative to more traditional methods employed in classical organic chemistry. The synthesis of cyclic structures based on acetylene systems has important applications in the formation of nanostructures, naturally occurring compounds and chemosensory materials for the design of nonlinear optics, electronic and photonic devices. Alkynes in Cycloadditions presents a modern review of regioselective synthesis of aromatic and non-aromatic carbocyclic and heterocyclic ring systems based primarily on [2+2+2] and [4+2] cycloadditions, and other reactions of acetylenic units including enediynes and enyne-allenes. Topics covered include: New strategies for the formation of aromatic and polynuclear hydrocarbons based on (Z)-hex-3-en-1,5-diyne and (Z)-hepta-1,2,4-triene-6-yne blocks. One-step synthesis of benzene derivatives, β-substituted naphthalenes and acenes by the cycloaromatization of enediynes and enyne-allenes by Bergman, Myers-Saito and Shmittel. Mechanisms of cycloaromatization resulting in the formation of fulvene and indene systems. Heterocyclization involving enyne-carbodiimides. New achievements in classical cycloaddition reactions such as the Diels-Alder condensation with acetylenic dienophiles and [2+2] cycloadditions with acetylene components Alkynes in Cycloadditions presents a comprehensive summary of the literature on methods for the synthesis of ring systems from acetylenes for academic researchers working in the fields of organic synthesis, physical organic chemistry, organometallic chemistry, catalysis, materials science, nanomaterials and biochemistry.



C H Activation For Asymmetric Synthesis


C H Activation For Asymmetric Synthesis
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Author : Françoise Colobert
language : en
Publisher: John Wiley & Sons
Release Date : 2019-08-29

C H Activation For Asymmetric Synthesis written by Françoise Colobert and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-08-29 with Science categories.


Provides, in one handbook, comprehensive coverage of one of the hottest topics in stereoselective chemistry Written by leading international authors in the field, this book introduces readers to C-H activation in asymmetric synthesis along with all of its facets. It presents stereoselective C-H functionalization with a broad coverage, from outer-sphere to inner-sphere C-H bond activation, and from the control of olefin geometry to the induction of point, planar and axial chirality. Moreover, methods wherein asymmetry is introduced either during the C-H activation or in a different elementary step are discussed. Presented in two parts?asymmetric activation of C(sp3)-H bonds and stereoselective synthesis implying activation of C(sp2)-H bonds?CH-Activation for Asymmetric Synthesis showcases the diversity of stereogenic elements, which can now be constructed by C-H activation methods. Chapters in Part 1 cover: C(sp3)-H bond insertion by metal carbenoids and nitrenoids; stereoselective C-C bond and C-N bond forming reactions through C(sp3)?H bond insertion of metal nitrenoids; enantioselective intra- and intermolecular couplings; and more. Part 2 looks at: C-H activation involved in stereodiscriminant step; planar chirality; diastereoselective formation of alkenes through C(sp2)?H bond activation; amongst other methods. -Covers one of the most rapidly developing fields in organic synthesis and catalysis -Clearly structured in two parts (activation of sp3- and activation of sp2-H bonds) -Edited by two leading experts in C-H activation in asymmetric synthesis CH-Activation for Asymmetric Synthesis will be of high interest to chemists in academia, as well as those in the pharmaceutical and agrochemical industry.



Alkylation And C N Bond Activation Are Catalyzed By Alcohols


Alkylation And C N Bond Activation Are Catalyzed By Alcohols
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Author : Kishore Sinnu
language : en
Publisher: Self Employed
Release Date : 2023-10-26

Alkylation And C N Bond Activation Are Catalyzed By Alcohols written by Kishore Sinnu and has been published by Self Employed this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-10-26 with Business & Economics categories.


In the field of organic chemistry, the use of alcohols as catalysts for C-N bond activation and alkylation reactions has garnered significant attention in recent years. Jagannath Rana, a renowned chemist, has contributed greatly to this area of research through his groundbreaking studies. Alcohols, a widely available and environmentally friendly resource, have proven to be effective catalysts for a variety of chemical reactions, including C-N bond activation and alkylation. This type of catalysis can be achieved with either homogeneous or heterogeneous catalysis. Homogeneous catalysis, in which the alcohol is completely dissolved in the reaction mixture, is widely used in laboratory-scale reactions. Heterogeneous catalysis, on the other hand, involves the use of a solid-supported alcohol catalyst, which can be recycled and reused. The activation of C-N bonds using alcohols as catalysts is a highly efficient and selective process. The reaction occurs by nucleophilic attack of the amide or other nitrogen-containing compound on the activated alcohol. The resulting intermediate can undergo alkylation by a variety of electrophiles, including alkyl halides, alkenes, and alkynes. The use of alcohols as catalysts for C-N bond activation and alkylation reactions has several advantages over traditional methods. First, alcohols are abundant and inexpensive, making them an attractive alternative to more costly catalysts. Additionally, alcohols are non-toxic and can be used in environmentally friendly, sustainable chemistry practices. Rana's research has focused on the use of metal catalysis for C-N bond activation and alkylation reactions using alcohols as catalysts. In particular, he has studied the use of palladium catalysts in these reactions, as palladium is a widely available and inexpensive metal with excellent catalytic activity. Rana's work has demonstrated that palladium-catalyzed C-N bond activation and alkylation using alcohols as catalysts can be highly selective, producing the desired products with high yields and minimal waste. Overall, the use of alcohols as catalysts for C-N bond activation and alkylation reactions is a promising area of research in the field of organic chemistry. Rana's contributions have advanced our understanding of this process and opened up new avenues for the development of sustainable, environmentally friendly chemical processes.



C H Bond Activation And Catalytic Functionalization Ii


C H Bond Activation And Catalytic Functionalization Ii
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Author : Pierre H. Dixneuf
language : en
Publisher: Springer
Release Date : 2016-03-10

C H Bond Activation And Catalytic Functionalization Ii written by Pierre H. Dixneuf and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-03-10 with Science categories.


The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.



C H Bond Activation And Catalytic Functionalization I


C H Bond Activation And Catalytic Functionalization I
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Author : Pierre H. Dixneuf
language : en
Publisher: Springer
Release Date : 2015-12-18

C H Bond Activation And Catalytic Functionalization I written by Pierre H. Dixneuf and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-12-18 with Science categories.


The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.



Silver Catalysis In Organic Synthesis


Silver Catalysis In Organic Synthesis
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Author : Chao-Jun Li
language : en
Publisher: John Wiley & Sons
Release Date : 2018-12-07

Silver Catalysis In Organic Synthesis written by Chao-Jun Li and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-12-07 with Science categories.


Covers all the aspects of the recent achievements in silver catalyzed reactions Silver catalysis has emerged as a powerful tool in the field of organic synthesis. This comprehensive book systematically explores the unique performance of silver catalysis, introducing all the recent progress of silver catalysis in organic synthesis. It clearly emphasizes the unique features of silver catalysis and provides the reaction mechanism involved. This two-volume book also provides vivid schematics and tables throughout to enhance the accessibility to the relevant theory and mechanisms. Silver Catalysis in Organic Synthesis begins with an introduction to Silver Chemistry before moving on to chapters covering: Silver-Catalyzed Cycloaddition Reactions; Silver-Catalyzed Cyclizations; Silver-Mediated Radical Reactions; Silver-Mediated Fluorination, Perfluoroalkylation and Trifluoromethylthiolation Reactions; Coupling Reactions and C-H Functionalization; Silver-Catalyzed CO2 Incorporation; Silver-Catalyzed Carbene, Nitrene, and Silylene Transfer Reactions; Asymmetric Silver-Catalyzed Reactions; Silver-Catalyzed Reduction and Oxidation of Aldehydes and Their Derivatives; Silver Complexes in Organic Transformations; and Silver Nanoparticles in Organic Transformations. -Covers recently developed organic reactions catalyzed by silver, along with their reaction mechanism -Introduces many new reactions and mechanisms related to silver catalysis -Offers professionals and newcomers in the related fields a survey of new advances in silver catalysis in organic synthesis Silver Catalysis in Organic Synthesis will appeal to a wide readership including chemists, biochemists, pharmaceutical scientists, biomedical researchers, agriculture scientists, and graduate students in the related fields.



Activation Of Small Inorganic Molecules


Activation Of Small Inorganic Molecules
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Author : M.M. Taqui Khan
language : en
Publisher: Elsevier
Release Date : 2012-12-02

Activation Of Small Inorganic Molecules written by M.M. Taqui Khan and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.


Homogeneous Catalysis by Metal Complexes, Volume I: Activation of Small Inorganic Molecules reviews and systematizes the chemistry of the metal ion activation of the small diatomic molecules. The book discusses the activation of molecular hydrogen, molecular oxygen, molecular nitrogen, carbon monoxide, and nitric oxide.



Organometallic Chemistry And Catalysis


Organometallic Chemistry And Catalysis
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Author : Didier Astruc
language : en
Publisher: Springer Science & Business Media
Release Date : 2007-08-02

Organometallic Chemistry And Catalysis written by Didier Astruc and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-08-02 with Science categories.


This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.