Advances In Metal Carbene Chemistry
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Advances In Metal Carbene Chemistry
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Author : U. Schubert
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Advances In Metal Carbene Chemistry written by U. Schubert and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
There are only few topics in organometallic chemistry, which have stimulated research activities in as many areas, as transition-metal carbene (alkylidene) complexes. About 25 years after the first planned synthesis of a carbene complex in E.O. Fischer's laboratory in Munich the NATO Advanced Research Workshop on Transition-Metal Carbene Complexes was the first meeting which,brought together scientists from different disciplines to discuss inorganic, organic, theoretical structural catalysis-related aspects of metal carbene chemistry. The 70th birthday of Professor E.O. Fischer was a good occasion for this enterprise. The organizers of the meeting (K.D. Dotz, Marburg; F.R. KreiBl, Munchen; U. Schubert, Wurzburg) were encouraged by the fact that most of the leading scientists in this area were able to participate in the workshop. The very high standard of the contributions is reflected in this book, which contains papers from the majority of the participants. The Proceedings show the state of the art in metal carbene chemistry and will hopefully be a landmark in the development of this area of chemistry. Generous financial support for the workshop and for the preparation of this book was provided by the Scientific Affairs Division of NATO and some companies. The organizers also acknowledge the efforts of the staff of the Bildungs zentrum der Hans-Seidel-Stiftung in Wild bad Kreuth for creating a pleasant and stimulating atmosphere during the conference.
Advances In Metal Carbene Chemistry
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Author : U. Schubert
language : en
Publisher:
Release Date : 1989-04-30
Advances In Metal Carbene Chemistry written by U. Schubert and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989-04-30 with categories.
Transition Metal Catalyzed Carbene Transformations
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Author : Jianbo Wang
language : en
Publisher: John Wiley & Sons
Release Date : 2022-05-16
Transition Metal Catalyzed Carbene Transformations written by Jianbo Wang and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-05-16 with Science categories.
Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer. Highlights the dynamic nature of the field of transition-metal-catalyzed carbene transformations Summarizes the catalytic radical approach for selective carbene cyclopropanation, high enantioselectivity in X-H insertions, and bio-inspired carbene transformations Introduces chiral N,N'-dioxide and chiral guanidine-based catalysts and different transformations with gold catalysis Discusses approaches in cycloaddition reactions with metal carbenes and polymerization with carbene transformations Outlines multicomponent reactions through gem-difunctionalization and transition-metal-catalyzed cross-coupling using carbene precursors Transition Metal-Catalyzed Carbene Transformations is essential reading for all chemists involved in organometallics, including organic and inorganic chemists, catalytic chemists, and chemists working in industry.
Metal Carbenes In Organic Synthesis
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Author : Florencio Zaragoza Dörwald
language : en
Publisher: John Wiley & Sons
Release Date : 2008-09-26
Metal Carbenes In Organic Synthesis written by Florencio Zaragoza Dörwald and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-09-26 with Science categories.
There are hardly more versatile compounds in organic synthesis than carbene complexes. The rapid development of new synthetic methods involving carbene complexes - stereoselective cyclopropanation, carbonyl olefination, olefin metathesis, etc. - reveals the value and high potential of these compounds. Their application ranges from the synthesis of fine chemicals to polymer production. This comprehensive, well structured handbook presents the fundamental principles and the recent advances in carbene complex chemistry. Arranged according to structure and reactivity, all relevant classes of carbene complexes, their generation, and application in organic synthesis are discussed in detail. Critically selected, up-to-date references and valuable experimental procedures await the reader. Every chemist searching for a concise introduction and reference work for carbene complex chemistry will welcome this practical guide. "...this concise presentation of all the aspects of the use of carbene complexes in synthesis will help provide the impetus for even more rapid developments in this field of research." R. H. Grubbs (Caltech)
Advances In Metal Organic Chemistry
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Author : Lanny S. Liebeskind
language : en
Publisher: Elsevier
Release Date : 2013-10-22
Advances In Metal Organic Chemistry written by Lanny S. Liebeskind and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Science categories.
Advances in Metal-Organic Chemistry: A Research Annual, Volume 2 presents the virtues of metal-oriented organic chemistry utilizing stoichiometric and catalytic reagents. This book discusses of value for the synthesis of generally useful organic structures. Organized into seven chapters, this volume begins with an overview of the synthetic applications of chromium tricarbonyl stabilized benzylic carbanions. This text then examines the application of organometallic complexes to stereoselective organic synthesis. Other chapters consider the carbine addition reaction that has been shown to be useful in many cases, but complications arise because of the inherently high reactivity of these species. This book discusses as well the most common substituted-arene complexes, particularly those of benzaldehyde and benzoic acid that are stable when prepared by indirect routes via acetals or esters. The final chapter deals with the efficient ring homologation methodology for cyclic alkenes. This book is a valuable resource for synthetic organic chemists and organometallic chemists.
Metal Carbenes In Organic Synthesis
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Author : K H Dtz
language : en
Publisher: Springer Science & Business Media
Release Date : 2004-09-21
Metal Carbenes In Organic Synthesis written by K H Dtz and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-09-21 with Science categories.
With contributions by numerous experts
Advances In Organometallic Chemistry
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Author :
language : en
Publisher: Elsevier
Release Date : 2024-07-25
Advances In Organometallic Chemistry written by and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-07-25 with Science categories.
Advances in Organometallic Chemistry, Volume 82, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. Chapters in this new release include Pd-catalysis: a useful tool in the field of polymer synthesis. Recent advances and applications, Modern Mechanistic Approaches for the Depolymerization of Commodity Plastics via Homogeneous Metal Catalysis, Functionalization of fullerenes by transition metal catalyzed cyclization reactions, and Synergistic Metal-Ligand Reactivity in Half-Sandwich Complexes of Fe, Co, and Ni for Bond Activation and Catalysis. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material
Advances In The Chemistry Of Group 10 Transition Metal Carbenes
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Author : Cody Robert Work
language : en
Publisher:
Release Date : 2022
Advances In The Chemistry Of Group 10 Transition Metal Carbenes written by Cody Robert Work and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022 with categories.
Advances In Carbene Chemistry
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Author : U.H. Brinker
language : en
Publisher: Elsevier
Release Date : 1998-07-02
Advances In Carbene Chemistry written by U.H. Brinker and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998-07-02 with Science categories.
Beginning as chemical curiosities, carbenes are now solidly established as reactive intermediates with fascinating and productive research areas of their own. Five decades of divalent carbon chemistry have provided us with a vast repertoire of new, unusual and surprising reactions. Some of those reactions, once classified as exotic, have become standard methods in organic synthesis. These highly reactive carbene species have been harnessed and put to work to achieve difficult synthetic tasks that other reactive intermediates cannot easily perform. The fruitful relationship between experiment and theory has pushed carbene chemistry further toward the direction of reaction control; that is, regio- and stereoselectivity in intra- and intermolecular addition and insertion reactions. The interplay between experiment and modern spectroscopy has led to the characterisation of many carbenes that are crucial to both an understanding and a further development of this field. Understanding of carbene chemistry has advanced dramatically, especially in the last decade, and new developments continue to emerge. Some of the recent exciting findings have been collected in the first volume of Advances in Carbene Chemistry. With this second volume, the series will continue to provide a periodic coverage of carbene chemistry in its broadest sense - leading into the next century.
Advances In Metal Organic Chemistry
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Author : Lanny S. Liebeskind
language : en
Publisher: JAI Press(NY)
Release Date : 1989
Advances In Metal Organic Chemistry written by Lanny S. Liebeskind and has been published by JAI Press(NY) this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989 with Science categories.
