Carbon Dioxide Reduction Via Homogeneous Catalytic Synthesis And Hydrogenation Of N N Dimethylformamide
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Carbon Dioxide Reduction Via Homogeneous Catalytic Synthesis And Hydrogenation Of N N Dimethylformamide
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Author : Serge Schreiner
language : en
Publisher:
Release Date : 1988
Carbon Dioxide Reduction Via Homogeneous Catalytic Synthesis And Hydrogenation Of N N Dimethylformamide written by Serge Schreiner and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with categories.
The previously reported catalytic reaction between CO2, H2, and (CH3)2NH to yield N, N-dimethylformamide (DMF) has been found to produce also trimethylamine (TMA) in the presence of several Ru, Os, Rh, Ir and Pt complexes. In separate experiments, the hydrogenation of DMF, catalyzed by the same or other complexes, also gave TMA. Thus, evidence is presented for the overall catalytic reduction of CO2 the the methyl group ( -CH3, incorporated in TMA). Keywords: Carbon dioxide, Hydrogenation, Homogeneous catalysis, N, N Dimethylformamide, Ethyl radicals.
Transformation Of Carbon Dioxide To Formic Acid And Methanol
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Author : Wan-Hui Wang
language : en
Publisher: Springer
Release Date : 2017-10-26
Transformation Of Carbon Dioxide To Formic Acid And Methanol written by Wan-Hui Wang and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-10-26 with Science categories.
This brief explains the principles and fundamentals of carbon dioxide utilization and highlights the transformation to fuels and value-added chemicals such as formic acid and methanol. It is divided into six chapters, including an introduction to the basics of CO2 utilization and transformation of CO2 to formic acid and methanol with homogeneous and heterogeneous catalysts, respectively. The brief will appeal to a wide readership of academic and industrial researchers focusing on homogeneous and heterogeneous catalysis, organometallic chemistry, green chemistry, energy conversion and storage.
Reversible Homogeneous Catalysis Of Carbon Dioxide Hydrogenation Reduction At Room Temperature And Low Pressures Mediated By Platinum O Diphosphine Cluster Complex In Solution
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Author : Serge Schreiner
language : en
Publisher:
Release Date : 1987
Reversible Homogeneous Catalysis Of Carbon Dioxide Hydrogenation Reduction At Room Temperature And Low Pressures Mediated By Platinum O Diphosphine Cluster Complex In Solution written by Serge Schreiner and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1987 with categories.
A platinum complex,?Pt2(u-PCP)3 (PCP = (C6H5)2PCH2P(C6H6)2, catalyzes the synthesis of N, N-dimehtylformamide (DMF) from CO2, H2 and (CH3)2NH in toluene solution at 25-100C and total pressures of 0.96-114 atm of the three reactant gases. The turnover numbers, DMF/complex/day, range from 9 at 25C and 0.96 atm to 1375 at 100 C and 114 atm. The homogeneous synthesis of DMF is readily reversible by either increasing the temperature, lowering the pressure of the reactants, or both, during the catalytic reaction. The formation of DMF appears to be dependent on the partial pressures of the individual reactants. Separate reactions of the three reactants with (Pt2(u-PCP)3) at ambient conditions (25C, 700 torr) give adducts with (CH3)2NH, but not with CO2 or H2. Keywords: Carbon Dioxide, Hydrogenation, Homogeneous Catalysis, N, N dimethylformamide, Platinum, Phosphine Complex.
The Chemistry Of The Catalyzed Hydrogenation Of Carbon Monoxide
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Author : G. Henrici-Olive
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
The Chemistry Of The Catalyzed Hydrogenation Of Carbon Monoxide written by G. Henrici-Olive and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
During the oil embargo, in the winter 1973174, parts of Western Europe present ed an almost war-like aspect on Saturdays and Sundays: no traffic on the high ways, no crowds at ski resorts and other weekend entertainment places, no gaso line at the pumps. Living and teaching then in that part of the world, and discussing the situa tion with our students, we came to the conclusion that it would be timely to col lect the fine chemistry already known at the time in the field of conversion of coal to gasoline and other chemicals, and by this way help to draw the attention to this important alternative to crude oil. The idea of this book was born. The energy shock of the early seventies has been healthy and of great conse quences in chemistry. Large amounts of research money have been put to work since, and our knowledge of the possibilities and limitations of coal-based chemistry has increased enormously. During several years it appeared inap propriate to write a monograph about a topic which was in the midst of such an impetuous development. Nevertheless, we collected, and critically selected, the upcoming work as it appeared in the literature, and also tried to provide some modest input ourselves. Now, ten years later, the situation seems to be settled to a certain degree.
Carbon Dioxide To Chemicals And Fuels
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Author : Aulice Scibioh
language : en
Publisher: Elsevier
Release Date : 2018-01-02
Carbon Dioxide To Chemicals And Fuels written by Aulice Scibioh and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-01-02 with Technology & Engineering categories.
Carbon Dioxide to Chemicals and Fuels provides a snapshot of the present status of this rapidly growing field, examining ongoing breakthroughs in research and development, motivations, innovations and their respective impacts and perspectives. It also covers in detail the existing technical barriers to achieving key goals in this area. This book details the various methods, both currently available and potential, for conversion of CO2 into fuels and chemicals. With explanation of concepts and their applications, Carbon Dioxide to Chemicals and Fuels offers an interdisciplinary approach that draws on and clarifies the most recent research trends. Explains the fundamental aspects of CO2 utilization Provides recent developments in CO2 utilization for the production of chemicals Answers the questions surrounding why some processes have not commercialized Discusses and analyses in detail many available catalytic conversion methods
Conversion Of Carbon Dioxide Into Hydrocarbons Vol 2 Technology
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Author : Inamuddin
language : en
Publisher: Springer Nature
Release Date : 2019-11-13
Conversion Of Carbon Dioxide Into Hydrocarbons Vol 2 Technology written by Inamuddin and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-11-13 with Science categories.
This book presents chemical and biological methods to convert carbon dioxide into various products such as methanol, ethanol, formic acid, formaldehyde, volatile organic compounds, syngas and polymers.
Conversion Of Carbon Dioxide Into Hydrocarbons Vol 1 Catalysis
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Author : Inamuddin
language : en
Publisher: Springer Nature
Release Date : 2020-01-01
Conversion Of Carbon Dioxide Into Hydrocarbons Vol 1 Catalysis written by Inamuddin and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-01-01 with Science categories.
This book presents the catalytic conversion of carbon dioxide into various hydrocarbons and other products using photochemical, electrochemical and thermo-chemical processes. Products include formate, formic acid, alcohols, lower and higher hydrocarbons, gases such as hydrogen, carbon monoxide and syngas.
Catalytic Reduction Of Carbon Dioxide To Methane And Other Species Via Formamide Intermediation Synthesis And Hydrogenation Of Hc O Nh2 In The Presence Of Ir Cl Co Ph3p 2
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Author : L. Vaska
language : en
Publisher:
Release Date : 1988
Catalytic Reduction Of Carbon Dioxide To Methane And Other Species Via Formamide Intermediation Synthesis And Hydrogenation Of Hc O Nh2 In The Presence Of Ir Cl Co Ph3p 2 written by L. Vaska and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with categories.
Formamide, HC(O)NH2, is catalytically synthesized from Carbon dioxide, Hydrogen and Ammonia in homogeneous toluene or alcohol solutions mediated by Ir(Cl)(CO)(Ph3P)2. The same iridium compound is used in the catalytic hydrogenation of neat formamide which leads to methane and N-methylformamides. The latter overall reaction is complicated due to the concurrent thermal decomposition of formamide yielding carbon black, NH3, Carbon monoxide, CO2, and water. The various possible steps in this complex catalytic system are briefly examined. Keywords: Trans-chlorocarbonylbis(triphenylphosphine)iridium. (aw).
Green Biphasic Homogeneous Catalysis And Synthesis Using Carbon Dioxide
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Author : David Jacob Heldebrant
language : en
Publisher:
Release Date : 2005
Green Biphasic Homogeneous Catalysis And Synthesis Using Carbon Dioxide written by David Jacob Heldebrant and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2005 with categories.
Greenhouse Gas Carbon Dioxide Mitigation
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Author : Martin M. Halmann
language : en
Publisher: CRC Press
Release Date : 1998-11-23
Greenhouse Gas Carbon Dioxide Mitigation written by Martin M. Halmann and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998-11-23 with Nature categories.
Any mention of the "greenhouse effect" tends to ignite controversy. While the rising atmospheric concentrations of greenhouse gases-especially carbon dioxide- are certainly among the most pressing issues today, theoretical and perceived consequences have been subject to conjecture and misinformation. That raging debate has obscured an important fact: scientists and engineers are hard at work on methods to reduce CO2 emissions, and devise practical methods for their remediation. Greenhouse Gas Carbon Dioxide Mitigation: Science and Technology sheds light on the most recent advancements, documented by two of the world's leading researchers on CO2. Aware of the complexity and still-unknown factors behind climatic change, the authors consider the need to make CO2 mitigation viable for both environmental and economic gain. To that end, Professor Halmann offers new insights into interesting chemical pathways for the conversion of CO2 to useful products. Steinberg adds real-life engineering solutions, applicable to heavy CO2-producing industrial processes, and improving efficiency of energy conversion. Exciting theories and pilot projects are also testing the potential for CO2 utilization, conversion, reduction, and disposal. Greenhouse Gas Carbon Dioxide Mitigation: Science and Technology reports on the use of biomass, such as ocean fertilization and "energy farms," to put CO2 to practical and safe use. Professional and academic readers involved with CO2 research will find Greenhouse Gas Carbon Dioxide Mitigation: Science and Technology an invaluable roadmap for information and inspiration-a way to move beyond argument, and into action.