Continuous Process For Oxidative Conversion Of Methane To Higher Hydrocarbons In The Gas Phase
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Continuous Process For Oxidative Conversion Of Methane To Higher Hydrocarbons In The Gas Phase
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Author :
language : en
Publisher:
Release Date : 1988
Continuous Process For Oxidative Conversion Of Methane To Higher Hydrocarbons In The Gas Phase written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with categories.
Methane Conversion By Oxidative Processes
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Author : Wolf
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-11-11
Methane Conversion By Oxidative Processes written by Wolf and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-11 with Technology & Engineering categories.
A reasonable case could be made that the scientific interest in catalytic oxidation was the basis for the recognition of the phenomenon of catalysis. Davy, in his attempt in 1817 to understand the science associated with the safety lamp he had invented a few years earlier, undertook a series of studies that led him to make the observation that a jet of gas, primarily methane, would cause a platinum wire to continue to glow even though the flame was extinguished and there was no visible flame. Dobereiner reported in 1823 the results of a similar investigation and observed that spongy platina would cause the ignition of a stream of hydrogen in air. Based on this observation Dobereiner invented the first lighter. His lighter employed hydrogen (generated from zinc and sulfuric acid) which passed over finely divided platinum and which ignited the gas. Thousands of these lighters were used over a number of years. Dobereiner refused to file a patent for his lighter, commenting that "I love science more than money." Davy thought the action of platinum was the result of heat while Dobereiner believed the ~ffect ~as a manifestation of electricity. Faraday became interested in the subject and published a paper on it in 1834; he concluded that the cause for this reaction was similar to other reactions.
Methane Conversion By Oxidative Processes
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Author : Eduardo E. Wolf
language : en
Publisher: Springer
Release Date : 1992
Methane Conversion By Oxidative Processes written by Eduardo E. Wolf and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992 with Science categories.
A reasonable case could be made that the scientific interest in catalytic oxidation was the basis for the recognition of the phenomenon of catalysis. Davy, in his attempt in 1817 to understand the science associated with the safety lamp he had invented a few years earlier, undertook a series of studies that led him to make the observation that a jet of gas, primarily methane, would cause a platinum wire to continue to glow even though the flame was extinguished and there was no visible flame. Dobereiner reported in 1823 the results of a similar investigation and observed that spongy platina would cause the ignition of a stream of hydrogen in air. Based on this observation Dobereiner invented the first lighter. His lighter employed hydrogen (generated from zinc and sulfuric acid) which passed over finely divided platinum and which ignited the gas. Thousands of these lighters were used over a number of years. Dobereiner refused to file a patent for his lighter, commenting that "I love science more than money." Davy thought the action of platinum was the result of heat while Dobereiner believed the ~ffect ~as a manifestation of electricity. Faraday became interested in the subject and published a paper on it in 1834; he concluded that the cause for this reaction was similar to other reactions.
Mechanism Imposed Limitations On The Yield Of Higher Hydrocarbons From The Oxidative Coupling Of Methane And Alternate Approaches To Methane Conversion
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Author :
language : en
Publisher:
Release Date : 1991
Mechanism Imposed Limitations On The Yield Of Higher Hydrocarbons From The Oxidative Coupling Of Methane And Alternate Approaches To Methane Conversion written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1991 with categories.
The conversion of methane to higher hydrocarbons via oxidative coupling over metal oxide catalysts is the subject of intense study as a route for natural gas upgrading. Detailed study on the reaction of methane over a mixed manganese-magnesium oxide implicates a mechanism involving generation of methyl radicals at the surface, followed by radical coupling as well as other radical reactions in the gas phase as the predominant mode of carbon-carbon bond formation. Analysis of the consequences of this mechanisms suggests that there is an inherent limit on yield, including a major adverse pressure effect, that may severely impact the potential utility of this route. Among several possible approaches to circumventing this limitation, a novel class of catalyst - transition metal-exchanged P -alumina -- has been found to be highly active for complete oxidation of methane. Results of catalytic and characterization studies will be presented.
The Changing Landscape Of Hydrocarbon Feedstocks For Chemical Production
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Author : National Academies of Sciences, Engineering, and Medicine
language : en
Publisher: National Academies Press
Release Date : 2016-12-10
The Changing Landscape Of Hydrocarbon Feedstocks For Chemical Production written by National Academies of Sciences, Engineering, and Medicine and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-12-10 with Science categories.
A decade ago, the U.S. chemical industry was in decline. Of the more than 40 chemical manufacturing plants being built worldwide in the mid-2000s with more than $1 billion in capitalization, none were under construction in the United States. Today, as a result of abundant domestic supplies of affordable natural gas and natural gas liquids resulting from the dramatic rise in shale gas production, the U.S. chemical industry has gone from the world's highest-cost producer in 2005 to among the lowest-cost producers today. The low cost and increased supply of natural gas and natural gas liquids provides an opportunity to discover and develop new catalysts and processes to enable the direct conversion of natural gas and natural gas liquids into value-added chemicals with a lower carbon footprint. The economic implications of developing advanced technologies to utilize and process natural gas and natural gas liquids for chemical production could be significant, as commodity, intermediate, and fine chemicals represent a higher-economic-value use of shale gas compared with its use as a fuel. To better understand the opportunities for catalysis research in an era of shifting feedstocks for chemical production and to identify the gaps in the current research portfolio, the National Academies of Sciences, Engineering, and Medicine conducted an interactive, multidisciplinary workshop in March 2016. The goal of this workshop was to identify advances in catalysis that can enable the United States to fully realize the potential of the shale gas revolution for the U.S. chemical industry and, as a result, to help target the efforts of U.S. researchers and funding agencies on those areas of science and technology development that are most critical to achieving these advances. This publication summarizes the presentations and discussions from the workshop.
The Gas Phase Oxidation Of Hydrocarbons
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Author : V. Ya. Shtern
language : en
Publisher: Elsevier
Release Date : 2016-07-29
The Gas Phase Oxidation Of Hydrocarbons written by V. Ya. Shtern and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-07-29 with Science categories.
The Gas-Phase Oxidation of Hydrocarbons reviews research on the mechanism of oxidation of paraffins, naphthenes, olefines, and aromatic hydrocarbons and explains in detail the phenomena and theories with significant kinetic equations and graphs. This book first presents a study of the development of research on the gaseous-phase oxidation of hydrocarbons. The non-chain schemes for the oxidation of hydrocarbons, such as hydroxylation, peroxidation, and aldehyde and dehydrogenation schemes, are then discussed. This book also presents experimental investigations and important topics such as oxidation of methane and olefinic hydrocarbons. This selection will be invaluable to students and experts in the field of chemistry and related disciplines.
Catalytic Partial Oxidation Of Methane At High Flowrates
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Author : Keith Lawrence Hohn
language : en
Publisher:
Release Date : 1999
Catalytic Partial Oxidation Of Methane At High Flowrates written by Keith Lawrence Hohn and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999 with categories.
Methane Conversion
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Author : D.M. Bibby
language : en
Publisher: Elsevier
Release Date : 1988-03-01
Methane Conversion written by D.M. Bibby and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988-03-01 with Technology & Engineering categories.
This proceedings volume comprises the invited plenary lectures, contributed and poster papers presented at a symposium organised to mark the successful inauguration of the world's first commercial plant for production of gasoline from natural gas, based on the Mobil methanol-to-gasoline process. The objectives of the Symposium were to present both fundamental research and engineering aspects of the development and commercialization of gas-to-gasoline processes. These include steam reforming, methanol synthesis and methanol-to-gasoline. Possible alternative processes e.g. MOGD, Fischer-Tropsch synthesis of hydrocarbons, and the direct conversion of methane to higher hydrocarbons were also considered.The papers in this volume provide a valuable and extremely wide-ranging overview of current research into the various options for natural gas conversion, giving a detailed description of the gas-to-gasoline process and plant. Together, they represent a unique combination of fundamental surface chemistry catalyst characterization, reaction chemistry and engineering scale-up and commercialization.
Catalysis
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Author : James Spivey
language : en
Publisher: Royal Society of Chemistry
Release Date : 2019-03-15
Catalysis written by James Spivey and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-03-15 with Catalysis categories.
Catalysts are required for a variety of applications and researchers are increasingly challenged to find cost effective and environmentally benign catalysts to use. This volume looks at modern approaches to catalysis and reviews the extensive literature including direct methane conversion, nanocomposite catalysts for transformation of biofuels into syngas and hydrogen, and catalytic wet air oxidation technology for industrial wastewater treatment. Appealing broadly to researchers in academia and industry, it will be of great benefit to any researcher wanting a succinct reference on developments in this area now and looking to the future.
Natural Gas Conversion
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Author : A. Holmen
language : en
Publisher: Elsevier
Release Date : 1991-05-27
Natural Gas Conversion written by A. Holmen and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1991-05-27 with Science categories.
These proceedings reflect the extensive fundamental and applied research efforts that are currently being made on the conversion of gas, in particular on the direct conversion of methane. The Symposium in Oslo focused on the following topics: Direct conversion of methane, Fischer-Tropsch chemistry, methanol conversion and natural gas conversion processes. The main aim was to present the state-of-the-art and progress currently being made within each of these areas. The book contains the papers presented and includes plenary lectures, short communications and posters. The papers will be of interest to scientists and engineers working in the field of gas conversion, transportation fuels, primary petrochemicals and catalysis.