Evaluating The Effect Of Powder Oxygen Content On The Microstructure And Mechanical Properties Of Silicon Carbide Densified By Spark Plasma Sintering
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Evaluating The Effect Of Powder Oxygen Content On The Microstructure And Mechanical Properties Of Silicon Carbide Densified By Spark Plasma Sintering
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Author : Vincent Alexander DeLucca
language : en
Publisher:
Release Date : 2017
Evaluating The Effect Of Powder Oxygen Content On The Microstructure And Mechanical Properties Of Silicon Carbide Densified By Spark Plasma Sintering written by Vincent Alexander DeLucca and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017 with Silicon carbide categories.
Silicon carbide (SiC) is an important material in industry due to its favorable mechanical, thermal, chemical, and electrical properties. While it has been mainly used as an abrasive material in the past, more modern applications like armor and other structural applications, often require densified ceramic bodies. SiC powders can be densified in a number of ways, but one common method is solid-state sintering, either with or without applied pressure. It is well known that in the presence of oxygen, pure SiC will form a passivating oxide layer of silica (SiO2) on its surface. This poses a problem in sintering as SiO2 can inhibit the densification of solid state sintered SiC. This thesis examines the effects of varying oxygen content levels in silicon carbide powders on the microstructure and mechanical properties of the resulting densified bodies after solid state sintering via the spark plasma sintering (SPS) method. Two commercial SiC powders were obtained, characterized, and treated to introduce a range of different oxygen content levels. These powders were then densified via the spark plasma sintering method using boron carbide and carbon additives to produce dense samples. Three series of samples were made using each powder, one varying the amount of carbon added as a particulate, one varying the amount of carbon added as a liquid resin, and one where the oxygen content of the powder was directly manipulated by HF washing, aging, or heat treating. The dense SiC samples were then characterized to determine the effect of the powder's oxygen content on the microstructure and mechanical properties. The samples were examined using scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), Knoop microhardness testing, and nondestructive ultrasonic evaluation techniques including acoustic spectroscopy and conventional NDE methods. SEM and EBSD analysis revealed that changes in the powder oxygen content can result in a number of microstructural effects. At intermediate oxygen levels, exaggerated grain growth can occur resulting in large plate-like grains, accompanied by a transformation from the 6H to 4H SiC polytype. At higher oxygen levels, densification may be inhibited and at very high oxygen contents formation of an oxygen rich secondary phase can occur. Varying the oxygen content of the SiC powder also significantly affects the mechanical properties of the dense ceramic. Ultrasonic measurements of the elastic properties showed a clear decrease in the elastic moduli as the oxygen content is increased. Knoop microhardness measurements show similar behavior with a reduction in hardness with increased powder oxygen content.
Effect Of Sintering Time And Composition Of Sintering Aids On The Core Rim Microstructure And Material Properties Of Spark Plasma Sintered Silicon Carbide
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Author : Steven E. Bagienski
language : en
Publisher:
Release Date : 2013
Effect Of Sintering Time And Composition Of Sintering Aids On The Core Rim Microstructure And Material Properties Of Spark Plasma Sintered Silicon Carbide written by Steven E. Bagienski and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013 with Ceramic materials categories.
Silicon carbide is an industrial ceramic used for many applications. Due to its complicated crystal structure, many different types exist and can be made to have a "core-rim" microstructure in individual grains. In this work, SiC samples were processed via a co-precipitation and spark plasma sintered to examine the core-rim microstructure by altering the sintering time when spark plasma sintered, the additive amounts, and the polytype composition. Samples were characterized via density, hardness, FESEM, XRD, and Raman analysis depending on the type of samples. The density and hardness of samples showed that the samples for the dwell time studied were densified but the ones of varying polytype were not. The hardness generally increased with longer sintering dwell times, whereas the density measurements were too similar to discern any appreciable difference between samples. The extent of the core-rim structure as seen from FESEM images had a large variability, but preliminary results hint at less core-rim features with longer dwell times. The XRD results were typical of the materials present in the sample and showed a SiO2 phase.
Effect Of Coprecipitation Of Sintering Aids On The Microstructure And Grain Boundary Development Of Sintered Silicon Carbide
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Author : Steven R. Mercurio
language : en
Publisher:
Release Date : 2011
Effect Of Coprecipitation Of Sintering Aids On The Microstructure And Grain Boundary Development Of Sintered Silicon Carbide written by Steven R. Mercurio and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011 with Silicon carbide categories.
Coprecipitation was examined as a method of introducing sintering aids into silicon carbide (SiC) as a fine, reactive coating. The improved sinterability and mixedness of coprecipitated samples, when coupled with advanced densification methods, developed fine grained SiC with varied microstructures. Coprecipitation imparted additional process control and influenced the phase, crystallinity, and properties of the grain boundaries. A simple coprecipitation process was developed to introduce aluminum and rare earth sintering aids into SiC. Early samples yielded low densities so the process was modified to address the dispersion of the SiC particles and breakdown of agglomerates before coating. The modifications improved the densification and influenced the structure and properties. Powders were prepared with varying weight percents of sintering aids and several rare earths in order to study the grain boundary structure and properties. Samples were densified using hot pressing and spark plasma sintering to better utilize the enhanced sinterability of coprecipitated powders. These samples were compared to conventional ball mill processing. Scanning electron microscopy was utilized to examine the microstructure and determine the grain size and presence of defects. The degree of mixedness of the additives was investigated through fluorescence measurements. X-ray diffraction was used to determine the polytype and phase distribution. Selected mechanical properties were measured and compared between the different samples. Hardness was studied extensively, including analysis of load-hardness curves over a range of loads. The hardness data and indents were examined in order to explore the fracture behavior and defect effects. Liquid phase sintered SiC prepared using coprecipitation exhibited very different phase content and crystallinity than ball milled samples. Fluorescence measurements for coprecipitated samples showed longer decay lifetimes indicating improved mixedness. Samples with amorphous grain boundaries and triple points were developed, where XRD results displayed a lower amount of yttrium aluminum garnet than other methods. The formation of a crystalline mullite phase and absence of excess alumina were observed. These overall results indicated the possibility of different fracture behavior.
Spark Plasma Sintering Of Materials
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Author : Pasquale Cavaliere
language : en
Publisher: Springer
Release Date : 2019-02-18
Spark Plasma Sintering Of Materials written by Pasquale Cavaliere and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-02-18 with Technology & Engineering categories.
This book describes spark plasma sintering (SPS) in depth. It addresses fundamentals and material-specific considerations, techniques, and applications across a broad spectrum of materials. The book highlights methods used to consolidate metallic or ceramic particles in very short times. It highlights the production of complex alloys and metal matrix composites with enhanced mechanical and wear properties. Emphasis is placed on the speed of the sintering processes, uniformity in product microstructure and properties, reduced grain growth, the compaction and sintering of materials in one processing step, various materials processing, and high energy efficiency. Current and potential applications in space science and aeronautics, automation, mechanical engineering, and biomedicine are addressed throughout the book.
Engineered Materials Abstracts
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Author :
language : en
Publisher:
Release Date : 1995-10
Engineered Materials Abstracts written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1995-10 with Ceramic materials categories.
Ceramic Abstracts
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Author :
language : en
Publisher:
Release Date : 1998
Ceramic Abstracts written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998 with Ceramics categories.
Field Assisted Sintering
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Author : Eugene A. Olevsky
language : en
Publisher: Springer
Release Date : 2018-08-09
Field Assisted Sintering written by Eugene A. Olevsky and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-08-09 with Technology & Engineering categories.
This book represents the first ever scientific monograph including an in-depth analysis of all major field-assisted sintering techniques. Until now, the electromagnetic field-assisted technologies of materials processing were lacking a systematic and generalized description in one fundamental publication; this work promotes the development of generalized concepts and of comparative analyses in this emerging area of materials fabrication. This book describes modern technologies for the powder processing-based fabrication of advanced materials. New approaches for the development of well-tailored and stable structures are thoroughly discussed. Since the potential of traditional thermo-mechanical methods of material treatment is limited due to inadequate control during processing, the book addresses ways to more accurately control the resultant material's structure and properties by an assisting application of electro-magnetic fields. The book describes resistance sintering, high-voltage consolidation, sintering by low-voltage electric pulses (including spark plasma sintering), flash sintering, microwave sintering, induction heating sintering, magnetic pulse compaction and other field-assisted sintering techniques. Includes an in-depth analysis of all major field-assisted sintering techniques; Explains new techniques and approaches for material treatment; Provides detailed descriptions of spark plasma sintering, microwave sintering, high-voltage consolidation, magnetic pulse compaction, and various other approaches when field-assisted treatment is applied.
Ultra High Temperature Ceramics
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Author : William G. Fahrenholtz
language : en
Publisher: John Wiley & Sons
Release Date : 2014-10-10
Ultra High Temperature Ceramics written by William G. Fahrenholtz and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-10-10 with Technology & Engineering categories.
The first comprehensive book to focus on ultra-high temperature ceramic materials in more than 20 years Ultra-High Temperature Ceramics are a family of compounds that display an unusual combination of properties, including extremely high melting temperatures (>3000°C), high hardness, and good chemical stability and strength at high temperatures. Typical UHTC materials are the carbides, nitrides, and borides of transition metals, but the Group IV compounds (Ti, Zr, Hf) plus TaC are generally considered to be the main focus of research due to the superior melting temperatures and stable high-melting temperature oxide that forms in situ. Rather than focusing on the latest scientific results, Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications broadly and critically combines the historical aspects and the state-of-the-art on the processing, densification, properties, and performance of boride and carbide ceramics. In reviewing the historic studies and recent progress in the field, Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications provides: Original reviews of research conducted in the 1960s and 70s Content on electronic structure, synthesis, powder processing, densification, property measurement, and characterization of boride and carbide ceramics. Emphasis on materials for hypersonic aerospace applications such as wing leading edges and propulsion components for vehicles traveling faster than Mach 5 Information on materials used in the extreme environments associated with high speed cutting tools and nuclear power generation Contributions are based on presentations by leading research groups at the conference "Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications II" held May 13-19, 2012 in Hernstein, Austria. Bringing together disparate researchers from academia, government, and industry in a singular forum, the meeting cultivated didactic discussions and efforts between bench researchers, designers and engineers in assaying results in a broader context and moving the technology forward toward near- and long-term use. This book is useful for furnace manufacturers, aerospace manufacturers that may be pursuing hypersonic technology, researchers studying any aspect of boride and carbide ceramics, and practitioners of high-temperature structural ceramics.
Thermal Processing Of Injection Molded Silicon Carbide
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Author : Richard E. Chinn
language : en
Publisher:
Release Date : 2015
Thermal Processing Of Injection Molded Silicon Carbide written by Richard E. Chinn and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015 with Micromachining categories.
Silicon carbide is an important and versatile nonoxide ceramic. Powder injection molding (PIM) is a method of high-speed fabrication of complex near-net shapes of SiC and other powders. Green micro-machining (GMM) is used to extend the shaping capability of green ceramics and powder metallurgy to smaller feature sizes. Debinding--removal of organic additives--is the rate-limiting step in PIM. Sintering aids enable densification of sintered powders, especially in the absence of applied pressure during sintering. Thermal Processing of Injection-Molded Silicon Carbide presents a study of the effects of GMM, debinding, sintering aids and sintering on two size distributions of PIM [alpha]-SiC with 5% each of Y2O3 and AlN as sintering aids. The use of 10% 20-nm particles, i.e., a bimodal size distribution, to increase the packing density of the green bodies was found to have a small effect on the rate of debinding, the liquid-phase sintering (LPS) precipitates, the microstructural development and the mechanical properties of SiC compared to the conventional monomodal size distribution, where D50 = 0.7 [micro]m. The nanoparticles and debinding methods did have a strong effect on the feasibility of GMM on SiC. The nanoparticles, debinding methods and GMM in combination significantly affected the sinterability of SiC. The rates and effects of solvent debinding and thermal debinding were measured and compared by various kinetic models. The catalytic effect of the bimodal SiC, if any, was small compared to PIM SiC with monomodal particles. The activation energy for thermal debinding was similar to that of solvent debinding. Too rapid of debinding by either method was detrimental to sintering in the form of fracture in the green body by residual stress. The debinding mechanism shifted from surface dissolution to bulk diffusion as the solvent debinding progressed. Changes in thermal debinding mechanisms were also noted as a function of heating rate. Thermal debinding was problematic in PIM bars with a large characteristic diffusion path length [psi], which led to fractures during sintering. Weak particle bonding and uncontrolled grain growth were observed in some cases after thermal debinding, and attributed to dissolution of aluminum in SiC, excess oxidation of the SiC and premature decomposition of polypropylene. Solvent debinding was less stressful, but not without fractures in some instances due to the swelling of the wax as it dissolved. Monomodal SiC was much more amenable to GMM than bimodal, whether solvent or thermally debound. The GMM swarf adhered to the monomodal more than to bimodal, even after the wax holding the swarf to the substrate was dissolved. The bimodal SiC had about one percentage point better densification than the monomodal. The grain size, precipitate content and Knoop hardness were about the same for monomodal and bimodal, whether solvent or thermally debound, with or without GMM, except in the case of thermally dewaxed bimodal SiC.
Densification Of Rapid Carbothermal Synthesized And Commercial Boron Carbide By Spark Plasma Sintering
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Author : Muhammet Fatih Toksoy
language : en
Publisher:
Release Date : 2014
Densification Of Rapid Carbothermal Synthesized And Commercial Boron Carbide By Spark Plasma Sintering written by Muhammet Fatih Toksoy and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014 with Boron categories.
Boron carbide is a structural ceramic material with exceptionally good physical and chemical properties. Thus, boron carbide is proposed for applications in extreme conditions. However synthesizing and sintering of boron carbide is extremely difficult due to its high melting point and strong covalent bonding. Secondary phases, non-uniform composition, complex stoichiometry and powder morphology are problems in most commercial powders as a result of synthesis and powder preparation procedures. Achieving more than 90% TD is difficult due to strong covalent bonding structure and low plasticity of boron carbide. Very high sintering temperatures that approach the melting point are needed for densification. This dissertation seeks to establish an improved understanding on Spark Plasma Sintering (SPS) behaviors of boron carbide and effects of powder properties on final products. Rapid carbothermal reduction (RCR) method was utilized to synthesize boron carbide powder. Submicron boron carbide powders with narrow particle size distribution were synthesized. Free carbon was significantly reduced and near B4C stoichiometry was achieved. Commercial boron carbide powders were also modified by processing in the RCR reactor. Free carbon was reduced to trace amounts; powder morphology and stoichiometry was modified. Commercial, synthesized and modified boron carbide powders were analyzed and characterized using X-Ray diffraction (XRD), electron microscopy, particle size analysis and chemical analyses. Synthesized boron carbide powder had smaller particle size, lower free carbon levels and increased concentration of twinning compared to commercial samples. Standard sintering procedure for boron carbide was established for SPS. Powders were sintered to different temperatures with various dwell times to analyze sintering behavior of boron carbide on SPS without any additives. Synthesized boron carbide powders reached +99% TD at lower temperature and shorter dwell times compared to commercial boron carbide samples. Highly dense materials were produced with limited grain growth. Dense samples were analyzed by XRD and electron microscopy. Knoop hardness tests were applied to dense boron carbide samples. Hardness results showed an improvement with RCR synthesized powders. Results were correlated and powder-sintering-final properties relations were established.