Interface Characterization Materials Designs For High Performance All Solid State Batteries
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Interface Characterization Materials Designs For High Performance All Solid State Batteries
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Author : Darren Huan Shen Tan
language : en
Publisher:
Release Date : 2021
Interface Characterization Materials Designs For High Performance All Solid State Batteries written by Darren Huan Shen Tan and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021 with categories.
All solid-state batteries (ASSBs) show great promise toward becoming the dominant next-generation energy storage technology. Compared to conventional liquid electrolyte-based lithium ion batteries, ASSBs utilize nonflammable inorganic solid-state electrolytes (SSEs), which translate to improved safety and the ability to operate over a wider temperature range. Although the recent discoveries of highly conductive SSEs led to tremendous progress in ASSB's development, they still face barriers that limit their practical application, such as poor interfacial stability, scalability challenges and limited performance at high current densities. Additionally, efforts to develop sustainable manufacturing of lithium ion batteries are still lacking, with no prevailing strategy developed yet to handle recyclability of ASSBs. Recognizing this, this dissertation seeks to evaluate SSEs beyond conventional factors and offer a perspective on various bulk/interface and chemical/electrochemical phenomena that are of interest to both the scientific community and the industry. Beginning from an introduction to the current state-of-the-art, rational solutions to overcome some major fundamental obstacles faced by the ASSBs will be discussed, strategies toward enabling scalability as well as potential designs for sustainable ASSB recycling models will be discussed. Specifically, lithium solid-state battery systems were studied using sulfide based SSEs. The electrochemical reactivity of the argyrodite Li6PS5Cl system was studied, to gain insight into its reaction mechanisms, products, and reversible redox behavior. In terms of scalability, binder-solvent-sulfide compatibility was evaluated, in order to enable scalable roll to roll processability of thin and flexible sulfide SSEs. To overcome performance limitations at the anode, carbon free alloys electrodes were enabled, achieving high critical current densities and low temperature operation of ASSB full cells, addressing a key bottleneck in ASSB development. Finally, a fully recyclable ASSB model was designed, incorporating direct recycling approaches that reduce energy and greenhouse gas emissions compared to conventional recycling technologies. Overall, this dissertation offers a deepened understanding of interfacial phenomena, and improved design strategies that translates into better material selection for high performance and sustainable ASSBs.
Solid State Batteries
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Author : Nithyadharseni Palaniyandy
language : en
Publisher: Springer Nature
Release Date : 2022-11-01
Solid State Batteries written by Nithyadharseni Palaniyandy and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-11-01 with Technology & Engineering categories.
This book offers a comprehensive analysis of novel design strategies in higher energy solid-state lithium batteries. It describes synthesis and experimental techniques to characterize the physical, chemical and electrochemical properties of the electrode and electrolytes. The book reports on electrochemical measurements of conductivity and related parameters in solid electrolytes and its interfaces. It also presents various technologies that have been used for the fabrication of all-solid-state lithium-ion batteries such as thin-film, 3D printing (additive manufacturing) and atomic layer deposition. A large part of the text focus on the description on the complete functioning and challenges with the electrochemistry of the electrodes and solid electrolyte interfaces. The book also supplies valuable insight into potential growth opportunities in this exciting market and cost-effective design tactics in solid-state assemblies.
Nanostructured Materials For Next Generation Energy Storage And Conversion
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Author : Qiang Zhen
language : en
Publisher: Springer Nature
Release Date : 2019-10-10
Nanostructured Materials For Next Generation Energy Storage And Conversion written by Qiang Zhen and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-10-10 with Technology & Engineering categories.
Volume 3 of a 4-volume series is a concise, authoritative and an eminently readable and enjoyable experience related to lithium ion battery design, characterization and usage for portable and stationary power. Although the major focus is on lithium metal oxides or transition metal oxide as alloys, the discussion of fossil fuels is also presented where appropriate. This monograph is written by recognized experts in the field, and is both timely and appropriate as this decade will see application of lithium as an energy carrier, for example in the transportation sector. This Volume focuses on the fundamentals related to batteries using the latest research in the field of battery physics, chemistry, and electrochemistry. The research summarised in this book by leading experts is laid out in an easy-to-understand format to enable the layperson to grasp the essence of the technology, its pitfalls and current challenges in high-power Lithium battery research. After introductory remarks on policy and battery safety, a series of monographs are offered related to fundamentals of lithium batteries, including, theoretical modeling, simulation and experimental techniques used to characterize electrode materials, both at the material composition, and also at the device level. The different properties specific to each component of the batteries are discussed in order to offer tradeoffs between power and energy density, energy cycling, safety and where appropriate end-of-life disposal. Parameters affecting battery performance and cost, longevity using newer metal oxides, different electrolytes are also reviewed in the context of safety concerns and in relation to the solid-electrolyte interface. Separators, membranes, solid-state electrolytes, and electrolyte additives are also reviewed in light of safety, recycling, and high energy endurance issues. The book is intended for a wide audience, such as scientists who are new to the field, practitioners, as well as students in the STEM and STEP fields, as well as students working on batteries. The sections on safety and policy would be of great interest to engineers and technologists who want to obtain a solid grounding in the fundamentals of battery science arising from the interaction of electrochemistry, solid-state materials science, surfaces, and interfaces.
Hard X Ray Photoelectron Spectroscopy Haxpes
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Author : Joseph Woicik
language : en
Publisher: Springer
Release Date : 2015-12-26
Hard X Ray Photoelectron Spectroscopy Haxpes written by Joseph Woicik and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-12-26 with Science categories.
This book provides the first complete and up-to-date summary of the state of the art in HAXPES and motivates readers to harness its powerful capabilities in their own research. The chapters are written by experts. They include historical work, modern instrumentation, theory and applications. This book spans from physics to chemistry and materials science and engineering. In consideration of the rapid development of the technique, several chapters include highlights illustrating future opportunities as well.
Interface Ionics
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Author : Yasutoshi Iriyama
language : en
Publisher: Springer
Release Date : 2024-10-27
Interface Ionics written by Yasutoshi Iriyama and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-10-27 with Technology & Engineering categories.
This book focuses on ion transport and storage around the interfaces in solid-state-ionics devices, especially for all-solid-state batteries. It covers materials research from fundamental model systems to practically important materials, advanced analysis methods, and computational & data science. This volume is intended for researchers in academia and industry who have studied or worked in this field. It is expected to provide readers with guidelines for interface and material design aimed at advancing all-solid-state batteries, as well as insights into the development of novel solid-state ionics devices. This book is a summary of the studies obtained in the Grant-in-Aid for Scientific Research on Innovative Areas "Interface Ionics” founded by the Japanese Ministry of Education, Culture, Sports, Science and Technology (MEXT) during 2019-2023.
Li S Batteries The Challenges Chemistry Materials And Future Perspectives
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Author : Rezan Demir-cakan
language : en
Publisher: #N/A
Release Date : 2017-06-09
Li S Batteries The Challenges Chemistry Materials And Future Perspectives written by Rezan Demir-cakan and has been published by #N/A this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-06-09 with Science categories.
'This book provides an excellent review and analysis of the latest information on rechargeable Li-S battery research. With a clear and concise writing style and in-depth technical material , this book will appeal to undergraduates and graduates, researchers, chemists, material scientists, and physicists working in the field of energy storage, especially those with an interest in Li-S battery technology.'IEEE Electrical Insulation MagazineLithium-sulfur (Li-S) batteries give us an alternative to the more prevalent lithium-ion (Li-ion) versions, and are known for their observed high energy densities. Systems using Li-S batteries are in early stages of development and commercialization however could potentially provide higher, safer levels of energy at significantly lower cost.In this book the history, scientific background, challenges and future perspectives of the lithium-sulfur system are presented by experts in the field. Focus is on past and recent advances of each cell compartment responsible for the performance of the Li-S battery, and includes analysis of characterization tools, new designs and computational modeling. As a comprehensive review of current state-of-play, it is ideal for undergraduates, graduate students, researchers, physicists, chemists and materials scientists interested in energy storage, material science and electrochemistry.
Solid State Batteries Materials Design And Optimization
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Author : Christian Julien
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-11-27
Solid State Batteries Materials Design And Optimization written by Christian Julien and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-27 with Science categories.
The field of solid state ionics is multidisciplinary in nature. Chemists, physicists, electrochimists, and engineers all are involved in the research and development of materials, techniques, and theoretical approaches. This science is one of the great triumphs of the second part of the 20th century. For nearly a century, development of materials for solid-state ionic technology has been restricted. During the last two decades there have been remarkable advances: more materials were discovered, modem technologies were used for characterization and optimization of ionic conduction in solids, trial and error approaches were deserted for defined predictions. During the same period fundamental theories for ion conduction in solids appeared. The large explosion of solid-state ionic material science may be considered to be due to two other influences. The first aspect is related to economy and connected with energy production, storage, and utilization. There are basic problems in industrialized countries from the economical, environmental, political, and technological points of view. The possibility of storing a large amount of utilizable energy in a comparatively small volume would make a number of non-conventional intermittent energy sources of practical convenience and cost. The second aspect is related to huge increase in international relationships between researchers and exchanges of results make considerable progress between scientists; one find many institutes joined in common search programs such as the material science networks organized by EEC in the European countries.
Computational Design Of Battery Materials
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Author : Dorian A. H. Hanaor
language : en
Publisher: Springer Nature
Release Date :
Computational Design Of Battery Materials written by Dorian A. H. Hanaor and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on with categories.
Design Of Advanced Polymer Electrolyte For High Performance Lithium And Sodium Batteries
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Author : Wenfeng Liang
language : en
Publisher:
Release Date : 2020
Design Of Advanced Polymer Electrolyte For High Performance Lithium And Sodium Batteries written by Wenfeng Liang and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020 with Polyelectrolytes categories.
The energy density of lithium ion batteries (LIBs) is limited by the capacities of the electrode materials. Lithium metal is a promising anode material for future LIBs due to its high theoretical specific capacity (3,860 mAh/g) and low redox potential (-3.04 V vs. standard hydrogen electrode). However, lithium plating in liquid electrolyte will form Li dendritic structure and subsequently penetrate the porous polymeric separator, resulting in battery short circuiting. A straightforward method to suppress the growth of lithium dendrites is to replace the liquid phase electrolyte with a solid-state one. Among different solid-state electrolyte candidates, solid polymer electrolyte (SPE) is advantageous due to its flexible nature and low-cost raw material. However, SPE typically exhibits low ionic conductivity compared to its liquid electrolyte counterpart, which thus could result in restricted use in battery applications. In this work, a rational approach to achieve highly ionic conductive and electrochemically stable SPEs will be discussed. A phase-diagram was firstly mapped out to provide guidance in designing a composite electrolyte with high ionic conductivity at room temperature. The thermal and electrochemical stability of SPE were then characterized. A dual-salt base electrolyte with lithium bis(oxalate)borate (LiBOB) and bis(trifluoromethanesulphonyl)imide (LiTFSI) exhibited excellent electrochemical stability from the passivation layer formed between the electrode/electrolyte interface. In addition, SPEs based on crosslinked fluoropolymer and poly(ethylene glycol) diacrylate (PEGDA) were investigated. Those properties of SPE enable the fabrication of solid-state batteries with lithium metal as an anode. Lithium plating/striping experiments and battery tests were conducted, and the results indicated that the dual-salt SPE could be a promising candidate electrolyte for next generation solid-state rechargeable battery. Sodium ion batteries display good performance yet with limited protection for the inevitable sodium dendrite growth if coupled with metallic sodium electrode, which is an adverse phenomenon that would eventually result in the deterioration of the battery. SPEs with superior ionic conductivity and outstanding electrochemical stability are promising for the all solid-state sodium batteries in grid-storage applications. In this study, a transparent free-standing SPE membrane comprising sodium perchlorate (NaClO4), PEGDA and plastic crystal molecules was fabricated. This sodium based SPE exhibits high sodium-ion conductive property (over 0.925 mS/cm at 30 oC) while being electrochemically stable. A rational approach has also been designed and achieved by using the phase diagram. The NaClO4-based SPE can not only exhibit excellent electrochemical stability with metallic sodium electrode, but also provide remarkable current rate and long-term cycling performance for the solid-state sodium metal batteries (SMB).
Handbook Of Solid State Batteries Second Edition
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Author : Nancy J Dudney
language : en
Publisher: World Scientific
Release Date : 2015-07-09
Handbook Of Solid State Batteries Second Edition written by Nancy J Dudney and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-07-09 with Science categories.
Solid-state batteries hold the promise of providing energy storage with high volumetric and gravimetric energy densities at high power densities, yet with far less safety issues relative to those associated with conventional liquid or gel-based lithium-ion batteries. Solid-state batteries are envisioned to be useful for a broad spectrum of energy storage applications, including powering automobiles and portable electronic devices, as well as stationary storage and load-leveling of renewably generated energy. This comprehensive handbook covers a wide range of topics related to solid-state batteries, including advanced enabling characterization techniques, fundamentals of solid-state systems, novel solid electrolyte systems, interfaces, cell-level studies, and three-dimensional architectures. It is directed at physicists, chemists, materials scientists, electrochemists, electrical engineers, battery technologists, and evaluators of present and future generations of power sources. This handbook serves as a reference text providing state-of-the-art reviews on solid-state battery technologies, as well as providing insights into likely future developments in the field. It is extensively annotated with comprehensive references useful to the student and practitioners in the field.