Iridium Catalysts For Organic Reactions
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Iridium Catalysts For Organic Reactions
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Author : Luis A. Oro
language : en
Publisher: Springer Nature
Release Date : 2021-03-29
Iridium Catalysts For Organic Reactions written by Luis A. Oro and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-03-29 with Science categories.
This new volume “Iridium Catalysts for Organic Reactions” in the series “Topics in Organometallic Chemistry” intends to update several representative well-known reactions and to introduce other less known or new reactions in particular covering sustainability aspects. Iridium complexes are efficient in many catalytic homogeneous transformations providing high efficiency in both results, activity and selectivity. The interest of the book lies in the presentation of the advances, new perspectives and application in a variety of representative iridium-catalysed reaction. All chapters in the volume are contributed by relevant international experts in the field. The book is aimed at researchers, graduate students and synthetic chemists at all levels in academia and industry.
Iridium Catalysts For Organic Reactions
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Author :
language : en
Publisher:
Release Date : 2021
Iridium Catalysts For Organic Reactions written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021 with Asymmetric synthesis categories.
This new volume "Iridium Catalysts for Organic Reactions" in the series "Topics in Organometallic Chemistry" intends to update several representative well-known reactions and to introduce other less known or new reactions in particular covering sustainability aspects. Iridium complexes are efficient in many catalytic homogeneous transformations providing high efficiency in both results, activity and selectivity. The interest of the book lies in the presentation of the advances, new perspectives and application in a variety of representative iridium-catalysed reaction. All chapters in the volume are contributed by relevant international experts in the field. The book is aimed at researchers, graduate students and synthetic chemists at all levels in academia and industry.
Iridium Complexes In Organic Synthesis
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Author : Luis A. Oro
language : en
Publisher: John Wiley & Sons
Release Date : 2008-12-03
Iridium Complexes In Organic Synthesis written by Luis A. Oro and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-12-03 with Science categories.
Ranging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis. A must for organic, complex and catalytic chemists, as well as those working with/on organometallics.
Homogeneous Catalysis With Compounds Of Rhodium And Iridium
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Author : R. Dickson
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Homogeneous Catalysis With Compounds Of Rhodium And Iridium written by R. Dickson and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Some years ago, I agreed to contribute a volume to the Academic Press 'Organo metallic Chemistry' series - the metals to be covered were rhodium and iridium. Initially, my plan was to discuss both the fundamental organometallic chemistry and applications in organic synthesis. When the first draft of the manuscript was complete, it was apparent that I had exceeded my allowance of pages by a huge amount. It was then that I decided that the catalysis section warranted separate treatment. I am grateful to Reidel for agreeing to publish this volume on Homogeneous Catalysis with Compounds of Rhodium and Iridium as part of their 'Catalysis by Metal Complexes' series. The material I had for the original Academic Press project covered the litera ture to the end of 1978. I decided to update this to the end of 1982 with a few key references from 1983. It is some measure of the rate of progress in this field that the number of references almost doubled during this revision.
Nhc P And N P Iridium Catalysts For Hydrogenations And Hydrogen Transfer Reactions
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Author : Sutthichat Kerdphon
language : en
Publisher:
Release Date : 2018
Nhc P And N P Iridium Catalysts For Hydrogenations And Hydrogen Transfer Reactions written by Sutthichat Kerdphon and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018 with categories.
Iridium Catalysis
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Author : Pher G. Andersson
language : en
Publisher: Springer Science & Business Media
Release Date : 2011-01-05
Iridium Catalysis written by Pher G. Andersson and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-01-05 with Science categories.
From the contents: Robert H Crabtree: Introduction and History. - Montserrat Diéguez, Oscar Pàmies and Carmen Claver: Iridium-catalysed hydrogenation using phosphorous ligands. - David H. Woodmansee and Andreas Pfaltz: Iridium Catalyzed Asymmetric Hydrogenation of Olefins with Chiral N,P and C,N Ligands. - Ourida Saidi and Jonathan M J Williams: Iridium-catalyzed Hydrogen Transfer Reactions. - John F. Bower and Michael J. Krische: Formation of C-C Bonds via Iridium Catalyzed Hydrogenation and Transfer Hydrogenation. - Jongwook Choi, Alan S. Goldman: Ir-Catalyzed Functionalization of CH Bonds. - Mark P. Pouy and John F. Hartwig: Iridium-Catalyzed Allylic Substitution. - Daniel Carmona and Luis A. Oro: Iridium-catalyzed 1.3-dipolar cycloadditions.
Catalytic Cascade Reactions
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Author : Peng-Fei Xu
language : en
Publisher: John Wiley & Sons
Release Date : 2013-10-02
Catalytic Cascade Reactions written by Peng-Fei Xu and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-02 with Science categories.
Demonstrates the advantages of catalytic cascade reactions for synthesizing natural products and pharmaceuticals Riding the wave of green chemistry, catalytic cascade reactions have become one of the most active research areas in organic synthesis. During a cascade reaction, just one reaction solvent, one workup procedure, and one purification step are needed, thus significantly increasing synthetic efficiency. Featuring contributions from an international team of pioneers in the field, Catalytic Cascade Reactions demonstrates the versatility and application of these reactions for synthesizing valuable compounds. The book examines both organocatalysis and transition-metal catalysis reactions, bringing readers up to date with the latest discoveries and activities in all major areas of catalytic cascade reaction research. Catalytic Cascade Reactions begins with three chapters dedicated to organocatalytic cascade reactions, exploring amines, Brønsted acids, and the application of organocatalytic cascade reactions in natural product synthesis and drug discovery. Next, the book covers: Gold-catalyzed cascade reactions Cascade reactions catalyzed by ruthenium, iron, iridium, rhodium, and copper Palladium-catalyzed cascade reactions of alkenes, alkynes, and allenes Application of transition-metal catalyzed cascade reactions in natural product synthesis and drug discovery Engineering mono- and multifunctional nanocatalysts for cascade reactions Multiple-catalyst-promoted cascade reactions All chapters are thoroughly referenced, providing quick access to important original research findings and reviews so that readers can explore individual topics in greater depth. Drawing together and analyzing published findings scattered across the literature, this book provides a single source that encapsulates our current understanding of catalytic cascade processes. Moreover, it sets the stage for the development of new catalytic cascade reactions and their applications.
Catalysis Of Organic Reactions
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Author : Michael E. Ford
language : en
Publisher: CRC Press
Release Date : 2000-10-18
Catalysis Of Organic Reactions written by Michael E. Ford and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-10-18 with Science categories.
This volume documents developments in the study of catalysis relating to organic synthesis and its application in industrial processes. It surveys a wide range of homo- and heterogeneous catalysis for industrial and pharmaceutical chemicals. It covers enantioselective hydrogenation, catalyzed hydrogens and oxidation, carbonylation, hydroaminomethylation, and more.
Iridium Complexes As Highly Active Catalysts For Hydrogen Isotope Exchange And Hydrogen Borrowing Processes
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Author : Philippa Kate Owens
language : en
Publisher:
Release Date : 2018
Iridium Complexes As Highly Active Catalysts For Hydrogen Isotope Exchange And Hydrogen Borrowing Processes written by Philippa Kate Owens and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018 with categories.
Over the last several decades, the organic chemistry community has become increasingly reliant upon iridium catalysis, with applications reported across a number of research areas. In recent years, the Kerr group has developed a series of iridium complexes, which were found to be excellent catalysts for hydrogen isotope exchange and olefin hydrogenation processes. The work described within this thesis centres upon the expansion of these catalysts' reactivity in hydrogen isotope exchange, as well as the synthesis and application of a series of novel iridium complexes, designed for use in hydrogen borrowing catalysis. Chapter one focuses on the development of three efficient and selective methods for hydrogen isotope exchange. Iridium(I) catalysts previously developed within the group have been employed in the successful deuteration of N-heterocycles, which represent an important and relatively underexplored class of labelling substrates. The labelling of a large range of indole, pyrrole, and quinoline derivatives is reported, in which the regioselectivity can be controlled through careful choice of N-protecting group. Extensive practical and computational mechanistic investigations offered insight into the mechanism of indole C3 labelling, which is believed to proceed via an iridium-indoline intermediate. In chapter two, the design and synthesis of a series of novel unsymmetrical NHC ligands, functionalised with electron donating substituents, is described. The corresponding neutral iridium NHC/halide complexes were prepared, and the steric and electronic properties of the ligands were investigated using a number of techniques. These novel complexes were then tested in the catalysis of hydrogen borrowing processes. Extensive optimisation led to the development of an efficient method for the room-temperature N-alkylation of anilines. This methodology was also expanded to include the synthesis of N-heterocycles viaintramolecular C-N bond formation, albeit using more forcing conditions. Lastly, a small series of chiral NHC ligands was designed, and their corresponding iridium complexes prepared and used in a preliminary screening of asymmetric hydrogen borrowing.
Catalysis Of Organic Reactions
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Author : Frank E. Herkes
language : en
Publisher: CRC Press
Release Date : 1998-08-21
Catalysis Of Organic Reactions written by Frank E. Herkes and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998-08-21 with Science categories.
Documents up-to-date developments in the study of catalysis and its applications to organic synthesis and industrial processes. The text examines the area of homogenous and heterogenous catalysis for industrial and pharmaceutical chemicals, focusing on recent advances in asymmetric synthesis, environmental uses, acid-based synthesis, hydrogenation, oxidation, alkylation, isomerization, amination, hydroformlyation, and more.