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Laboratory Studies Of Heterogeneous Catalytic Processes


Laboratory Studies Of Heterogeneous Catalytic Processes
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Laboratory Studies Of Heterogeneous Catalytic Processes


Laboratory Studies Of Heterogeneous Catalytic Processes
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Author : Erhard G. Christoffel
language : en
Publisher:
Release Date : 1989

Laboratory Studies Of Heterogeneous Catalytic Processes written by Erhard G. Christoffel and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989 with categories.




Laboratory Studies Of Heterogeneous Catalytic Processes


Laboratory Studies Of Heterogeneous Catalytic Processes
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Author : E.G. Christoffel
language : en
Publisher: Elsevier
Release Date : 1989-01-01

Laboratory Studies Of Heterogeneous Catalytic Processes written by E.G. Christoffel and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989-01-01 with Technology & Engineering categories.


Providing a concise treatment of methods of heterogeneous catalysis used in the laboratory, this book describes the basic phenomena of heterogeneous catalytic reaction systems and discusses in detail the experimental methods and procedures for investigating these systems. The introductory chapter illustrates the whole procedure with an actual example. The next chapter presents the basic phenomena of catalytic systems and the concepts used in studying them. The third chapter covers the description of methods for investigating reaction mechanisms and the dynamics of heterogeneous catalytic reaction systems. The last chapter discusses the design and operation modes of laboratory reactors, frequently used for the investigation of heterogeneous catalytic reactions. The approach is interdisciplinary, providing a balance between chemical engineering and chemical viewpoints of treating laboratory-scale reactors. Chemists and chemical engineers involved in catalyst research will be very interested in this book and it can also be usefully used in specialized courses for graduate students in chemistry or in chemical reaction engineering.



Experiments In Catalytic Reaction Engineering


Experiments In Catalytic Reaction Engineering
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Author : J.M. Berty
language : en
Publisher: Elsevier
Release Date : 1999-08-11

Experiments In Catalytic Reaction Engineering written by J.M. Berty and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999-08-11 with Technology & Engineering categories.


The science of catalytic reaction engineering studies the catalyst and the catalytic process in the laboratory in order to predict how they will perform in production-scale reactors. Surprises are to be avoided in the scaleup of industrial processes. The laboratory results must account for flow, heat and mass transfer influences on reaction rate to be useful for scaleup. Calculated performance based on these results must also be useful to maximization of profit and safety and minimization of pollution. To this end, information on products as well as byproducts and heat produced must be generated. If a sufficiently large database of knowledge is produced, optimization studies will be possible later if economic conditions change. The field of reaction engineering required new tools. For kinetic and catalyst testing, the most successful of these tools was the internal recycle reactor. Studies in recycle reactors can be made under well-defined conditions of flow and associated transfer processes, and close to commercial operation. The recycle reactor eliminates or minimizes the effect of transfer process, and allows the remaining ones to be known. Features of this book: • Provides insight into a field that is neither well understood nor properly appreciated. • Gives a deeper understanding of reaction engineering practice. • Helps avoid frustration and disappointment in industrial research. This book is short and clear enough to assist all members of the R&D and Engineering team, whether reaction engineers, or specialists in other fields. This is critical in this new age of computation and communication, when team members must each know at least something of their colleagues' fields. Additionally, many scientists in more exploratory or fundamental fields can use recycle reactors to study basic phenomena free of transfer interactions.



Heterogeneous Catalytic Materials


Heterogeneous Catalytic Materials
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Author : Guido Busca
language : en
Publisher: Newnes
Release Date : 2014-05-23

Heterogeneous Catalytic Materials written by Guido Busca and has been published by Newnes this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-05-23 with Technology & Engineering categories.


Heterogeneous Catalytic Materials discusses experimental methods and the latest developments in three areas of research: heterogeneous catalysis; surface chemistry; and the chemistry of catalysts. Catalytic materials are those solids that allow the chemical reaction to occur efficiently and cost-effectively. This book provides you with all necessary information to synthesize, characterize, and relate the properties of a catalyst to its behavior, enabling you to select the appropriate catalyst for the process and reactor system. Oxides (used both as catalysts and as supports for catalysts), mixed and complex oxides and salts, halides, sulfides, carbides, and unsupported and supported metals are all considered. The book encompasses applications in industrial chemistry, refinery, petrochemistry, biomass conversion, energy production, and environmental protection technologies. Provides a systematic and clear approach of the synthesis, solid state chemistry and surface chemistry of all solid state catalysts Covers widely used instrumental techniques for catalyst characterization, such as x-ray photoelectron spectroscopy, scanning electron microscopy, and more Includes characterization methods and lists all catalytic behavior of the solid state catalysts Discusses new developments in nanocatalysts and their advantages over conventional catalysts



Theoretical Studies In Heterogenous Catalysis


Theoretical Studies In Heterogenous Catalysis
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Author :
language : en
Publisher:
Release Date : 2008

Theoretical Studies In Heterogenous Catalysis written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008 with categories.


Traditionally, knowledge in heterogeneous catalysis has come through empirical research. Nowadays, there is a clear interest to change this since millions of dollars in products are generated every year in the chemical and petrochemical industries through catalytic processes. To obtain a fundamental knowledge of the factors that determine the activity of heterogeneous catalysts is a challenge for modern science since many of these systems are very complex in nature. In principle, when a molecule adsorbs on the surface of a heterogeneous catalyst, it can interact with a large number of bonding sites. It is known that the chemical properties of these bonding sites depend strongly on the chemical environment around them. Thus, there can be big variations in chemical reactivity when going from one region to another in the surface of a heterogeneous catalyst. A main objective is to understand how the structural and electronic properties of a surface affect the energetics for adsorption processes and the paths for dissociation and chemical reactions. In recent years, advances in instrumentation and experimental procedures have allowed a large series of detailed works on the surface chemistry of heterogeneous catalysts. In many cases, these experimental studies have shown interesting and unique phenomena. Theory is needed to unravel the basic interactions behind these phenomena and to provide a general framework for the interpretation of experimental results. Ideally, theoretical calculations based on density-functional theory have evolved to the point that one should be able to predict patterns in the activity of catalytic surfaces. As in the case of experimental techniques, no single theoretical approach is able to address the large diversity of phenomena occurring on a catalyst. Catalytic surfaces are usually modeled using either a finite cluster or a two-dimensionally periodic slab. Many articles have been published comparing the results of these two approaches. An important advantage of the cluster approach is that one can use the whole spectrum of quantum-chemical methods developed for small molecules with relatively minor modifications. On the other hand, the numerical effort involved in cluster calculations increases rather quickly with the size of the cluster. This problem does not exist when using slab models. Due to the explicit incorporation of the periodicity of the crystal lattice through the Bloch theorem, the actual dimension of a slab calculation depends only on the size of the unit cell. In practical terms, the slab approach is mainly useful for investigating the behavior of adsorbates at medium and high coverages. Very large unit cells are required at the limit of low to zero coverage, or when examining the properties and chemical behavior of isolated defect sites in a surface. In these cases, from a computational viewpoint, the cluster approach can be much more cost effective than the slab approach. Slab and cluster calculations can be performed at different levels of sophistication: semi-empirical methods, simple ab initio Hartree-Fock, ab initio post-Hartree-Fock (CI, MP2, etc), and density functional theory. Density-functional (DF) based calculations frequently give adsorption geometries with a high degree of accuracy and predict reliable trends for the energetics of adsorption reactions. This article provides a review of recent theoretical studies that deal with the behavior of novel catalysts used for hydrodesulfurization (HDS) reactions and the production of hydrogen (i.e. catalytic processes employed in the generation of clean fuels). These studies involve a strong coupling of theory and experiment. A significant fraction of the review is focused on the importance of size-effects and correlations between the electronic and chemical properties of catalytic materials. The article begins with a discussion of results for the desulfurization of thiophene on metal carbides and phosphides, systems which have the potential to become the next generation of industrial HDS catalysts. Then, systematic studies concerned with the hydrogen-evolution reaction (HER) on extended surfaces, organometallic complexes and enzymes are presented. Finally, the reasons for the high catalytic activity of Au-CeO2 and Cu-CeO2 in the production of hydrogen through the water-gas shift reaction (CO + H2O --> H2 + CO2) are analyzed. It is shown that theoretical methods are very valuable tools for helping in the rational design of heterogeneous catalysts.



Heterogeneous And Liquid Phase Processes


Heterogeneous And Liquid Phase Processes
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Author : Peter Warneck
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Heterogeneous And Liquid Phase Processes written by Peter Warneck and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


The "European Experiment on the Transport and Transformation of Environmentally Relevant Trace Constituents over Europe" (EUROTRAC) was established in 1986 to tackle the scientific problem and combine the expertise, knowledge and resources in Europe, in order to apply them over a large region covering the greater part of the continent. EUROTRAC is a coordinated multidisciplinary scientific research project involving field measurements, laboratory studies, instrument development and development of comprehensive computer models for the simulation of the physical and chemical processes in the lower atmosphere.



The Development Of Catalysis


The Development Of Catalysis
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Author : Adriano Zecchina
language : en
Publisher: John Wiley & Sons
Release Date : 2017-04-03

The Development Of Catalysis written by Adriano Zecchina and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-04-03 with Science categories.


This book gradually brings the reader, through illustrations of the most crucial discoveries, into the modern world of chemical catalysis. Readers and experts will better understand the enormous influence that catalysis has given to the development of modern societies. • Highlights the field's onset up to its modern days, covering the life and achievements of luminaries of the catalytic era • Appeals to general audience in interpretation and analysis, but preserves the precision and clarity of a scientific approach • Fills the gap in publications that cover the history of specific catalytic processes



Heterogeneous Catalysis At Nanoscale For Energy Applications


Heterogeneous Catalysis At Nanoscale For Energy Applications
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Author : Franklin Tao
language : en
Publisher: John Wiley & Sons
Release Date : 2015-02-09

Heterogeneous Catalysis At Nanoscale For Energy Applications written by Franklin Tao and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-02-09 with Science categories.


This book presents both the fundamentals concepts and latest achievements of a field that is growing in importance since it represents a possible solution for global energy problems. It focuses on an atomic-level understanding of heterogeneous catalysis involved in important energy conversion processes. It presents a concise picture for the entire area of heterogeneous catalysis with vision at the atomic- and nano- scales, from synthesis, ex-situ and in-situ characterization, catalytic activity and selectivity, to mechanistic understanding based on experimental exploration and theoretical simulation. The book: Addresses heterogeneous catalysis, one of the crucial technologies employed within the chemical and energy industries Presents the recent advances in the synthesis and characterization of nanocatalysts as well as a mechanistic understanding of catalysis at atomic level for important processes of energy conversion Provides a foundation for the potential design of revolutionarily new technical catalysts and thus the further development of efficient technologies for the global energy economy Includes both theoretical studies and experimental exploration Is useful as both a textbook for graduate and undergraduate students and a reference book for scientists and engineers in chemistry, materials science, and chemical engineering



Heterogeneous Catalysis For Energy Applications


Heterogeneous Catalysis For Energy Applications
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Author : Tomas R Reina
language : en
Publisher: Royal Society of Chemistry
Release Date : 2020-08-27

Heterogeneous Catalysis For Energy Applications written by Tomas R Reina and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-08-27 with Science categories.


Heterogeneous catalysis plays a central role in the global energy paradigm, with practically all energy-related process relying on a catalyst at a certain point. The application of heterogeneous catalysts will be of paramount importance to achieve the transition towards low carbon and sustainable societies. This book provides an overview of the design, limitations and challenges of heterogeneous catalysts for energy applications. In an attempt to cover a broad spectrum of scenarios, the book considers traditional processes linked to fossil fuels such as reforming and hydrocracking, as well as catalysis for sustainable energy applications such as hydrogen production, photocatalysis, biomass upgrading and conversion of CO2 to clean fuels. Novel approaches in catalysts design are covered, including microchannel reactors and structured catalysts, catalytic membranes and ionic liquids. With contributions from leaders in the field, Heterogeneous Catalysis for Energy Applications will be an essential toolkit for chemists, physicists, chemical engineers and industrials working on energy.



Heterogeneous Catalysis


Heterogeneous Catalysis
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Author : Giovanni Palmisano
language : en
Publisher: Elsevier
Release Date : 2022-01-08

Heterogeneous Catalysis written by Giovanni Palmisano and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-01-08 with Technology & Engineering categories.


Approx.320 pages Approx.320 pages