Main Group Metals In Organic Synthesis
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Main Group Metals In Organic Synthesis
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Author : Hisashi Yamamoto
language : en
Publisher: John Wiley & Sons
Release Date : 2006-03-06
Main Group Metals In Organic Synthesis written by Hisashi Yamamoto and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-03-06 with Science categories.
This is the first handbook to cover in detail all aspects of this fascinating field of chemistry. In this handy two-volume set, readers will instantly find the information they need, clearly structured according to the individual metals in the main groups, hitherto only accessible after much time-consuming research. The result is in indispensable aid for everyday work in the lab. Alongside all the classical organic reactions, this book focuses on the modern variations as well as novel, current reactions in organic synthesis that are closely linked to main group elements - both stoechiometric and catalytic. With this work the two prizewinning editors have succeeded in producing a comprehensive compendium of the main group metals as reagents for organic reactions. In short, this is a must for every organic chemist, whether as an efficient introduction to current research, for retaining an overview or for looking up detailed information.
Organometallics In Organic Synthesis
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Author : Ei-ichi Negishi
language : en
Publisher: Wiley
Release Date : 1980-04-25
Organometallics In Organic Synthesis written by Ei-ichi Negishi and has been published by Wiley this book supported file pdf, txt, epub, kindle and other format this book has been release on 1980-04-25 with Science categories.
Bridges the gap between the typical organic and organometallic texts by providing a current overall description of the chemistry of organometallics in organic synthesis in a digested form. Offers a highly systematic and logical account of virtually all the important aspects of the use of organometallics in organic synthesis. Primarily treats the reactant-product relationship, as well as some tentative but reasonable interpretations provided by the authors of individual papers and the author of this book. Over 1,200 references are cited, along with the great majority of relevant reviews and monographs.
Early Main Group Metal Catalysis
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Author : Sjoerd Harder
language : en
Publisher: John Wiley & Sons
Release Date : 2020-04-06
Early Main Group Metal Catalysis written by Sjoerd Harder and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-04-06 with Technology & Engineering categories.
Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.
Transition Metals In The Synthesis Of Complex Organic Molecules
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Author : Louis S. Hegedus
language : en
Publisher: University Science Books
Release Date : 1994
Transition Metals In The Synthesis Of Complex Organic Molecules written by Louis S. Hegedus and has been published by University Science Books this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994 with Organic compounds categories.
A text for use in a one-semester course for upper-level students familiar with basic organic chemistry, or as a survey course for practicing organic chemists. Chapters 1 and 2 present a brief overview of the formalisms and mechanisms required to understand the processes discussed in chapters 3-10, which deal with the application of transition metal organometallic chemistry to organic synthesis with specific attention to applications with complex molecules. Updates and expands chapters 13-20 of Principles and Applications of Organotransition Metal Chemistry, 2nd ed. (1987). Published by University Science Books, 20 Edgehill Rd., Mill Valley, CA 94941. Annotation copyright by Book News, Inc., Portland, OR
Organotransition Metals In Organic Synthesis
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Author : Sugata Chatterjee
language : en
Publisher: Elsevier
Release Date : 2020-12-15
Organotransition Metals In Organic Synthesis written by Sugata Chatterjee and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-12-15 with Science categories.
Organotransition Metals in Organic Synthesis: Fundamentals and Applications provides a fundamental understanding on how to use transition and main group metals to synthesize simple and complex molecules with a high degree of selectivity. This book details the basic concepts, elementary reactions, and latest developments of organometallic chemistry surrounding the transition metals. Topics covered include electronic configuration and structural, methods for carbon-transition metal bond creation, cleavage of metal-carbon bonds to form new carbon-carbon bonds, chemo-, region-, stereo- and enantio- control, and heterogeneous organometallic reactions. This book is an ideal resource for researchers and students working with metals in organic synthesis and organometallic chemistry, including those having no prior exposure to organometallic chemistry in synthesis. Includes extensive coverage of methods for creating carbon-transition metal bonds, such as oxidative addition, oxidative coupling, hydro and carbometallation, carbonyl insertion, transmetallation and metal carbenes and metathesis Ideal for students and researchers new to the pharmaceutical industry or organometallic chemistry in general, covering foundational information as well as select advanced applications Covers metals in organic synthesis, unprecedented selectivity, clean reactions, mild conditions, high yields, along with improvisation methods for existing synthesis methods
Organic Synthesis Using Transition Metals
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Author : Roderick Bates
language : en
Publisher: John Wiley & Sons
Release Date : 2012-04-12
Organic Synthesis Using Transition Metals written by Roderick Bates and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-04-12 with Science categories.
Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.
Organometallic Chemistry
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Author : Shay Beck
language : en
Publisher: Scientific e-Resources
Release Date : 2019-09-06
Organometallic Chemistry written by Shay Beck and has been published by Scientific e-Resources this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-09-06 with categories.
Organometallic Chemistry is the study of chemical compounds containing bonds between carbon and metal. The term "e;Metal"e; is defined deliberately broadly in this context and may include elements, such as silicon or boron, which are not metallic but are considered to be metalloids. Almost all branches of chemistry and material science now interface with organometallic chemistry. Organometallics find practical uses in stoichiometric and catalytic processes, especially processes involving carbon monoxide and alkene-derived polymers. Organometallic (OM) chemistry is the study of compounds containing, and reactions involving, metal-carbon bonds. The metal-carbon bond may be transient or temporary, but if one exists during a reaction or in a compound of interest, we're squarely in the domain of organometallic chemistry. Despite the denotational importance of the M-C bond, bonds between metals and the other common elements of organic chemistry also appear in OM chemistry: metal-nitrogen, metal-oxygen, metal-halogen, and even metal-hydrogen bonds all play a role. Metals cover a vast swath of the periodic table and include the alkali metals (group 1), alkali earth metals (group 2), transition metals (groups 3-12), the main group metals (groups 13-15, "e;under the stairs"e;), and the lanthanides and actinides. The principal idea of this book is to offer a comprehensive coverage of unconventional and thought-provoking topics in organometallic chemistry. It also supplies practical information about reaction mechanisms, along with the descriptions of contemporary applications to organic synthesis, organized by mechanism and kinetic. It will serve as a valuable reference tool for students and professional of organic and post organic chemistry, who need to become better acquainted with the subject.
Organometallic Chemistry Of The Transition Elements
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Author : Florian P. Pruchnik
language : en
Publisher: Springer Science & Business Media
Release Date : 1990-09-30
Organometallic Chemistry Of The Transition Elements written by Florian P. Pruchnik and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990-09-30 with Science categories.
Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.
Main Group Metal Organometallics In Organic Synthesis
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Author : A. McKillop
language : en
Publisher: Elsevier
Release Date : 2004-09-16
Main Group Metal Organometallics In Organic Synthesis written by A. McKillop and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-09-16 with Science categories.
The individual chapters in this volume cover the scope and impact of main group organometallic compounds and reagents on organic synthesis during the last ten to fifteen years. In a number of chapters, topics are dealt with in detail that either were not covered at all in COMC (eg selenium, tellurium) or were given scant attention (eg oxymercuration, organoantimony compounds). Certain topics, like directed metallation and LiKOR bases have only achieved prominence in synthesis in the last ten years, and are now reviewed by leading experts.
Metal Promoted Selectivity In Organic Synthesis
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Author : A. Noels
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Metal Promoted Selectivity In Organic Synthesis written by A. Noels and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The demand for selective organic reactions is growing more acute everyday. Indeed, greater product selectivity has an important impact on energy and resource utilization, in terms of reduced process energy requirements for product separation and purification, in terms of low-value by-products, and in terms of environmental acceptance and compatibility. Moreover, more and more chemicals, especially pharmaceuticals, have to be sold in an optically active form. The search for selectivity constitutes a tremendous challenge for the chemists. In the last two decades, homogeneous transition metal based catalysis has emerged as one of the most promising tools for obtaining selectivity. In connection with developments in this area, this book contains updated and expanded versions of most of the lectures presented at a Cornett course held in Trieste (Italy) in 1989 and sponsored by the European Community. A primary aim is to cultivate a deeper understanding of the parameters that govern the selectivities and stimulate a wider utilization of transition metal based catalysis in organic synthesis. All aspects of selectivity, chemo-, regio-, stereo- and enantioselectivity are considered and illustrated by applications in various fields or organic synthesis. The impact of catalysis in oxydation, reduction, carbonylation reactions, carbene chemistry, in Ni and Pd promoted dimerizations, oligomerizations as well as fonctionalisations is stressed, quite often with special emphasis laid on reaction mechanisms. In this aspect, the last chapter examplifies the interest of high pressure NMR and IR when investigating the nature of reaction intermediates in homogeneous reactions.