Making And Breaking Symmetry In Chemistry

DOWNLOAD

Download Making And Breaking Symmetry In Chemistry PDF/ePub or read online books in Mobi eBooks. Click Download or Read Online button to get Making And Breaking Symmetry In Chemistry book now. This website allows unlimited access to, at the time of writing, more than 1.5 million titles, including hundreds of thousands of titles in various foreign languages. If the content not found or just blank you must refresh this page

Making And Breaking Symmetry In Chemistry Syntheses Mechanisms And Molecular Rearrangements

DOWNLOAD
Author : Michael James Mcglinchey
language : en
Publisher: World Scientific
Release Date : 2022-03-09

Making And Breaking Symmetry In Chemistry Syntheses Mechanisms And Molecular Rearrangements written by Michael James Mcglinchey and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-03-09 with Science categories.

The elucidation of reaction mechanisms generally requires the carefully designed control of molecular symmetry to distinguish between the many possible reaction pathways. Making and Breaking Symmetry in Chemistry emphasises the crucial role played by symmetry in modern synthetic chemistry. After discussion of a number of famous classical experiments, the advances brought about by the introduction of new techniques, in particular NMR spectroscopy, are exemplified in numerous cases taken from the recent literature. Experimental verification of many of the predictions made in Woodward and Hoffmann's explication of the Conservation of Orbital Symmetry are described. Applications that involve the breaking of molecular symmetry to resolve these and other mechanistic problems in organic, inorganic and organometallic chemistry are presented in the first sections of the book, together with many examples of the detection of hitherto hidden rearrangement processes.Subsequently, under the aegis of making molecular symmetry, examples of the preparation of highly symmetrical molecules found in the organic, organometallic or inorganic domains are discussed. These include Platonic hydrocarbons or boranes, tetrahedranes, cubanes, prismanes, dodecahedrane, fullerene fragments such as corannulene, sumanene or semibuckminsterfullerene, and other systems of unusual geometries or bonding characteristics (Möbius strips, molecular brakes and gears, Chauvin's carbomers, Fitjer's rotanes, persubstituted rings, metal-metal multiple bonds, etc.). The text also contains vignettes of many of the scientists who made these major advances, as well as short sections that briefly summarise key features of important topics that underpin the more descriptive material. These include some aspects of chirality, NMR spectroscopy, and the use of isotopic substitution to break molecular symmetry. A brief appendix on point group symmetry and nomenclature is also helpfully provided.

Symmetry Group Theory And Mathematical Treatment In Chemistry

DOWNLOAD
Author : Takashiro Akitsu
language : en
Publisher: BoD – Books on Demand
Release Date : 2018-07-18

Symmetry Group Theory And Mathematical Treatment In Chemistry written by Takashiro Akitsu and has been published by BoD – Books on Demand this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-07-18 with Science categories.

The aim of this book Symmetry (Group Theory) and Mathematical Treatment in Chemistry is to be a graduate school-level text about introducing recent research examples associated with symmetry (group theory) and mathematical treatment in inorganic or organic chemistry, physical chemistry or chemical physics, and theoretical chemistry. Chapters contained can be classified into mini-review, tutorial review, or original research chapters of mathematical treatment in chemistry with brief explanation of related mathematical theories. Keywords are symmetry, group theory, crystallography, solid state, topology, molecular structure, electronic state, quantum chemistry, theoretical chemistry, and DFT calculations.

Encyclopedia Of Chemical Physics And Physical Chemistry Applications

DOWNLOAD
Author : Nicholas D. Spencer
language : en
Publisher: Taylor & Francis
Release Date : 2001

Encyclopedia Of Chemical Physics And Physical Chemistry Applications written by Nicholas D. Spencer and has been published by Taylor & Francis this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001 with Chemistry, Physical and theoretical categories.

The New Chemistry

DOWNLOAD
Author : Nina Hall
language : en
Publisher: Cambridge University Press
Release Date : 2000-11-16

The New Chemistry written by Nina Hall and has been published by Cambridge University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-11-16 with Science categories.

The New Chemistry is a unique and fascinating book - a showcase for modern chemistry. It highlights the most important developments in chemistry over the past 30 years, covering the latest research trends in a wide range of fields, both theoretical and experimental. The book consists of 17 self-contained chapters, each covering a different topic in chemistry, ranging from the discovery of new elements and synthetic techniques to the design of drugs and materials, and each written by one of the world's leading chemists in that particular field. It includes contributions from several Nobel Prize winners and is copiously illustrated with photographs and explanatory diagrams. Written in a lively and accessible style, this book will be of interest to scientists of all disciplines and will be useful as a reference text for anyone wanting to know more about modern chemistry.

Symmetry In Science

DOWNLOAD
Author : Joseph Rosen
language : en
Publisher: Springer
Release Date : 1996-10-25

Symmetry In Science written by Joseph Rosen and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-10-25 with Science categories.

Symmetry plays an essential role in science - not only in crystallography and quantum theory, where its role has long been explicitly recognized, but also in condensed-matter physics, thermodynamics, chemistry, biology, and others. This text discusses the concept of symmetry and its application to many areas of science. While it includes a detailed introduction to the theory of groups, which forms the mathematical apparatus for describing symmetries, it also includes a much more general discussion of the nature of symmetry and its role in science. Many problems serve to sharpen the reader's understanding, and an extensive bibliography concludes the book.

Advances In Quantum Chemistry

DOWNLOAD
Author : John R. Sabin
language : en
Publisher: Elsevier
Release Date : 2005-12-20

Advances In Quantum Chemistry written by John R. Sabin and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2005-12-20 with Science categories.

Advances in Quantum Chemistry presents surveys of current developments in this rapidly developing field that falls between the historically established areas of mathematics, physics, chemistry, and biology. With invited reviews written by leading international researchers, each presenting new results, it provides a single vehicle for following progress in this interdisciplinary area. This volume continues the tradition with high quality and thorough reviews of various aspects of quantum chemistry. It contains a variety of topics that include an extended and in depth discussion on the calculation of analytical first derivatives of the energy in a similarity transformed equation of motion couples cluster method.

Asymmetry In Biological Homochirality

DOWNLOAD
Author : David Hochberg
language : en
Publisher: MDPI
Release Date : 2021-06-04

Asymmetry In Biological Homochirality written by David Hochberg and has been published by MDPI this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-06-04 with Science categories.

Chirality, or handedness, is a fundamental physical characteristic, which spans the length scales ranging from elementary particles to the chiral asymmetry of spiral galaxies. The way in which chirality in chemistry, or molecular handedness, may have emerged in a primitive terrestrial environment, and how it can be triggered, amplified, and transferred, are deeply challenging problems rooted in both fundamental scientific interests and the technological potentials for science and society. Chirality constitutes a unifying feature of the living world and is a prime driving force for molecular selection and genetic evolution in biology. In this book, we offer a selection of five distinct approaches to this problem by leading experts in the field. The selected topics range from protein chirality and its relevance to protein ageing, protein aggregation and neurodegeneration, entropy production associated with chiral symmetry breaking in closed systems, chiral oscillations in polymerization models involving higher-order oligomers, the mirror symmetry breaking in liquids and its implications for the development of homochirality in abiogenesis, the role of chirality in the chemical sciences, and some philosophical implications of chirality.

Philosophy Of Chemistry

DOWNLOAD
Author : Eric Scerri
language : en
Publisher: Springer
Release Date : 2014-11-11

Philosophy Of Chemistry written by Eric Scerri and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-11-11 with Science categories.

This volume follows the successful book, which has helped to introduce and spread the Philosophy of Chemistry to a wider audience of philosophers, historians, science educators as well as chemists, physicists and biologists. The introduction summarizes the way in which the field has developed in the ten years since the previous volume was conceived and introduces several new authors who did not contribute to the first edition. The editors are well placed to assemble this book, as they are the editor in chief and deputy editors of the leading academic journal in the field, Foundations of Chemistry. The philosophy of chemistry remains a somewhat neglected field, unlike the philosophy of physics and the philosophy of biology. Why there has been little philosophical attention to the central discipline of chemistry among the three natural sciences is a theme that is explored by several of the contributors. This volume will do a great deal to redress this imbalance. Among the themes covered is the question of reduction of chemistry to physics, the reduction of biology to chemistry, whether true chemical laws exist and causality in chemistry. In addition more general questions of the nature of organic chemistry, biochemistry and chemical synthesis are examined by specialist in these areas.

Properties Of Materials

DOWNLOAD
Author : Robert E. Newnham
language : en
Publisher: OUP Oxford
Release Date : 2004-11-12

Properties Of Materials written by Robert E. Newnham and has been published by OUP Oxford this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-11-12 with Science categories.

Crystals are sometimes called 'Flowers of the Mineral Kingdom'. In addition to their great beauty, crystals and other textured materials are enormously useful in electronics, optics, acoustics, and many other engineering applications. This book describes the underlying principles of crystal physics and chemistry, covering a wide range of topics, and illustrating numerous applications in many fields of engineering using the most important materials. It has been written at a level suitable for science and engineering students and can be used for teaching a one- or two-semester course. Tensors, matrices, symmetry and structure-property relationships form the main subjects of the book. Whilst tensors and matrices provide the mathematical framework for understanding anisotropy, on which the physical and chemical properties of crystals and textured materials often depend, atomistic arguments are also needed to quantify the property coefficients in various directions. The atomistic arguments are partly based on symmetry and partly on the basic physics and chemistry of materials. After introducing the point groups appropriate for single crystals, textured materials and ordered magnetic structures, the directional properties of many different materials are described: linear and nonlinear elasticity, piezoelectricity and electrostriction, magnetic phenomena, diffusion and other transport properties, and both primary and secondary ferroic behaviour. With crystal optics (its roots in classical mineralogy) having become an important component of the information age, nonlinear optics is described along with the piezo-optics, magneto-optics and electro-optics, and analogous linear and nonlinear acoustic wave phenomena. Enantiomorphism, optical activity, and chemical anisotropy are discussed in the final chapters of the book.

Symmetry Spectroscopy And Crystallography

DOWNLOAD
Author : Robert Glaser
language : en
Publisher: John Wiley & Sons
Release Date : 2015-10-05

Symmetry Spectroscopy And Crystallography written by Robert Glaser and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-10-05 with Science categories.

Written in a clear and understandable manner, this book provides a comprehensive, yet non-mathematical, treatment of the topic, covering the basic principles of symmetry and the important spectroscopic techniques used to probe molecular structure. The chapters are extensively illustrated and deal with such topics as symmetry elements, operations and descriptors, symmetry guidelines, high-fidelity pseudosymmetry, crystallographic symmetry, molecular gears, and experimental techniques, including X-ray crystallography and NMR spectroscopy. As an additional feature, 3D animations of most of the structures and molecules covered are available online at wiley.com. As a result, chemists learn how to understand and predict molecular structures and reactivity. Authored by a renowned expert with numerous publications and an excellent track record in research and teaching, this is a useful source for graduate students and researchers working in the field of organic synthesis, physical chemistry, biochemistry, and crystallography, while equally serving as supplementary reading for courses on stereochemistry, organic synthesis, or crystallography.