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Methane Activation And Utilization In The Petrochemical And Biofuel Industries


Methane Activation And Utilization In The Petrochemical And Biofuel Industries
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Methane Activation And Utilization In The Petrochemical And Biofuel Industries


Methane Activation And Utilization In The Petrochemical And Biofuel Industries
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Author : Hua Song
language : en
Publisher: Springer Nature
Release Date : 2021-11-15

Methane Activation And Utilization In The Petrochemical And Biofuel Industries written by Hua Song and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-11-15 with Technology & Engineering categories.


This book discusses effective and alternative uses for natural gas (NG) and highlights the utilization of NG in the field of methane activation and chemical production. It details the techniques used during the reforming process of petrochemical and bio-derived fuels and it presents cutting-edge research that describes the utilization of NG that enables it to be more cost-effective and eliminate the expensive greenhouse gas emitting process of hydrogen production. The book addresses three major topics: NG use in upstream heavy oil and bitumen upgrading, NG and its use in downstream oil refining through co-aromatization of various feeds in the petrochemical industry, and NG use in the upgrading of bio-derived fuels and discusses alternative uses of NG. In-depth chapters demonstrate uses for NG beyond heating homes, through catalysis and in-situ hydrogen donation, and its potential applications for the petrochemical and biofuel industries.



Colloidal Design Of Active Selective And Stable Catalysts For Methane Utilization


Colloidal Design Of Active Selective And Stable Catalysts For Methane Utilization
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Author : Emmett Daniel Goodman
language : en
Publisher:
Release Date : 2020

Colloidal Design Of Active Selective And Stable Catalysts For Methane Utilization written by Emmett Daniel Goodman and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020 with categories.


Due to recent advances in locating and extracting natural gas resources, scientists in academia and industry are looking for new processes to take advantage of methane as a chemical precursor and fuel. However, there remain significant challenges in methane utilization; these are related to the strength of methane's carbon-hydrogen bonds, which makes this molecule difficult to activate and utilize. Without a catalyst, methane activation necessitates very high temperatures (~1000 oC), which lead to high energy costs, advanced infrastructure, toxic by-products, and poor product selectivity. Our work focuses on developing catalysts with well-defined structural properties to understand what makes materials active, selective, and stable for methane transformations. To understand which specific nanostructures are best for methane activation, size- and composition- controlled Pt/Pd nanocrystals were designed and studied to reveal the effect of catalyst structure on methane activation. Here, we discuss the effect of these unexplored parameters on methane activation rates, resistance to common catalytic poisons, and changes in oxidation state -- each of which has an important role in contributing to low-temperature activity. Perhaps the greatest challenge in methane activation is selective product formation. In this area, we studied how tuning catalyst support can help selectively produce valuable products (synthesis gas) rather than typical combustion products (carbon dioxide and water). Additionally, we started looking at even more unique nanostructures, involving both organic and inorganic components, for selective methane transformations. The high temperatures needed to activate methane require stable catalysts. By taking advantage of modular colloidal catalyst assembly, we demonstrated synthetic approaches to tune, and measure, the spatial properties of nanocrystal active sites. We found that in many conditions, the spatial properties of active sites determined catalyst stability. In Pd/Al2O3 materials we observed that closer nanocrystals are more stable, in a distant-dependent degradation process. However, in Pd/SiO2 materials we found the opposite - that stability properties are largely distant-independent. Overall, by developing colloidal approaches to catalyst synthesis, we created well-defined catalysts with precisely-controlled sizes, compositions, and spatial properties, which have helped us uncover important design rules for active, selective, and stable methane transformations.



Methane To Liquid Fuels And Chemicals A Catalytic Approach To Energy Sustainability And Green Chemistry


Methane To Liquid Fuels And Chemicals A Catalytic Approach To Energy Sustainability And Green Chemistry
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Author : Kissa Rajif Alunga
language : de
Publisher:
Release Date : 2014-11-26

Methane To Liquid Fuels And Chemicals A Catalytic Approach To Energy Sustainability And Green Chemistry written by Kissa Rajif Alunga and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-11-26 with categories.


Scholarly Research paper from the year 2014 in the subject Chemistry - Organic Chemistry, Xiamen University, language: English, abstract: Methane is considered to be an alternative for crude oil in the production of petrochemicals and clean liquid fuels. It is the most abundant energy resource ever discovered in the history of petrochemical industry, often found in remote regions and serves as a feedstock for the production of chemicals and source of energy in the 21st century. Although methane is currently being used in such important applications, its potential for the production of products such as ethylene or liquid hydrocarbon fuels has not been fully realized. A number of catalytic strategies are being explored to effectively transform methane into vital products whilst considering environmental impacts, these strategies include: steam and carbon dioxide reforming, partial oxidation of methane to form CO and H2, the direct oxidation of methane to methanol and formaldehyde, oxidative coupling of methane to ethylene and direct conversion to aromatics. Extensive utilization of methane for the production of fuels and chemicals appears to be near, but current economic uncertainties and technological associated challenges limit the amount of research activity and the implementation of emerging technologies.



Gaseous Carbon Waste Streams Utilization


Gaseous Carbon Waste Streams Utilization
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Author : National Academies of Sciences, Engineering, and Medicine
language : en
Publisher: National Academies Press
Release Date : 2019-02-22

Gaseous Carbon Waste Streams Utilization written by National Academies of Sciences, Engineering, and Medicine and has been published by National Academies Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-02-22 with Science categories.


In the quest to mitigate the buildup of greenhouse gases in Earth's atmosphere, researchers and policymakers have increasingly turned their attention to techniques for capturing greenhouse gases such as carbon dioxide and methane, either from the locations where they are emitted or directly from the atmosphere. Once captured, these gases can be stored or put to use. While both carbon storage and carbon utilization have costs, utilization offers the opportunity to recover some of the cost and even generate economic value. While current carbon utilization projects operate at a relatively small scale, some estimates suggest the market for waste carbon-derived products could grow to hundreds of billions of dollars within a few decades, utilizing several thousand teragrams of waste carbon gases per year. Gaseous Carbon Waste Streams Utilization: Status and Research Needs assesses research and development needs relevant to understanding and improving the commercial viability of waste carbon utilization technologies and defines a research agenda to address key challenges. The report is intended to help inform decision making surrounding the development and deployment of waste carbon utilization technologies under a variety of circumstances, whether motivated by a goal to improve processes for making carbon-based products, to generate revenue, or to achieve environmental goals.



Green Carbon Dioxide


Green Carbon Dioxide
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Author : Gabriele Centi
language : en
Publisher: John Wiley & Sons
Release Date : 2014-01-17

Green Carbon Dioxide written by Gabriele Centi and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-01-17 with Technology & Engineering categories.


PROMISING NEW APPROACHES TO RECYCLE CARBON DIOXIDE AND REDUCE EMISSIONS With this book as their guide, readers will learn a variety of new approaches and methods to recycle and reuse carbon dioxide (CO2) in order to produce green fuels and chemicals and, at the same time, minimize CO2 emissions. The authors demonstrate how to convert CO2 into a broad range of essential products by using alternative green energy sources, such as solar, wind, and hydro-power as well as sustainable energy sources. Readers will discover that CO2 can be a driving force for the sustainable future of both the chemical industry and the energy and fuels industry. Green Carbon Dioxide features a team of expert authors, offering perspectives on the latest breakthroughs in CO2 recycling from Asia, Europe, and North America. The book begins with an introduction to the production of CO2-based fuels and chemicals. Next, it covers such topics as: Transformation of CO2 to useable products through free-radical-induced reactions Hydrogenation of CO2 to liquid fuels Direct synthesis of organic carbonates from CO2 and alcohols using heterogeneous oxide catalysts Electrocatalytic reduction of CO2 in methanol medium Fuel production from photocatalytic reduction of CO2 with water using TiO2-based nanocomposites Use of CO2 in enhanced oil recovery and carbon capture and sequestration More than 1,000 references enable readers to explore individual topics in greater depth. Green Carbon Dioxide offers engineers, chemists, and managers in the chemical and energy and fuel industries a remarkable new perspective, demonstrating how CO2 can play a significant role in the development of a sustainable Earth.



Fischer Tropsch Technology


Fischer Tropsch Technology
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Author : André Steynberg
language : en
Publisher: Elsevier
Release Date : 2004-10-30

Fischer Tropsch Technology written by André Steynberg and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-10-30 with Technology & Engineering categories.


Fischer-Tropsch Technology is a unique book for its state-of-the-art approach to Fischer Tropsch (FT) technology. This book provides an explanation of the basic principles and terminology that are required to understand the application of FT technology. It also contains comprehensive references to patents and previous publications. As the first publication to focus on theory and application, it is a contemporary reference source for students studying chemistry and chemical engineering. Researchers and engineers active in the development of FT technology will also find this book an invaluable source of information. * Is the first publication to cover the theory and application for modern Fischer Tropsch technology * Contains comprehensive knowledge on all aspects relevant to the application of Fischer Tropsch technology* No other publication looks at past, present and future applications



Fundamentals Of Thermochemical Biomass Conversion


Fundamentals Of Thermochemical Biomass Conversion
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Author : R.P. Overend
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Fundamentals Of Thermochemical Biomass Conversion written by R.P. Overend and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


Throughout the world many projects have been underway to investigate the conversion of renewable biomass into energy and synthetic fuels by thermo chemical methods such as combustion, pyrolysis, gasification and lique faction. While many of these represent prior art used during the early 20th century, the recent decade since the 1970s oil shock has immeasurably increased the knowledge base for such processes. Much of the new knowledge has been gained by persons who were not trained in classical wood chemistry and there have not yet been many attempts to synthesize the knowledge into a corpus of systematic information. To bring this about the International Energy Agency's Forestry Energy collaboration, the Gas Research Institute, the National Research Council of Canada and the US Department of Energy jointly sponsored a conference on the Fundamentals of Thermochemical Biomass Conversion in Estes Park, Colorado which was held on October 18-22, 1982. The Conference, which was structured around invited plenary papers and contributions from researchers, served as the basis for the papers in this volume which reflect the substantial conclusions of the Conference. During the planning for the Conference, it was realized by the editors in their capacity as Co-chairmen that a major problem in biomass research was the lack of reproducibility between reported experiments and their inter comparison on account of the heterogeneity of biomass materials. A well known wood chemist, George M.



Biomass Utilization


Biomass Utilization
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Author : Wilfred Cote
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-12-01

Biomass Utilization written by Wilfred Cote and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-12-01 with Science categories.


This proceedings volume represents the culmination of nearly three years of planning, organizing and carrying out of a NATO Ad vanced Study Institute on Biomass Utilization. The effort was initi ated by Dr. Harry Sobel, then Editor of Biosources Digest, and a steering committee representing the many disciplines that this field brings together. . When the fiscal and logistical details of the original plan could not be worked out, the idea was temporarily suspended. In the spring of 1982, the Renewable Materials Institute of the State University of New York at the College of Environmental Science and Forestry in Syracuse, New York revived the plan. A number of modifications had to be made, including the venue which was changed from the U.S.A. to Portugal. Additional funding beyond the basic support provided by the Scientific Affairs Division of NATO had to be obtained. Ul timately there were supplementary grants from the Foundation for Microbiology and the Anne S. Richardson Fund to assist student participants. The New York State College of Forestry Foundation, Inc. provided major support through the Renewable Ma terials Institute. The ASI was held in Alcabideche, Portugal from September 26 to October 9, 1982. Eighty participants including fifteen principal lecturers were assembled at the Hotel Sintra Estoril for the program that was organized as a comprehensive course on biomass utilization. The main lectures were supplemented by relevant short papers offered by the participants.



Natural Gas Conversion Vi


Natural Gas Conversion Vi
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Author : T.H. Fleisch
language : en
Publisher: Elsevier
Release Date : 2001-06-01

Natural Gas Conversion Vi written by T.H. Fleisch and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001-06-01 with Technology & Engineering categories.


This volume contains peer-reviewed manuscripts describing the scientific and technological advances presented at the 6th Natural Gas Conversion Sumposium held in Alaska in June 2001. This symposium continues the tradition of excellence and the status as the premier technical meeting in this area established by previous meetings. The 6th Natural Gas Conversion Symposium is conducted under the overall direction of the Organizing Committee. The Program Committee was responsible for the review, selection, editing of most of the manuscripts included in this volum. A standing International Advisory Board has ensured the effective long-term planning and the continuity and technical excellence of these meetings.



Fundamentals Of Petroleum Refining


Fundamentals Of Petroleum Refining
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Author : Mohamed A. Fahim
language : en
Publisher: Elsevier
Release Date : 2009-11-19

Fundamentals Of Petroleum Refining written by Mohamed A. Fahim and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-11-19 with Technology & Engineering categories.


Fundamentals of Petroleum Refining presents the fundamentals of thermodynamics and kinetics, and it explains the scientific background essential for understanding refinery operations. The text also provides a detailed introduction to refinery engineering topics, ranging from the basic principles and unit operations to overall refinery economics. The book covers important topics, such as clean fuels, gasification, biofuels, and environmental impact of refining, which are not commonly discussed in most refinery textbooks. Throughout the source, problem sets and examples are given to help the reader practice and apply the fundamental principles of refining. Chapters 1-10 can be used as core materials for teaching undergraduate courses. The first two chapters present an introduction to the petroleum refining industry and then focus on feedstocks and products. Thermophysical properties of crude oils and petroleum fractions, including processes of atmospheric and vacuum distillations, are discussed in Chapters 3 and 4. Conversion processes, product blending, and alkylation are covered in chapters 5-10. The remaining chapters discuss hydrogen production, clean fuel production, refining economics and safety, acid gas treatment and removal, and methods for environmental and effluent treatments. This source can serve both professionals and students (on undergraduate and graduate levels) of Chemical and Petroleum Engineering, Chemistry, and Chemical Technology. Beginners in the engineering field, specifically in the oil and gas industry, may also find this book invaluable. Provides balanced coverage of fundamental and operational topics Includes spreadsheets and process simulators for showing trends and simulation case studies Relates processing to planning and management to give an integrated picture of refining