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Organoderivatives Of Rare Earth Elements


Organoderivatives Of Rare Earth Elements
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Organoderivatives Of Rare Earth Elements


Organoderivatives Of Rare Earth Elements
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Author : Mikhail Bochkarev
language : en
Publisher: Springer
Release Date : 2012-12-24

Organoderivatives Of Rare Earth Elements written by Mikhail Bochkarev and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-24 with Science categories.


The present book is based on the work of M.N.Bochkarev, G.S.Kalinina, L.N. zakharov and S.Ya.Khorshev. The Russian edition of that book appeared under the same title in 1989 and covered literature data up to the middle of 1986. Since that time the number of publications on this subject increased significantly. In this volume we include all the data published up to the end of 1990, as well as some of the most important relevant articles of 1991. Therefore, this book should be considered as a new book, devoted to the same problems, rather than as just a translation of the mentioned issue. This book deals with compounds of scandium, yttrium, lanthanum and lanthanoids containing direct metal-carbon bond, Le. with the real organometallic complexes of these metals. Besides, the volume includes the rare earth complexes, in which organic ligand is bonded to the metal atom via the atom of another element of the Periodic Table. In other words, the book includes all classes of rare earth organoderivatives. Carboxilates, fl-diketonates and related chelates are the exceptions, because their properties are closer to inorganic compounds and they were fully described elsewhere. It should be noted, that "rare earth elements", "rare earth metals", "lanthanoids" and related terms are used in this book for indicating scandium, yttrium, lanthanum and the following 14 elements of the Periodic Table.



Organoderivatives Of Rare Earth Elements


Organoderivatives Of Rare Earth Elements
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Author : M.N. Bochkarev
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Organoderivatives Of Rare Earth Elements written by M.N. Bochkarev and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


The present book is based on the work of M.N.Bochkarev, G.S.Kalinina, L.N. zakharov and S.Ya.Khorshev. The Russian edition of that book appeared under the same title in 1989 and covered literature data up to the middle of 1986. Since that time the number of publications on this subject increased significantly. In this volume we include all the data published up to the end of 1990, as well as some of the most important relevant articles of 1991. Therefore, this book should be considered as a new book, devoted to the same problems, rather than as just a translation of the mentioned issue. This book deals with compounds of scandium, yttrium, lanthanum and lanthanoids containing direct metal-carbon bond, Le. with the real organometallic complexes of these metals. Besides, the volume includes the rare earth complexes, in which organic ligand is bonded to the metal atom via the atom of another element of the Periodic Table. In other words, the book includes all classes of rare earth organoderivatives. Carboxilates, fl-diketonates and related chelates are the exceptions, because their properties are closer to inorganic compounds and they were fully described elsewhere. It should be noted, that "rare earth elements", "rare earth metals", "lanthanoids" and related terms are used in this book for indicating scandium, yttrium, lanthanum and the following 14 elements of the Periodic Table.



Coordination Compounds Continuation


Coordination Compounds Continuation
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Author : Therald Moeller
language : en
Publisher: Springer
Release Date : 1981

Coordination Compounds Continuation written by Therald Moeller and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1981 with Science categories.




Ion Exchange And Solvent Extraction Reactions Organometallic Compounds


Ion Exchange And Solvent Extraction Reactions Organometallic Compounds
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Author : Therald Moeller
language : en
Publisher: Springer
Release Date : 1983

Ion Exchange And Solvent Extraction Reactions Organometallic Compounds written by Therald Moeller and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1983 with Science categories.




Expanding Synthetic Aspects Of Redox And Mechanical Organometallic Chemistry Of Rare Earth Complexes


Expanding Synthetic Aspects Of Redox And Mechanical Organometallic Chemistry Of Rare Earth Complexes
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Author : Christopher Matthew Kotyk
language : en
Publisher:
Release Date : 2015

Expanding Synthetic Aspects Of Redox And Mechanical Organometallic Chemistry Of Rare Earth Complexes written by Christopher Matthew Kotyk and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015 with categories.


This dissertation describes the synthesis, characterization, and reactivity of organometallic complexes of yttrium and the lanthanides in an effort to more completely understand the nature of a recently-discovered class of +2 ions of these rare earth metals. The reactivity of complexes of a new set of Ln2+ ions (Ln = rare earth metal) with unprecedented 4fn5d1 electron configurations has been explored to expand the unique chemistry possible with the rare earth elements. The isolation of unexpected reaction products is described as well as the discovery of a new divalent lanthanide system and the utilization of solvent-free mechanochemical synthesis for established rare earth organometallic species. In Chapter 1, the reactivity of the highly-reducing, air-, moisture-, and temperature-sensitive divalent lanthanide complexes [K(2.2.2-cryptand)][Cp'3Ln] (Ln = Y, La, Ce, Dy) is characterized by examining reactions with aromatic organic substrates of known reduction potential. Complexes of the 4fn5d1 Ln2+ ions reduce naphthalene and biphenyl within minutes to form a new class of reduced aromatic complexes, [K(2.2.2-cryptand)][Cp'2Ln(n4-C10H8)] (Ln = Y, La, Ce, Dy) and [K(2.2.2-cryptand)][Cp'2Y(n6-C6H5Ph)], respectively. The naphthalene reactions also produced the previously unobserved ligand redistribution products [K(2.2.2-cryptand)][Cp'4Ln] (Ln = Y, La), which show the effect of the lanthanide contraction on structure as the lanthanum complex has four n5-Cp' rings while yttrium has three n5-Cp' rings and one n1-Cp' ring.



Comprehensive Coordination Chemistry Ii


Comprehensive Coordination Chemistry Ii
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Author : J. A. McCleverty
language : en
Publisher: Newnes
Release Date : 2003-12-03

Comprehensive Coordination Chemistry Ii written by J. A. McCleverty and has been published by Newnes this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-12-03 with Science categories.


Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.



Chemistry Of The Elements


Chemistry Of The Elements
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Author : N. N. Greenwood
language : en
Publisher: Elsevier
Release Date : 2012-12-02

Chemistry Of The Elements written by N. N. Greenwood and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.


When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century. Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will not only value during their formal education, but will keep and refer to throughout their careers as chemists. Completely revised and updated Unique approach to the subject More comprehensive than competing titles



Rare Earths 98


Rare Earths 98
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Author : R. C. Woodward
language : en
Publisher:
Release Date : 1999

Rare Earths 98 written by R. C. Woodward and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999 with Science categories.


The rare earth elements and compounds have unique spectroscopic, magnetic and chemical properties. These materials not only provide interesting windows into many aspects of science but are being used in an ever increasing number of strategic applications, particularly in the high growth sectors of world economics such as electronics, environmental protection (catalysis), magnets, nuclear medicine therapy and agriculture.



Rare Earth Elements


Rare Earth Elements
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Author : John H. Forsberg
language : en
Publisher:
Release Date : 1983

Rare Earth Elements written by John H. Forsberg and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1983 with categories.




Lanthanide And Actinide Chemistry


Lanthanide And Actinide Chemistry
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Author : Simon Cotton
language : en
Publisher: John Wiley & Sons
Release Date : 2024-01-23

Lanthanide And Actinide Chemistry written by Simon Cotton and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-01-23 with Science categories.


LANTHANIDE AND ACTINIDE CHEMISTRY Lanthanides and actinides, also known as “f elements,” are a group of metals which share certain important properties and aspects of electronic structure. They have a huge range of applications in the production of electronic devices, magnets, superconductors, fuel cells, sensors, and more. The cursory treatment of these important metals in most inorganic chemistry textbooks makes a book-length treatment essential. Since 2006, Lanthanide and Actinide Chemistry has met this need with a thorough, accessible overview. With in-depth accounts of the lanthanides, actinides, and transactinides, this book is ideal for both undergraduate and postgraduate students in inorganic chemistry or chemical engineering courses. Now updated to reflect groundbreaking recent research, this promises to continue as the essential introductory volume on the subject. Readers of the second edition of Lanthanide and Actinide Chemistry will also find: New and expanded subject areas including lanthanide enzymes, single-molecule magnets, luminescence and upconversion, organometallic and coordination chemistry; and many more. Up-to-date information on the myriad modern applications of f-elements Lists of objectives and learning goals at the start of each chapter Lanthanide and Actinide Chemistry is ideal for advanced undergraduates and graduate students in f-element chemistry, inorganic chemistry, or any related field. INORGANIC CHEMISTRY ADVANCED TEXTBOOK This series reflects the pivotal role of modern inorganic and physical chemistry in a whole range of emerging areas, such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in established areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry.