Oxidation Of C H Bonds
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Oxidation Of C H Bonds
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Author : Wenjun Lu
language : en
Publisher: John Wiley & Sons
Release Date : 2017-02-03
Oxidation Of C H Bonds written by Wenjun Lu and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-02-03 with Science categories.
A combination of oxidation methods and C‒H bond functionalization, this book emphasizes mechanistic understanding and critical analysis of synthetic reactions to offer a guide or manual for practicing chemists. • Combines oxidation methods and C‒H bond functionalization, two of the most important aspects of organic synthesis • Deals with C‒H bonds, an area of dynamic and continuous research across chemistry and catalysis • Helps readers understand the fundamental and applied differences among various oxidation methods and reactions • Covers mechanistic details, conditions, oxidation reagents, and practical aspects of different reactions
Oxidation Of Unactivated C H Bonds Catalyzed By Manganese Complexes Control Over Site Selectivity And Enantioselectivity
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Author : Michela Milan
language : en
Publisher:
Release Date : 2018
Oxidation Of Unactivated C H Bonds Catalyzed By Manganese Complexes Control Over Site Selectivity And Enantioselectivity written by Michela Milan and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018 with categories.
The oxidation of aliphatic C-H bonds is a very powerful reaction because it allows the functionalization of inert C-H bonds, converting them into a suitable sites for further chemical elaboration. It also represents one of the most challenging reactions in modern synthetic organic chemistry because the multitude of aliphatic C-H bonds in a molecule makes site selective oxidation particularly difficult. Moreover, the introduction of chirality represents an unmet but very appealing challenge, because the asymmetric oxidation of hydrocarbons produces chiral compounds of high value in organic synthesis from readily available starting materials. Until now, examples of enantioselective oxidation of nonactivated aliphatic C-H bonds remain exclusive to enzymes. This thesis has been devoted to the development of new catalytic systems capable to oxidize nonactivated aliphatic C-H bonds in a site-selective and enantioselective manner. In particularly, chemo- and enantioselective aliphatic C-H oxidation reactions, especially focused in amide containing substrates have been developed.
Oxidation
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Author : Barry M. Trost
language : en
Publisher: Elsevier
Release Date : 1992-09-08
Oxidation written by Barry M. Trost and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-09-08 with Science categories.
This volume covers all methods of oxidation for use in organic synthesis. Emphasis has been placed on selectivity and functional group compatibility together with practical utility and applications. The volume is broadly divided to cover oxidation of unactivated carbon-hydrogen bonds, oxidation of activated carbon-hydrogen bonds, that is to say those adjacent to activating substituents and adjacent to heteroatoms, and oxidation of carbon-carbon double bonds. The volume also covers oxidation of C-X bonds, carbon-carbon single bonds, heteroatom oxidation and a number of special topics such as electrochemical methods, oxidative rearrangements, solid supported reagents, electron transfer oxidation, and biological methods.
Selective Oxidation Of Unactivated C H Bonds By Supramolecular Control
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Author : Yat-Sing Fung
language : en
Publisher:
Release Date : 2012
Selective Oxidation Of Unactivated C H Bonds By Supramolecular Control written by Yat-Sing Fung and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012 with Hydrocarbons categories.
Alkane C H Activation By Single Site Metal Catalysis
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Author : Pedro J. Pérez
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-09-15
Alkane C H Activation By Single Site Metal Catalysis written by Pedro J. Pérez and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-09-15 with Science categories.
Over the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C−H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. Alkane C-H Activation by Single-Site Metal Catalysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions. Chapter 1 offers a comprehensive summary of the main discoveries realized so far. Chapter 2 reviews the so-called electrophilic activation, initiated by Shulpín in the late 60s, and the base for the Catalytica system. Chapter 3 examines the catalytic borylation of alkanes, discovered by Hartwig, whereas chapter 4 provides an updated vision of the alkane dehydrogenation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. The history of C-H bond activation, and the current research described in this book, highlight the current research and present the reader with an outlook of this field which continues to be explored by an increasingly visionary and enthusiastic group of organic, organometallic, biological and physical chemists.
Metal Free Oxidation Of Unactivated Sp3 C H Bonds
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Author : Sergej Maciuk
language : en
Publisher:
Release Date : 2021
Metal Free Oxidation Of Unactivated Sp3 C H Bonds written by Sergej Maciuk and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021 with categories.
The Activation Of Dioxygen And Homogeneous Catalytic Oxidation
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Author : D.H.R. Barton
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
The Activation Of Dioxygen And Homogeneous Catalytic Oxidation written by D.H.R. Barton and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
This monograph consists of the proceedings of the Fifth International Symposium on the Activation of Dioxygen and Homogeneous Catalytic Oxidation, held in College Station, Texas, March 14-19, 1993. It contains an introductory chapter authored by Professors D. H. R. Barton and D. T. Sawyer, and twenty-nine chapters describing presentations by the plenary lecturers and invited speakers. One of the invited speakers, who could not submit a manuscript for reasons beyond his control, is represented by an abstract of his lecture. Also included are abstracts of forty-seven posters contributed by participants in the symposium. Readers who may wish to know more about the subjects presented in abstract form are invited to communicate directly with the authors of the abstracts. This is the fifth international symposium that has been held on this subject. The first was hosted by the CNRS, May 21-29, 1979, in Bendor, France (on the Island of Bandol). The second meeting was organized as a NATO workshop in Padova, Italy, June 24-27, 1984. This was followed by a meeting in Tsukuba, Japan, July 12-16, 1987. The fourth symposium was held at Balatonfured, Hungary, September 10-14, 1990. The sixth meeting is scheduled to take place in Delft, The Netherlands (late Spring, 1996); the organizer and host will be Professor R. A. Sheldon.
Chromium Oxidations In Organic Chemistry
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Author : G. Cainelli
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Chromium Oxidations In Organic Chemistry written by G. Cainelli and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Chromium oxidation, well known and widely explored in organic chemistry since the very beginning of this science, is a topic of current interest for the organic chemist as evidenced by the continuous development of new techni ques and procedures reported in the literature. Chromium oxidation is a simple process which can be easily performed in the laboratory and scaled up in industry as well. Although almost every oxidizable organic functional group may undergo chromium oxidation, the most important fields of appli cation are the oxidation of alcohols, allylic and benzylic oxidation, oxidative degradation and oxidation of some organometallic compounds. A high degree of selectivity is often possible by choosing the most suitable reagent among those several ones now available. This book takes account of the various functional groups that undergo oxidation and the entire literature up to 1982. It has been written in the hope to help the synthetic organic chemist in his experimental work. For this purpose a number of tables comprising yields and references have been included; detailed descriptions of typical procedures are meant to show the experimental conditions and the scope of the reactions. We wish to thank Dr. Mario Orena for his valuable scientific and technical assistence and Prof. Bruno Camerino, who read the entire manuscript and corrected many of the errors. Bologna, February 1984 Gianfranco Cainelli Giuliana Cardillo Table of Contents I. Introduction . . . . . . . . . . .
Electrocatalytic Oxidation Of Small Molecules Containing C O And C H Bonds And A Method For Release Of Microfabricated Structures
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Author : González María (María Josefina)
language : en
Publisher:
Release Date : 1996
Electrocatalytic Oxidation Of Small Molecules Containing C O And C H Bonds And A Method For Release Of Microfabricated Structures written by González María (María Josefina) and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996 with categories.
Remote C H Bond Functionalizations
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Author : Debabrata Maiti
language : en
Publisher: John Wiley & Sons
Release Date : 2021-01-05
Remote C H Bond Functionalizations written by Debabrata Maiti and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-01-05 with Science categories.
A guide to contemporary advancements in the field of distal C—H functionalization Remote C—H Bond Functionalizations provides a comprehensive overview on the most recent developments in the field of distal C—H functionalization. The text explores how distal C—H functionalization can be applied in various pharmaceutical and agrochemical industries. With contributions from a noted panel of experts on the topic, the book offers a coherent and comprehensive discussion about different strategies. The contributors cover a broad range of topics including C—H functionalization of palladium/norbornene catalysis, ruthenium-catalyzed remote functionalization, the non-directed distal C(sp2)—H, functionalization, transition metal catalyzed distal para-selective C—H functionalization, and much more. The book also includes information on effective strategies as well as the engineering of templates. Throughout the book, the authors lay the foundations for future research. This important book: Contains the most recent research on one of the most important topics in organic synthesis Provides a broad overview on contemporary advancements in the field of distal C—H functionalization Includes deep insights into distal C—H functionalizations Offers information on applications in various industries Written for organic chemists, chemists working with organometallics, and industrial chemists, Remote C—H Bond Functionalizations presents a systematic compilation of the field.
