Palladium In Organic Synthesis
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Palladium In Organic Synthesis
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Author : Jiro Tsuji
language : en
Publisher: Springer Science & Business Media
Release Date : 2005-07-06
Palladium In Organic Synthesis written by Jiro Tsuji and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2005-07-06 with Science categories.
with contributions by numerous experts
Handbook Of Organopalladium Chemistry For Organic Synthesis
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Author : Ei-ichi Negishi
language : en
Publisher: John Wiley & Sons
Release Date : 2003-11-24
Handbook Of Organopalladium Chemistry For Organic Synthesis written by Ei-ichi Negishi and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-11-24 with Science categories.
Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.
Organic Synthesis With Palladium Compounds
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Author : Jiro Tsuji
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Organic Synthesis With Palladium Compounds written by Jiro Tsuji and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Around 30 years ago the transition metal chemistry received great impulses. In the focus have been reactions of nickel and cobalt and herein especially their carbonyls. Also industrial processes have been developed. When the technical oxidation of ethylene with palladium chloride had been discovered, and a great number oflaboratory reactions, many groups have turned towards this subject. Apart from two important industrial processes - acetaldehyde and vinylacetate from ethylene - a great number of conversions and catalytic reactions with palladium compounds have been researched. Their mechanisms have been cleared up and have con tributed to a better understanding of the complex chemistry of palladium. Last but not least these reactions have also served for more understanding of organic transition metal compounds and catalyses in general. Numerous conventional reactions appear today in a different light. The effects of co-
Palladium Reagents And Catalysts
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Author : Jiro Tsuji
language : en
Publisher:
Release Date : 1995
Palladium Reagents And Catalysts written by Jiro Tsuji and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1995 with Science categories.
Basic chemistry of organopalladium compounds; Classification of the reactions involving Pd(II) compounds and Pd(O) complexes.
Palladium Reagents And Catalysts
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Author : Jiro Tsuji
language : en
Publisher: John Wiley & Sons
Release Date : 2006-02-08
Palladium Reagents And Catalysts written by Jiro Tsuji and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-02-08 with Science categories.
Jiro Tsuji, one of the pioneers in this field of organic synthesis, provides synthetic organic chemists with a remarkable overview of the many applications of organopalladium chemistry. Tsuji discusses the recent developments in the field as well as the explosive growth over the last five years. Highlighting the most recent discoveries in this rapidly expanding field, the book; Focuses on new aspects of organopalladium chemistry, putting emphasis on synthetic applications Investigates the new perspectives on the synthetic uses of contemporary organopalladium chemistry This volume, together with Innovations in Organic Synthesis, Tsuji's previous title, provides complete coverage of over 40 years of organopalladium chemistry. Palladium Reagents and Catalysts: New Perspectives for the 21st Century is an essential reference source and companion for students, and both industrial and academic research chemists working in organic synthesis, particularly on synthesis of natural products and medicinal compounds. Those studying development of new synthetic methodology and organometallic chemistry will also find this book valuable.
Perspectives In Organopalladium Chemistry For The 21st Century
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Author : J. Tsuji
language : en
Publisher:
Release Date : 1999-11-09
Perspectives In Organopalladium Chemistry For The 21st Century written by J. Tsuji and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999-11-09 with Science categories.
Perspectives in Organopalladium Chemistry for the 21st Century is a monograph on modern organopalladium chemistry, with an emphasis on the use of palladium in organic synthesis. The collection of articles is reprinted from a special issue of the Journal of Organometallic Chemistry. The field of organopalladium chemistry is evolving rapidly, building on a growing catalogue of reactions that employ palladium-containing catalysts. This book should hold particular interest for those who apply palladium reagents and catalysts to organic synthesis; in fact, palladium is considered by many to be the most useful transition element employed for organic syntheses. This selection of articles by leading scientists, published as "Perspectives in Organopalladium Chemistry for the 21st Century", provides an impressive overview of the field that every chemist who works with organometallic palladium catalysts should read.
Palladium Reagents In Organic Syntheses
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Author : Richard F. Heck
language : en
Publisher:
Release Date : 1985
Palladium Reagents In Organic Syntheses written by Richard F. Heck and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1985 with Science categories.
Solid Phase Organic Syntheses Volume 2
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Author : Peter J. H. Scott
language : en
Publisher: John Wiley & Sons
Release Date : 2012-07-02
Solid Phase Organic Syntheses Volume 2 written by Peter J. H. Scott and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-07-02 with Science categories.
Integrates solid-phase organic synthesis with palladium chemistry The Wiley Series on Solid-Phase Organic Syntheses keeps researchers current with major accomplishments in solid-phase organic synthesis, providing full experimental details. Following the validated, tested, and proven experimental procedures, readers can easily perform a broad range of complex syntheses needed for their own experiments and industrial applications. The series is conveniently organized into themed volumes according to the specific type of synthesis. This second volume in the series focuses on palladium chemistry in solid-phase synthesis, exploring palladium catalysts and reactions, procedures for preparation and utilization, ligands, and linker reactions. The first part of the volume offers a comprehensive overview of the field. Next, the chapters are organized into three parts: Part Two: Palladium-Mediated Solid-Phase Organic Syntheses Part Three: Immobilized Catalysts and Ligands Part Four: Palladium-Mediated Multifunctional Cleavage Each chapter is written by one or more leading international experts in palladium chemistry. Their contributions reflect a thorough examination and review of the current literature as well as their own first-hand laboratory experience. References at the end of each chapter serve as a gateway to the field's literature. The introduction of palladium-mediated, cross-coupling reactions more than thirty years ago revolutionized the science of carbon-carbon bond formation. It has now become a cornerstone of today's synthetic organic chemistry laboratory. With this volume, researchers in organic and medicinal chemistry have access to a single resource that explains the fundamentals of palladium chemistry in solid-phase synthesis and sets forth clear, step-by-step instructions for conducting their own syntheses.
Metal Complexes
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Author : Peter Maitlis
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Metal Complexes written by Peter Maitlis and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
The Organic Chemistry of Palladium, Volume 1: Metal Complexes deals with the number of organic reactions that can be catalyzed by palladium, particularly as regards the structures bonding, and reactions of the metal complexes. The book discusses monodentate ligands which are either neutral (carbonyls, isonitriles, carbenes) or anionic (methyl, phenyl, ethynyl, hydride). The text also examines the complexes formed by 1,3-. 1,4-, and 1,5-diolefins where four carbon atoms are bound to the metal. Palladium (II) can undergo a reaction with the 1,3-dienes and results in a ?-allylic complexes where only three carbon atoms are coordinated to the metal. (The bonding situation in complexes 1,4- and 1,5-dienes, where no great interaction between the olefins are similar to that in monoolefin complexes, is straightforward), Olefins can also react with palladium chloride in protic solvents to produce ketones (or aldehydes) or organic coupling products. Some experiments conducted by Huttel et al shows that some palladium was precipitated from the reactions giving lower yields, resulting in various aldehydes and ketones as by products. The book also discusses cyclopentadienyl and benzene complexes. The text can prove beneficial for researchers, investigators and scientists whose works involve organic chemistry, analytical chemistry, physical chemistry and inorganic chemistry.
Catalytic Reactions
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Author : Peter Maitlis
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Catalytic Reactions written by Peter Maitlis and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
The Organic Chemistry of Palladium, Volume I1: Catalytic Reactions deals with organic transformations resulting from palladium complexes either stoichiometrically or catalytically. One feature of a reaction catalyzed by transition metals is the absence of evidence for the typical reactive intermediates of organic chemistry, carbanions, and carbonium ions. This lack of evidence is due to the metal acting both as a source and a sink of electrons that result in energetically unfavorable ionic intermediaries. The book explains that palladium (II) can induce C-O bond formation. These reactions involve oxidation of the organic substrate and reduces the Pd(II) to metal, and are not catalytic. Industrial applications can re-oxidize the palladium metal back to Pd(II) in situ, making the reactions catalytic. The text also discusses certain reactions that can form C-O bonds as part of an oxidative process. The book also describes significant reactions that can be catalyzed by palladium metal, such as in the hydrogenation of multiple bonds, in the carbonylation of certain olefins and acetylenes, and in the catalytic cracking of high molecular weight hydrocarbons. Organic chemists, analytical chemists, investigators, and scientists whose works involve physical or inorganic chemistry will find the book truly useful.
