Process Design And Economics For Biochemical Conversion Of Lignocellulosic Biomass To Ethanol
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Process Design And Economics For Biochemical Conversion Of Lignocellulosic Biomass To Ethanol
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Author :
language : en
Publisher:
Release Date : 2011
Process Design And Economics For Biochemical Conversion Of Lignocellulosic Biomass To Ethanol written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011 with categories.
Process Design And Economics For Biochemical Conversion Of Lignocellulosic Biomass To Ethanol
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Author :
language : en
Publisher:
Release Date : 2011
Process Design And Economics For Biochemical Conversion Of Lignocellulosic Biomass To Ethanol written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011 with Alcohol as fuel categories.
This report describes one potential biochemical ethanol conversion process, conceptually based upon core conversion and process integration research at NREL. The overarching process design converts corn stover to ethanol by dilute-acid pretreatment, enzymatic saccharification, and co-fermentation. Building on design reports published in 2002 and 1999, NREL, together with the subcontractor Harris Group Inc., performed a complete review of the process design and economic model for the biomass-to-ethanol process. This update reflects NREL's current vision of the biochemical ethanol process and includes the latest research in the conversion areas (pretreatment, conditioning, saccharification, and fermentation), optimizations in product recovery, and our latest understanding of the ethanol plant's back end (wastewater and utilities). The conceptual design presented here reports ethanol production economics as determined by 2012 conversion targets and "nth-plant" project costs and financing. For the biorefinery described here, processing 2,205 dry ton/day at 76% theoretical ethanol yield (79 gal/dry ton), the ethanol selling price is $2.15/gal in 2007 dollars.
Process Design And Economics For The Conversion Of Lignocellulosic Biomass To Hydrocarbon Fuels And Coproducts 2018 Biochemical Design Case Update Biochemical Deconstruction And Conversion Of Biomass To Fuels And Products Via Integrated Biorefinery Pathways
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Author :
language : en
Publisher:
Release Date : 2018
Process Design And Economics For The Conversion Of Lignocellulosic Biomass To Hydrocarbon Fuels And Coproducts 2018 Biochemical Design Case Update Biochemical Deconstruction And Conversion Of Biomass To Fuels And Products Via Integrated Biorefinery Pathways written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018 with categories.
Over the past decade, NREL conducted a campaign to quantify the economic implications associated with observed and future targeted performance for the biochemical conversion of corn stover to ethanol through techno-economic modeling. This report serves as an update to the biological sugar conversion approach, reflecting modifications to underlying conversion operational strategies, as well as refinements to the techno-economic model details. In addition, the report includes a more quantitative focus on envisioned processing requirements for achieving final fuel cost goals moving further into the future, via inclusion of value-added coproducts.
Process Design And Economics For Conversion Of Lignocellulosic Biomass To Ethanol
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Author :
language : en
Publisher:
Release Date : 2011
Process Design And Economics For Conversion Of Lignocellulosic Biomass To Ethanol written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011 with Biomass conversion categories.
This design report describes an up-to-date benchmark thermochemical conversion process that incorporates the latest research from NREL and other sources. Building on a design report published in 2007, NREL and its subcontractor Harris Group Inc. performed a complete review of the process design and economic model for a biomass-to-ethanol process via indirect gasification. The conceptual design presented herein considers the economics of ethanol production, assuming the achievement of internal research targets for 2012 and nth-plant costs and financing.
Process Design And Economics For Conversion Of Lignocellulosic Biomass To Ethanol
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Author :
language : en
Publisher:
Release Date : 2011
Process Design And Economics For Conversion Of Lignocellulosic Biomass To Ethanol written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011 with categories.
Cellulosic Ethanol From Corn Stover Cost Analysis Ethanol E11a
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Author : Intratec
language : en
Publisher: Intratec Solutions
Release Date : 2016-05-01
Cellulosic Ethanol From Corn Stover Cost Analysis Ethanol E11a written by Intratec and has been published by Intratec Solutions this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-05-01 with Business & Economics categories.
This report presents a cost analysis of second generation Ethanol production from corn stover via a biochemical conversion process. The process examined is similar to the process reported by the National Renewable Energy Laboratory (NREL). This process involves the following steps in the production of hydrous Ethanol: corn stover pretreatment with dilute acid and ammonia conditioning; enzymatic hydrolysis; and fermentation. Electricity is also generated as by-product. This report examines one-time costs associated with the construction of a United States-based plant and the continuing costs associated with the daily operation of such a plant. More specifically, it discusses: * Capital Investment, broken down by: - Total fixed capital required, divided in production unit (ISBL); infrastructure (OSBL) and contingency - Alternative perspective on the total fixed capital, divided in direct costs, indirect costs and contingency - Working capital and costs incurred during industrial plant commissioning and start-up * Production cost, broken down by: - Manufacturing variable costs (raw materials, utilities) - Manufacturing fixed costs (maintenance costs, operating charges, plant overhead, local taxes and insurance) - Depreciation and corporate overhead costs * Raw materials consumption, products generation and labor requirements * Process block flow diagram and description of industrial site installations (production unit and infrastructure) This report was developed based essentially on the following reference(s): Humbird, D., et al., "Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol, " Report NREL/TP-5100-47764, National Renewable Energy Laboratory (NREL), 2011 Keywords: Ethyl Alcohol, Bioethanol, Lignocellulosic Biomass, 2nd Generation, Cellulosic Sugar, Hemicelluloses, Cellulose
Lignocellulosic Biomass To Ethanol Process Design And Economics Utilizing Co Current Dilute Acid Prehydrolysis And Enzymatic Hydrolysis For Corn Stover
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Author :
language : en
Publisher:
Release Date : 2002
Lignocellulosic Biomass To Ethanol Process Design And Economics Utilizing Co Current Dilute Acid Prehydrolysis And Enzymatic Hydrolysis For Corn Stover written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002 with categories.
This report is an update of NREL's ongoing process design and economic analyses of processes related to developing ethanol from lignocellulosic feedstocks. The U.S. Department of Energy (DOE) is promoting the development of ethanol from lignocellulosic feedstocks as an alternative to conventional petroleum-based transportation fuels. DOE funds both fundamental and applied research in this area and needs a method for predicting cost benefits of many research proposals. To that end, the National Renewable Energy Laboratory (NREL) has modeled many potential process designs and estimated the economics of each process during the last 20 years. This report is an update of the ongoing process design and economic analyses at NREL. We envision updating this process design report at regular intervals; the purpose being to ensure that the process design incorporates all new data from NREL research, DOE funded research and other sources, and that the equipment costs are reasonable and consistent with good engineering practice for plants of this type. For the non-research areas this means using equipment and process approaches as they are currently used in industrial applications. For the last report, published in 1999, NREL performed a complete review and update of the process design and economic model for the biomass-to-ethanol process utilizing co-current dilute acid prehydrolysis with simultaneous saccharification (enzymatic) and co-fermentation. The process design included the core technologies being researched by the DOE: prehydrolysis, simultaneous saccharification and co-fermentation, and cellulase enzyme production. In addition, all ancillary areas--feed handling, product recovery and purification, wastewater treatment (WWT), lignin combustor and boiler-turbogenerator, and utilities--were included. NREL engaged Delta-T Corporation (Delta-T) to assist in the process design evaluation, the process equipment costing, and overall plant integration. The process design and costing for the lignin combustor and boiler turbogenerator was reviewed by Reaction Engineering Inc. (REI) and Merrick & Company reviewed the wastewater treatment. Since then, NREL has engaged Harris Group (Harris) to perform vendor testing, process design, and costing of critical equipment identified during earlier work. This included solid/liquid separation and pretreatment reactor design and costing. Corn stover handling was also investigated to support DOE's decision to focus on corn stover as a feedstock for lignocellulosic ethanol. Working with Harris, process design and costing for these areas were improved through vendor designs, costing, and vendor testing in some cases. In addition to this work, enzyme costs were adjusted to reflect collaborative work between NREL and enzyme manufacturers (Genencor International and Novozymes Biotech) to provide a delivered enzyme for lignocellulosic feedstocks. This report is the culmination of our work and represents an updated process design and cost basis for the process using a corn stover feedstock. The process design and economic model are useful for predicting the cost benefits of proposed research. Proposed research results can be translated into modifications of the process design, and the economic impact can be assessed. This allows DOE, NREL, and other researchers to set priorities on future research with an understanding of potential reductions to the ethanol production cost. To be economically viable, ethanol production costs must be below market values for ethanol. DOE has chosen a target ethanol selling price of $1.07 per gallon as a goal for 2010. The conceptual design and costs presented here are based on a 2010 plant start-up date. The key research targets required to achieve this design and the $1.07 value are discussed in the report.
Biochemical Conversion Of Lignocellulosic Biomass To Ethanol
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Author : Deepak Kumar
language : en
Publisher:
Release Date : 2014
Biochemical Conversion Of Lignocellulosic Biomass To Ethanol written by Deepak Kumar and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014 with Agricultural wastes as fuel categories.
Ethanol production from lignocellulosic feedstock has been under intense scrutiny as a transportation fuel due to its potential to address concerns of increasing energy consumption, limited fossil energy resources, climate changes due to greenhouse gas emissions from fossil fuels, and especially use of non-food biomaterials, which address the biggest limitation of first generation bioethanol. Despite these advantages, the lignocellulosic ethanol production on commercial scale is still on verge because of high processing costs of ethanol production. In the biochemical conversion process, biomass is converted to ethanol by sequential steps of pretreatment (to reduce the recalcitrance of biomass), hydrolysis (conversion of sugar polymers to monomers) and fermentation (sugars to ethanol). Every year, about a million ton of grass straw is available as agricultural residue in Pacific Northwest. There were no previous comprehensive studies to evaluate the technical feasibility, economic viability and environmental sustainability of the bioethanol produced using grass straw in Willamette valley. The focus of this dissertation was to investigate the potential of cellulosic ethanol production from grass straw, assess the techno-economic viability and environmental impacts of the bioethanol production and development of a stochastic molecular model for modeling cellulose hydrolysis. This dissertation was divided into four studies focused on individual aspects of the overall objective. The first study evaluated the ethanol production potential from straws produced from three major grass seed varieties (perennial ryegrass (Lolium perenne L.), tall fescue (Festuca arundinacea Schreb) and bentgrass (Agrostis sp.)) in Pacific Northwest. Feedstocks were pretreated using three chemical pretreatments (dilute acid, dilute alkali, and hot water) and subsequently hydrolyzed enzymatically to investigate the effect of pretreatment and estimate the potential ethanol yields. Carbohydrate content in biomass varied from 40.6 to 52.9%, with tall fescue having the maximum cellulose content of 32.4%. All pretreatment were effective in increasing the hydrolysis yields, and theoretical maximum ethanol yields were in the range of 276 to 360 L per ton of biomass. The second study performed the comprehensive techno-economic analysis of ethanol production from tall fescue using dilute acid, dilute alkali, hot water, and steam explosion pretreatment technologies. Detailed process models incorporating all unit operations in lignocellulosic ethanol plant with 250,000 metric ton biomass/ year processing capacity were developed in SuperPro Designer. The ethanol production cost were estimated from $0.81 to $0.88/ L of ethanol, and were found highly sensitive to biomass price, enzyme cost, and pentose sugar fermentation efficiency. Energy from lignin residue burning was found sufficient to meet the steam requirement in the production process. Third study performed the life cycle assessment for bioethanol production from grass straw considering various pretreatment technology options. The study revealed that ethanol production from grass straw provide environmental benefits compared to use of gasoline, with 57.43-112.67% reduction in fossil energy use to produce 10,000 MJ of fuel. The GHG emissions during life cycle of ethanol production were estimated in the range of -131 to -555.4 kg CO2 eq. per 10,000 MJ of fuel. It was observed that assumptions and allocation procedure used during the analysis had a significant effect on the LCA results. During the techno-economic assessment of bioethanol process, it was found that cost of cellulose enzymes was significant fraction of the total ethanol production cost. A comprehensive enzymatic hydrolysis model can play critical role in optimizing the enzyme composition and dosage, improving understanding of the process mechanism and reducing the cost of enzymes, a major bottleneck in the ethanol production process. A novel approach of stochastic molecular modeling, in which each hydrolysis event is translated into a discrete event, was used to develop a mechanistic model for cellulose hydrolysis in the fourth study. Cellulose structure was modeled as a group of microfibrils consisting of elementary fibrils bundles, where each elementary fibril was represented as a three dimensional matrix of glucose molecules. Major structural properties: crystallinity, degree of polymerization, surface accessibility, and enzyme characteristics: mode of action, binding and surface blockage, inhibition, along with the dynamic morphological changes in structure of cellulose were incorporated in the model. Hydrolysis of cellulose was simulated based on Monte Carlo simulation technique. Hydrolysis results predicted by model simulations had shown a good fit with the experimental data from hydrolysis of pure cellulose using purified enzymes for various hydrolysis conditions. The model was effective in capturing the dynamic behavior of cellulose hydrolysis during action of individual as well as multiple cellulases. Model was able to simulate and validate all the important expected experimental observations: effect of structural properties, enzyme inhibition and enzyme loadings on the hydrolysis and degree of synergism on different substrates. The work from this dissertation proved the significance of choosing technology options, drew a comparison among different pretreatment technologies, identified the critical processes and inputs that have significant effect on the ethanol production cost, net energy, and GHG emissions. Results from the last study confirmed the validity of using the stochastic molecular modeling approach to quantitatively and qualitatively describe the cellulose hydrolysis, which has wide potential application in bioethanol production research to reduce the enzyme cost.
Cellulosic Ethanol From Switchgrass Cost Analysis Ethanol E81a
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Author : Intratec
language : en
Publisher: Intratec
Release Date : 2019-09-17
Cellulosic Ethanol From Switchgrass Cost Analysis Ethanol E81a written by Intratec and has been published by Intratec this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-09-17 with Business & Economics categories.
This report presents a cost analysis of second generation Ethanol production from switchgrass based on a biochemical conversion process. The process examined is similar to the process reported by the National Renewable Energy Laboratory (NREL). This process involves the following steps in the production of hydrous Ethanol: biomass pretreatment with dilute acid and ammonia conditioning; enzymatic hydrolysis; and fermentation. Electricity is also generated as by-product. This report was developed based essentially on the following reference(s): Humbird, D., et al., "Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol, " Report NREL/TP-5100-47764, National Renewable Energy Laboratory (NREL), 2011 Keywords: Ethyl Alcohol, Bioethanol, Lignocellulosic Biomass, 2nd Generation, Cellulosic Sugar, Hemicelluloses, Cellulose
Process Design Strategies For Biomass Conversion Systems
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Author : Denny K. S. Ng
language : en
Publisher: John Wiley & Sons
Release Date : 2016-01-19
Process Design Strategies For Biomass Conversion Systems written by Denny K. S. Ng and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-01-19 with Technology & Engineering categories.
This book covers recent developments in process systems engineering (PSE) for efficient resource use in biomass conversion systems. It provides an overview of process development in biomass conversion systems with focus on biorefineries involving the production and coproduction of fuels, heating, cooling, and chemicals. The scope includes grassroots and retrofitting applications. In order to reach high levels of processing efficiency, it also covers techniques and applications of natural-resource (mass and energy) conservation. Technical, economic, environmental, and social aspects of biorefineries are discussed and reconciled. The assessment scales vary from unit- to process- and life-cycle or supply chain levels. The chapters are written by leading experts from around the world, and present an integrated set of contributions. Providing a comprehensive, multi-dimensional analysis of various aspects of bioenergy systems, the book is suitable for both academic researchers and energy professionals in industry.