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Silica Aerogel Polymer Nanocomposites And New Nanoparticle Syntheses


Silica Aerogel Polymer Nanocomposites And New Nanoparticle Syntheses
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Silica Aerogel Polymer Nanocomposites And New Nanoparticle Syntheses


Silica Aerogel Polymer Nanocomposites And New Nanoparticle Syntheses
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Author :
language : en
Publisher:
Release Date : 2009

Silica Aerogel Polymer Nanocomposites And New Nanoparticle Syntheses written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009 with categories.


Aerogels are extremely high surface area, low density materials with applications including thermal and acoustic insulators, radiation detectors and cometary dust particle traps. However, their low density and aggregate structure makes them extremely fragile and practically impossible to machine or handle without breaking. This has led to the development of aerogel composites with enhanced mechanical properties through the addition of polymers or surface modifiers. To date, attempts to strengthen aerogels have come with significant increases in density and processing time. Here I will describe our search for a solution to these problems with our invention using methyl cyanoacrylate chemical vapor deposition (CVD) to strengthen silica, aminated silica and bridged polysilsesquioxane aerogels. This approach led to a strength improvement of the composites within hours and the strongest composite prepared had a 100x strength improvement over the precursor aerogel. We also developed the first approach to control the molecular weight of the polymers that reinforce silica aerogels using surface-initiated atom transfer radical polymerization (SI-ATRP). Although PMMA reinforcement of silica aerogels improved the mechanical properties, further strength improvements were achieved by cross-linking the grafted PMMA. Additionally, we developed the first silica aerogels reinforced with polyaniline nanofibers that were strong and electrically conductive. Reinforcing silica aerogels with polyaniline allowed them to be used as a sensor for the detection of protonating and deprotonating gaseous species. Finally we developed a new approach for the synthesis of silica and bridged polysilsesquioxane spheres using a surfactant free synthesis. This approach allowed for the first in-situ incorporation of base sensitive functionalities during the sol-gel polymerization.



Sol Gel Nanocomposites


Sol Gel Nanocomposites
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Author : Massimo Guglielmi
language : en
Publisher: Springer
Release Date : 2014-07-05

Sol Gel Nanocomposites written by Massimo Guglielmi and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-07-05 with Technology & Engineering categories.


This book provides comprehensive coverage of nanocomposite materials obtained by the sol-gel method, from synthesis to applications and including design tools for combining different properties. Sol-gel nanocomposites are of great interest in meeting processing and application requirements for the development of multifunctional materials. These materials are already commercialized for a number of applications from scratch-resistant and anti-adhesive coatings to optical materials with active and passive properties. Biomedical applications, holographic recordings, fuel cells and hydrogen storage, resists and catalysts are among the potential uses. The novel mechanical, optical and electronic properties of nanocomposite materials depend not only on the individual component materials, but also on their morphology and nanoscale interfacial characteristics. Sol-gel is a highly versatile method for obtaining both the matrix and the filler of the nanocomposite and for chemically adjusting the interface to optimize structure and properties. Although nanocomposites are widely discussed in the literature, the focus has been mainly on polymer nanocomposites. This book addresses nanocomposites based on inorganic or hybrid organic-inorganic matrices, with an emphasis on the scientific principles which are the basis for nanocomposite sol-gel synthesis and applications. A didactic approach is followed, with different topics developed from a fundamental point of view together with key examples and case studies. First comprehensive treatment of nanocomposites obtained by sol-gel methods Focuses on nanocomposites with inorganic and hybrid organic-inorganic matrices Describes design tools to optimize structure and properties for various applications Covers synthesis, processing, characterization, and modeling Uses first principles to describe the influence of interfacial characteristics on materials properties Presents case studies for both films and bulk applications Provides examples of products on the market, with descriptions of the scientific principles at the base of their success Includes contributions from recognized leaders in this multidisciplinary area.



Silica And Clay Dispersed Polymer Nanocomposites


Silica And Clay Dispersed Polymer Nanocomposites
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Author : Md Rezaur Rahman
language : en
Publisher: Woodhead Publishing
Release Date : 2018-06-13

Silica And Clay Dispersed Polymer Nanocomposites written by Md Rezaur Rahman and has been published by Woodhead Publishing this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-06-13 with Technology & Engineering categories.


The production of ‘polymer nanocomposites’ has recently gained considerable attention from both the academic and industrial community, especially in the area of nanoscience. This is mainly due to their enhanced improvements in physico-mechanical, thermal and barrier properties compared to micro and more conventional composites. Their nanoscale dimensions, biodegradable character, cost-effectiveness and sustainability have constituted a stimulus for this increasing interest. Currently there is no limit to the possibility of applications. However, despite all this progress, it is still difficult to achieve uniform dispersion between the filler and the matrix, as agglomerations form far too easily and the production of polymer nanocomposites with high mechanical and thermal properties is still limited. The authors of this proposed book, are of the opinion, that with the increase in scientific publications and the rapid progress in processing possibilities to produce nanocomposites based on various nanoscale fillers (silica/clay), a book that collects all of these scientific findings in one place would be timely and of great interest to both students and scientific researchers, who are concerned with the production, and application of nanocomposites as new innovative materials. The authors aim is to present the latest research findings on the fabrication, properties and applications of nanofillers as reinforcement in polymer nanocomposites. Particular emphasis will be placed on the introduction of various nanofillers (silica/clay) into different elastomeric polymer matrices that will enhance the properties of these materials and their applications. The book will provide an up-to-date review of major innovations in the field and act as a reference for future research in materials science and engineering, which is highly topical due to the demand to produce more sustainable and eco-friendly innovative advanced materials from elastomeric polymers. Emphasis on silica/clay as outstanding reinforcing potential in elastomeric polymer matrices Up-to-date on the most relevant innovations in the field of silica/clay nanocomposites and their extensive applications in advanced material science Establishes the most suitable fabrication methods, properties and applications as a solid foundation in materials science and engineering disciplines Includes the incorporation of dual nanofillers that significantly improve the properties of nanocomposites



Recent Advances In Elastomeric Nanocomposites


Recent Advances In Elastomeric Nanocomposites
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Author : Vikas Mittal
language : en
Publisher: Springer Science & Business Media
Release Date : 2011-01-15

Recent Advances In Elastomeric Nanocomposites written by Vikas Mittal and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-01-15 with Technology & Engineering categories.


‘Recent Advances in Elastomeric Nanocomposites’ reviews the recent progresses in the synthesis, processing as well as applications of elastomeric nanocomposites. Elastomers are a very important class of polymer materials and the generation of their nanocomposites by the incorporation of nano-filler has led to significant enhancement of their properties and, hence, expansion of their application potential. Most of the studies related with these materials are present in the form of research papers. Here, the authors present a comprehensive text covering the whole of the subject. The book is tailored more from the applications point of view, but also provide enough introductory material for research scholars new to this field.



Recent Advances In Polymer Nanocomposites Synthesis And Characterisation


Recent Advances In Polymer Nanocomposites Synthesis And Characterisation
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Author : Sabu Thomas
language : en
Publisher: CRC Press
Release Date : 2010-08-03

Recent Advances In Polymer Nanocomposites Synthesis And Characterisation written by Sabu Thomas and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010-08-03 with Science categories.


This book examines the current state of the art, new challenges, opportunities, and applications in the area of polymer nanocomposites. Special attention has been paid to the processing-morphology-structure-property relationship of the system. Various unresolved issues and new challenges in the field of polymer nanocompostes are discussed. The infl



Aerogels Handbook


Aerogels Handbook
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Author : Michel Andre Aegerter
language : en
Publisher: Springer Science & Business Media
Release Date : 2011-06-10

Aerogels Handbook written by Michel Andre Aegerter and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-06-10 with Technology & Engineering categories.


Aerogels are the lightest solids known. Up to 1000 times lighter than glass and with a density as low as only four times that of air, they show very high thermal, electrical and acoustic insulation values and hold many entries in Guinness World Records. Originally based on silica, R&D efforts have extended this class of materials to non-silicate inorganic oxides, natural and synthetic organic polymers, carbon, metal and ceramic materials, etc. Composite systems involving polymer-crosslinked aerogels and interpenetrating hybrid networks have been developed and exhibit remarkable mechanical strength and flexibility. Even more exotic aerogels based on clays, chalcogenides, phosphides, quantum dots, and biopolymers such as chitosan are opening new applications for the construction, transportation, energy, defense and healthcare industries. Applications in electronics, chemistry, mechanics, engineering, energy production and storage, sensors, medicine, nanotechnology, military and aerospace, oil and gas recovery, thermal insulation and household uses are being developed with an estimated annual market growth rate of around 70% until 2015. The Aerogels Handbook summarizes state-of-the-art developments and processing of inorganic, organic, and composite aerogels, including the most important methods of synthesis, characterization as well as their typical applications and their possible market impact. Readers will find an exhaustive overview of all aerogel materials known today, their fabrication, upscaling aspects, physical and chemical properties, and most recent advances towards applications and commercial products, some of which are commercially available today. Key Features: •Edited and written by recognized worldwide leaders in the field •Appeals to a broad audience of materials scientists, chemists, and engineers in academic research and industrial R&D •Covers inorganic, organic, and composite aerogels •Describes military, aerospace, building industry, household, environmental, energy, and biomedical applications among others



Synthesis Of Inorganic Nanomaterials


Synthesis Of Inorganic Nanomaterials
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Author : Sneha Mohan
language : en
Publisher: Woodhead Publishing
Release Date : 2018-06-29

Synthesis Of Inorganic Nanomaterials written by Sneha Mohan and has been published by Woodhead Publishing this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-06-29 with Technology & Engineering categories.


Synthesis of Inorganic Nanomaterials: Advances and Key Technologies discusses the latest advancements in the synthesis of various types of nanomaterials. The book's main objective is to provide a comprehensive review regarding the latest advances in synthesis protocols that includes up-to-date data records on the synthesis of all kinds of inorganic nanostructures using various physical and chemical methods. The synthesis of all important nanomaterials, such as carbon nanostructures, Core-shell Quantum dots, Metal and metal oxide nanostructures, Nanoferrites, polymer nanostructures, nanofibers, and smart nanomaterials are discussed, making this a one-stop reference resource on research accomplishments in this area. Leading researchers from industry, academia, government and private research institutions across the globe have contributed to the book. Academics, researchers, scientists, engineers and students working in the field of polymer nanocomposites will benefit from its solutions for material problems. Provides an up-to-date data record on the synthesis of all kinds of organic and inorganic nanostructures using various physical and chemical methods Presents the latest advances in synthesis protocols Includes the latest techniques used in the physical and chemical characterization of nanomaterials Covers the characterization of all the important materials groups, such as carbon nanostructures, core-shell quantum dots, metal and metal oxide nanostructures, Nano ferrites, polymer nanostructures and nanofibers



Advances In Aerogel Composites For Environmental Remediation


Advances In Aerogel Composites For Environmental Remediation
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Author : Aftab Aslam Parwaz Khan
language : en
Publisher: Elsevier
Release Date : 2021-05-29

Advances In Aerogel Composites For Environmental Remediation written by Aftab Aslam Parwaz Khan and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-05-29 with Science categories.


Advances in Aerogel Composites for Environmental Remediation presents both contextual information aboutaerogels and details about their application in environmental remediation. A wide variety of aerogels are discussed, rangingfrom common to advanced and from natural to synthetic. By exploring ongoing research and developments in the environmentalremediation technologies using aerogel and its composites, this book addresses common day-to-day environmental problemsand presents solutions to the use of aerogel materials. The chapters discuss fabrication of various aerogel composites, alongwith their design and applications toward different environmental remediation technologies. Additionally, the properties andadvantages of aerogels are compared and contrasted to those of traditional materials. Given the consistent increase in environmental pollution, there is an urgent need to explore new materials for advances in remediationtechnology. Advances in Aerogel Composites for Environmental Remediation brings researchers and practitionersin the fields of environmental remediation, environmental science, and engineering to the forefront of remediation technologieswith a thorough breakdown of the benefits of and techniques relevant to aerogel composites. Covers basic properties, unique properties, and fabrication techniques of aerogels, from basic silica aerogels topresent-day conventional aerogels Discusses most of the major environmental remediation techniques and the advantages of using aerogels for theseremediation techniques in comparison to using traditional methods Presents future prospects for utilizing aerogels in modern day-to-day life and in the fabrication of tangible new products



Polymer Nanocomposite Films And Coatings


Polymer Nanocomposite Films And Coatings
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Author : Mayank Pandey
language : en
Publisher: Elsevier
Release Date : 2024-01-22

Polymer Nanocomposite Films And Coatings written by Mayank Pandey and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-01-22 with Technology & Engineering categories.


Polymer Nanocomposite Films and Coatings: Processes, Fundamental Properties and Applications presents a comprehensive review on the fundamental chemistry, physics, biology and engineering aspects of polymer nanocomposite films and coatings.The content of the book covers design configuration, synthesis and processing methods, structure, fundamental properties, and a wide range of applications in diverse research fields. Various unresolved issues and new technical challenges regarding regulatory affairs, safety considerations and environmental and health impact are also discussed in detail.The book will be a valuable reference resource for scientists, engineers, and postgraduate students, working in the field of polymer composites and nanocomposites helping them to find solutions to both fundamental and applied problems associated with this important research field. Presents recent research developments in the synthesis, processing, functionalization, and properties of polymer nanocomposite films and coatings Covers applications in electronics and optoelectronic devices, sensors and actuators, solar energy, food packaging, anticorrosion, anti-wear, antifouling, electromagnetic interference shielding, dielectric, aerospace, and textile industries as well as in biomedical fields for antibacterial, antifungal, and drug delivery applications Includes comprehensive coverage with a global, internationally recognized author-base



Nanocomposites And Polymers With Analytical Methods


Nanocomposites And Polymers With Analytical Methods
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Author : John Cuppoletti
language : en
Publisher: BoD – Books on Demand
Release Date : 2011-08-09

Nanocomposites And Polymers With Analytical Methods written by John Cuppoletti and has been published by BoD – Books on Demand this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-08-09 with Science categories.


This book contains 16 chapters. In the first part, there are 8 chapters describing new materials and analytic methods. These materials include chapters on gold nanoparticles and Sol-Gel metal oxides, nanocomposites with carbon nanotubes, methods of evaluation by depth sensing, and other methods. The second part contains 3 chapters featuring new materials with unique properties including optical non-linearities, new materials based on pulp fibers, and the properties of nano-filled polymers. The last part contains 5 chapters with applications of new materials for medical devices, anodes for lithium batteries, electroceramics, phase change materials and matrix active nanoparticles.