The Solid State Chemistry Of Binary Metal Hydrides
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The Solid State Chemistry Of Binary Metal Hydrides By George G Libowitz
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Author : George G. Libowitz
language : en
Publisher:
Release Date : 1965
The Solid State Chemistry Of Binary Metal Hydrides By George G Libowitz written by George G. Libowitz and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1965 with categories.
The Solid State Chemistry Of Binary Metal Hydrides
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Author : George G. Libowitz
language : en
Publisher:
Release Date : 1965
The Solid State Chemistry Of Binary Metal Hydrides written by George G. Libowitz and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1965 with Hydrides categories.
The Kinetics Of Binary Metal Hydride Decomposition
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Author : Igor E. Gabis
language : en
Publisher:
Release Date : 2017
The Kinetics Of Binary Metal Hydride Decomposition written by Igor E. Gabis and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017 with Science categories.
Author Biography:Igor E. Gabis received his Ph.D. and Dr.Sci. degrees in Physics from Saint-Petersburg State University (Russia), where he has been working and currently is a full professor of the Department of Solid State Electronics. Research interests of Prof. Gabis include kinetics of interaction of hydrogen with metals and non-metallic solids, adsorption, diffusion and dissolution phenomena, hydrogen storage and purification, electronics of solids. For a number of years the research group of Prof. Gabis has been studying decomposition of binary metal hydrides.Book Description:From the point of view of hydrogen, desorption metal hydrides are extremely complex and interesting. Various metal hydrides differ so much, range in terms of decomposition temperatures and pressures and look like materials from separate classes. Many research articles are devoted to metal hydrides; many of them study the kinetics of dehydriding. However, there is still no complete understanding of the processes that govern kinetics. The reason is for the high number of factors that influence the rate of hydride decomposition and hydrogen desorption. First of all, properties of metal hydrides are diverse. The number of hydride phases, decomposition rates and ranges of absorbed energy are very different. The rates of hydrogen desorption, diffusion and phase transition also can influence the kinetics of dehydriding.The aim of this book is to summarise the authors'' research of dehydriding kinetics with electronic structures of the materials taken into account, and to determine which elementary processes influence the decomposition rates. The book is not a reference guide on the dehydriding rates of constants. Even more so, in order to keep the subject as simple as possible, the authors restrict the discussion only to binary hydrides when talking about basic dehydriding laws. It is possible, however, that ternary and more complex hydrides have their own unique properties.The authors describe experimental results through physically clear and well studied processes, such as desorption, diffusion, reaction of hydride decomposition, etc. as well as by using conservation laws. On the other hand, describing the entire process in the most general way, taking into account all of the possible reactions and excluding some on the grounds of experimental results, also seems unsound. The authors believe that complexity of models must be comparable to that of experimental data; additional factors should be taken into account only in order to improve poor fitting.The following factors seem the most important: Electronic properties of the hydride (type of bonding); phase morphology; incubation and nucleation; physically reasonable elementary processes mentioned above (diffusion, adsorption and desorption, decomposition and formation of the hydride phase, etc.); and the variety of powder particles.Over recent years, much effort has been made to activate the decomposition of magnesium and aluminium hydrides with the hope of finding appropriate materials for keeping hydrogen in solids aboard a vehicle. Most of the research dealt with mechanochemical activation (i.e., ball milling in the presence of catalysts, often in hydrogen). The choice of catalytic materials is not always logical; this was one more reason for systemizing the dehydriding kinetics. Naturally, activated materials must follow the general pattern of decomposing metal hydrides. A separate section is devoted to the activation of magnesium and aluminium hydrides; aside from mechanochemical, we also discuss the thermal and photoactivation of these materials.Target Audience:The book will be interesting to researchers who study metal hydrides; to students who study the condensed matter physics; to engineers of hydrogen energy industry, in particular to specialists in constructing hydrogen accumulators. Ideas proposed in the book can interest chemists who study chemical kinetics of metal compounds. In academy, the book can be used in masters courses on the condensed matter physics.
The Solid State Chemistry Of Binary Metal Hybrides
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Author :
language : en
Publisher:
Release Date : 1965
The Solid State Chemistry Of Binary Metal Hybrides written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1965 with categories.
Solid State Chemistry Of Energy Conversion And Storage
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Author : John B. Goodenough
language : en
Publisher:
Release Date : 1977
Solid State Chemistry Of Energy Conversion And Storage written by John B. Goodenough and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1977 with Science categories.
Metal Hydrides
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Author : William M. Mueller
language : en
Publisher: Elsevier
Release Date : 2013-09-12
Metal Hydrides written by William M. Mueller and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-09-12 with Science categories.
Metal Hydrides focuses on the theories of hydride formation as well as on experimental procedures involved in the formation of hydrides, the reactions that occur between hydrides and other media, and the physical and mechanical properties of the several classes of hydrides. The use of metal hydrides in the control of neutron energies is discussed, as are many other immediate or potential uses, e.g., in the production of high-purity hydrogen and in powder metallurgy. It is hoped that this book will serve as a valuable reference to students, research professors, and industrial researchers in metal hydrides and in allied fields. Selected chapters may serve specialists in other fields as an introduction to metal hydrides. The information contained herein will also be of lasting and practical value to the metallurgist, inorganic chemist, solid-state physicist, nuclear engineer, and others working with chemical or physical processes involving metal-hydrogen systems.
Hydrides
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Author : Patrick C. Dam
language : en
Publisher:
Release Date : 2018
Hydrides written by Patrick C. Dam and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018 with Science categories.
Hydrides: Types, Bonds and Applications first proposes metal hydrides as a fascinating class of compounds due to the small mass and size of hydrogen. Its medium electronegativity causes a large flexibility in terms of metal-ligand interactions, resulting in a vast variety of possible compositions, chemical bonding, crystal structures and physical properties. However, numerous unsolved problems remain on our way towards a sustainable, carbon free energy system based on renewable energy and on hydrogen as a future energy carrier. Thus, the authors present the structural details of alkali, alkali earth based selected tetra-boro hydrides. Selected hydrides have recently been suggested for applications in optoelectronics and as solid electrolytes for battery applications. Their use in optoelectronic devices depends on their stability with respect to doping, solubility of shallow donors and acceptors, electrical and optical properties. The authors describe the nature of the bonding in hydrides, and show how these affect the properties of these materials, focussing on application in the energy storage and in the transportation sector. Next, the features of gas discharge and plasma sources based on Penning trap with metal hydride cathodes are presented. In such devices, metal hydrides fulfill the functions of both a cathode and the solid-state generator of working gas. The authors determine that hydrogen desorbed from metal hydride significantly changes the properties of the discharge. This is expressed, for example, in the fact that the plasma source based on Penning trap with metal hydride cathode appears to generate current-compensated ion beams with the ability to control the energy of the extracted ions. Lastly, the book discusses metal hydrides obtaining in sintered electrodes of nickel-cadmium batteries with electrochemical methods by the way of electrolyte decomposition onto hydrogen and oxygen. It was shown that as a result of electrolyte decomposition, oxygen releases from batteries, while hydrogen partly releases and is partly (in virtue of its high diffusion permeability) accumulated in sintered matrices of electrodes of nickel-cadmium batteries in the metal hydrides form.
Handbook Of Solid State Chemistry 6 Volume Set
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Author : Richard Dronskowski
language : en
Publisher: John Wiley & Sons
Release Date : 2017-10-23
Handbook Of Solid State Chemistry 6 Volume Set written by Richard Dronskowski and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-10-23 with Technology & Engineering categories.
This most comprehensive and unrivaled compendium in the field provides an up-to-date account of the chemistry of solids, nanoparticles and hybrid materials. Following a valuable introductory chapter reviewing important synthesis techniques, the handbook presents a series of contributions by about 150 international leading experts -- the "Who's Who" of solid state science. Clearly structured, in six volumes it collates the knowledge available on solid state chemistry, starting from the synthesis, and modern methods of structure determination. Understanding and measuring the physical properties of bulk solids and the theoretical basis of modern computational treatments of solids are given ample space, as are such modern trends as nanoparticles, surface properties and heterogeneous catalysis. Emphasis is placed throughout not only on the design and structure of solids but also on practical applications of these novel materials in real chemical situations.
Nbs Special Publication
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Author :
language : en
Publisher:
Release Date : 1977
Nbs Special Publication written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1977 with Weights and measures categories.
Inorganic Hydrides
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Author : B. L. Shaw
language : en
Publisher: Elsevier
Release Date : 2013-10-22
Inorganic Hydrides written by B. L. Shaw and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Science categories.
Inorganic Hydrides focuses on the hydrides of chemical elements. The hydrides discussed in this book are classified into four principal categories — ionic, covalent, transition metal hydrides, and metallic hydrides. Hydrides that do not fit into general classification, such as hydrides of copper and zinc, can be described as borderline hydrides and form a transition in type between the covalent hydrides of the later elements of the periodic table and the metallic hydrides of the transition elements. This text begins with an introduction to the classes of hydrides and hydrides of hydrogen, discussing element by element through frequent comparisons. The transition metal hydrides and metallic hydrides are also elaborated. This selection concludes with the chapter on bonding and bond strengths in hydrides, followed by the applications of infrared, Raman, and nuclear magnetic resonance spectroscopy. The general chemistry of water and its solvent properties are also briefly deliberated. This publication is suitable for undergraduates, particularly on covering the developments and chemistry of inorganic hydrides.