The Structure Energetics And Dynamics Of Organic Ions
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The Structure Energetics And Dynamics Of Organic Ions
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Author : Tomas Baer
language : en
Publisher: John Wiley & Sons
Release Date : 1996-09-10
The Structure Energetics And Dynamics Of Organic Ions written by Tomas Baer and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-09-10 with Science categories.
Recent advances in both experimental techniques and theoretical methodologies have meant that increasingly sophisticated studies concerning the formation, structures, energetics and reaction dynamics of state- or energy-selected molecular ions can now be performed. In order to better serve the ion chemistry and physics community, each volume of this series is dedicated to reviewing a specific topic, emphasizing new experimental and theoretical developments in the study of ions. The Wiley Series in Ion Chemistry and Physics will help stimulate new research directions and point to future opportunities in the field of ion chemistry and physics. This volume, the fifth in the series, concentrates on the important area of organic ions. Our understanding of these ions has been significantly improved over the last decade due to both theoretical and experimental advances, and it is now routinely possible to calculate organic ion structures by ab initio molecular orbital methods with very high precision. At the same time, the experimental tools used to study organic ions have become much more refined. This volume provides a timely overview of some of the key approaches which are currently producing such important results in the study of negative ions, and contains seven chapters written by acknowledged experts in the field. It will be of great interest to both experts and newcomers, both of whom will benefit from the in-depth discussion of the latest methods and results.
Ions And Ion Pairs And Their Role In Chemical Reactions
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Author : J. Smid
language : en
Publisher: Elsevier
Release Date : 2013-09-03
Ions And Ion Pairs And Their Role In Chemical Reactions written by J. Smid and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-09-03 with Science categories.
Ions and Ion Pairs and their Role in Chemical Reactions covers a wide spectrum of ion pairing phenomena. This book focuses on the structure, dynamics, and energetics of ions and ion pairs and their complexes with solvent molecules and ion coordinating ligands in the solid, liquid, and gaseous state. Organized into 12 chapters, this book begins with an overview of the theory and complications involved in dipole moment measurements in slightly conductive polar solvents. This text then explores the measurement of gas phase ion-molecule equilibria by special spectrometric methods. Other chapters consider the NMR experiments on potassium biphenyl, sodium biphenyl, and rubidium biphenyl, dissolved in different solvents. This book discusses as well the ion pair formation of some cyclic conjugated carbanions and nitranions. The final chapter deals with the information obtained from relaxation measurements on processes such as ionic dissociation, aggregation, and solvent separation. This book is a valuable resource for chemists, organic chemists, and quantum chemists.
Cluster Ions
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Author : Cheuk-Yiu Ng
language : en
Publisher:
Release Date : 1993-11-30
Cluster Ions written by Cheuk-Yiu Ng and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1993-11-30 with Science categories.
Cluster Ions Edited by Cheuk-Yiu Ng, Ames Laboratory, Iowa State University, lowa, USA Tomas Baer, University of North Carolina, NC, USA Ivan Powis, University of Nottingham, UK As a result of many recent advances in both experimental techniques and theoretical methodologies, increasingly detailed and sophisticated studies concerning the formation, structures, energetics, and reaction dynamics of state- or energy-selected molecular ions can now be performed. In order better to serve the ion chemistry and physics communities, each volume of this series will be dedicated to reviewing a specific topic emphasizing new experimental and theoretical developments in the study of ions. This first volume is devoted to the physics and chemistry of clusters. Measurement of cluster ion properties, made as a function of cluster size, are expected to shed some light on the basic understanding of the transition from gas phase to condensed matter. The interest in cluster research is also motivated by the important roles that clusters play in many practical fields, such as catalysis and microelectronics. The authors of the seven chapters making up this volume are among the most active researchers in their respective areas. This series will help stimulate new research directions and point to future opportunities in the field of ion chemistry.
Unimolecular And Bimolecular Ion Molecule Reaction Dynamics
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Author : Cheuk-Yiu Ng
language : en
Publisher:
Release Date : 1994-09-06
Unimolecular And Bimolecular Ion Molecule Reaction Dynamics written by Cheuk-Yiu Ng and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994-09-06 with Science categories.
Unimolecular and Bimolecular Ion—Molecule Reaction Dynamics Cheuk-Yiu Ng, Ames Laboratory, Iowa State University, Iowa, USA Tomas Baer, University of North Carolina, NC, USA Ivan Powis, University of Nottingham, UK Recent advances in both experimental techniques and theoretical methodologies have meant that increasingly sophisticated studies concerning the formation, structures, energetics, and reaction dynamics of state- or energy-selected molecular ions can now be performed. In order to better serve the ion chemistry and physics community, each volume of this series will be dedicated to reviewing a specific topic, emphasizing new experimental and theoretical developments in the study of ions. This third volume is devoted to the study of unimolecular and bimolecular ionic processes. Special emphasis is given to studies related to planetary and interstellar ion chemistry and physics, the understanding of which has been a great impetus to the study of ion—molecule reactions. Each of the nine chapters making up this volume is written by a leading researcher in the respective field. This series will help stimulate new research directions and point to future opportunities in the fields of ion chemistry and physics.
The Structure Dependent Energy Of Organic Compounds
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Author : Árpád Furka
language : en
Publisher: Springer
Release Date : 2019-04-05
The Structure Dependent Energy Of Organic Compounds written by Árpád Furka and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-04-05 with Science categories.
This brief introduces readers to an alternative thermochemical reference system that makes it possible to use the heats of formation of organic compounds to deduce the energies that depend entirely on their structures, and which provides calculated values for most of the characteristic structures appearing in organic molecules. These structure-dependent energies are provided e.g. for selected compounds of normal and cyclic alkanes, open chain and cyclic olefins (including conjugated polyenes), alkynes, aromatic hydrocarbons and their substituted derivatives. The oxygen, sulfur and nitrogen derivatives of the above-mentioned compounds are also represented with calculated structure-dependent energies including alcohols, ethers, aldehydes and ketones, carboxylic acids, thiols, sulfides, amines, amides, heterocyclic compounds and others. Most organic reactions can be interpreted as the disappearance of certain structures and formation of others. If the structure-dependent energies are known, it can be shown how the disappearing and the newly formed structures contribute to the heat of reactions and to the driving forces. As experienced by the author, who pioneered the concept, structure dependent energies can help teachers to make organic chemistry more accessible for their students. Accordingly, the brief offers a valuable resource for all those who teach organic chemistry at universities, and for those who are learning it.
Molecular Reaction Dynamics
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Author : Raphael D. Levine
language : en
Publisher: Cambridge University Press
Release Date : 2009-06-04
Molecular Reaction Dynamics written by Raphael D. Levine and has been published by Cambridge University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-06-04 with Technology & Engineering categories.
Molecular reaction dynamics is the study of chemical and physical transformations of matter at the molecular level. The understanding of how chemical reactions occur and how to control them is fundamental to chemists and interdisciplinary areas such as materials and nanoscience, rational drug design, environmental and astrochemistry. This book provides a thorough foundation to this area. The first half is introductory, detailing experimental techniques for initiating and probing reaction dynamics and the essential insights that have been gained. The second part explores key areas including photoselective chemistry, stereochemistry, chemical reactions in real time and chemical reaction dynamics in solutions and interfaces. Typical of the new challenges are molecular machines, enzyme action and molecular control. With problem sets included, this book is suitable for advanced undergraduate and graduate students, as well as being supplementary to chemical kinetics, physical chemistry, biophysics and materials science courses, and as a primer for practising scientists.
Advanced Organic Chemistry
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Author : Reinhard Bruckner
language : en
Publisher: Academic Press
Release Date : 2002
Advanced Organic Chemistry written by Reinhard Bruckner and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002 with Science categories.
A best-selling mechanistic organic chemistry text in Germany, this text's translation into English fills a long-existing need for a modern, thorough and accessible treatment of reaction mechanisms for students of organic chemistry at the advanced undergraduate and graduate level. Knowledge of reaction mechanisms is essential to all applied areas of organic chemistry; this text fulfills that need by presenting the right material at the right level.
Fundamentals And Applications Of Gas Phase Ion Chemistry
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Author : K.R. Jennings
language : en
Publisher: Springer Science & Business Media
Release Date : 1999
Fundamentals And Applications Of Gas Phase Ion Chemistry written by K.R. Jennings and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999 with Science categories.
This book draws together leading workers in the fields of mass spectrometry and gas phase ion chemistry, providing a forum for the exchange of ideas and information. It contains 14 lecture summaries and accounts of seven workshops with contributions from Europe and North America.
Reactive Intermediate Chemistry
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Author : Robert A. Moss
language : en
Publisher: John Wiley & Sons
Release Date : 2004-01-07
Reactive Intermediate Chemistry written by Robert A. Moss and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-01-07 with Science categories.
Reactive Intermediate Chemistry presents a detailed and timely examination of key intermediates central to the mechanisms of numerous organic chemical transformations. Spectroscopy, kinetics, and computational studies are integrated in chapters dealing with the chemistry of carbocations, carbanions, radicals, radical ions, carbenes, nitrenes, arynes, nitrenium ions, diradicals, etc. Nanosecond, picosecond, and femtosecond kinetic realms are explored, and applications of current dynamics and electronic structure calculations are examined. Reactive Intermediate Chemistry provides a deeper understanding of contemporary physical organic chemistry, and will assist chemists in the design of new reactions for the efficient synthesis of pharmaceuticals, fine chemicals, and agricultural products. Among its features, this authoritative volume is: Edited and authored by world-renowned leaders in physical organic chemistry. Ideal for use as a primary or supplemental graduate textbook for courses in mechanistic organic chemistry or physical chemistry. Enhanced by supplemental reading lists and summary overviews in each chapter.
Molecular Ions
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Author : Terry Alan Miller
language : en
Publisher: North-Holland
Release Date : 1983
Molecular Ions written by Terry Alan Miller and has been published by North-Holland this book supported file pdf, txt, epub, kindle and other format this book has been release on 1983 with Science categories.