The Synthesis And Properties Of Novel Ferrocenyl Transition Metal Complexes And Other Ferrocenes For Potential Application In Catalysis And Materials Chemistry
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The Synthesis And Properties Of Novel Ferrocenyl Transition Metal Complexes And Other Ferrocenes For Potential Application In Catalysis And Materials Chemistry
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Author : Vincent Onserio Nyamori
language : en
Publisher:
Release Date : 2001
The Synthesis And Properties Of Novel Ferrocenyl Transition Metal Complexes And Other Ferrocenes For Potential Application In Catalysis And Materials Chemistry written by Vincent Onserio Nyamori and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001 with categories.
Ferrocenes
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Author : Antonio Togni
language : en
Publisher: John Wiley & Sons
Release Date : 2008-07-11
Ferrocenes written by Antonio Togni and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-07-11 with Science categories.
With applications ranging from asymmetric catalysis to magnetic materials, ferrocene is one of the most versatile building blocks in synthesis. This book captures the multidisciplinary nature of ferrocene research, including topics such as ferrocene-containing polymers, ferrocene-containing thermotropic liquid crystals, chiral ferrocene derivatives, and ferrocene-containing charge-transfer materials. In addition, the reader will find * valuable information for planning syntheses * over 70 tables, making relevant data available at a glance * carefully selected references, providing an easy access to the primary literature Up-to-date, and written by leading international experts in the field, among them R. Deschenaux, C. D. Hall, Y. Butsugan, and R. Herrmann, this book is a welcome source of in-depth information for graduate students and professionals in organic, organometallic, and polymer chemistry, as well as in materials science.
Synthesis Properties And Applications Of Ferrocene Based Derivatives Polymers And Hydrogels
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Author : Li Wang
language : en
Publisher: Springer
Release Date : 2018-04-02
Synthesis Properties And Applications Of Ferrocene Based Derivatives Polymers And Hydrogels written by Li Wang and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-04-02 with Technology & Engineering categories.
After an introduction to their fundamentals and history, this book systematically reviews ferrocene-based compounds, polymers and hydrogels. It explains in detail the synthetic methods for and properties of each ferrocene-based compound, polymer and hydrogel, and also extensively discusses their applications, including electrochemistry, catalysis and sensors. An outlook chapter on remaining challenges and future perspectives rounds out the coverage. Providing a wealth of valuable information on ferrocene-related studies, the book appeals to researchers, professionals and graduate students working in the fields of organic and polymer chemistry, as well as materials science.
Chiral Ferrocenes In Asymmetric Catalysis
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Author : Li-Xin Dai
language : en
Publisher: John Wiley & Sons
Release Date : 2010-02-01
Chiral Ferrocenes In Asymmetric Catalysis written by Li-Xin Dai and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010-02-01 with Science categories.
This book meets the long-felt need for a reference on ferrocenes with the focus on catalysis. It provides a thorough overview of the synthesis and characterization of different types of chiral ferrocene ligands, their application to various catalytic asymmetric reactions, and versatile chiral materials as well as drug intermediates synthesized from them. Written by the "who's who" of ferrocene catalysis, this is a guide to the design of new ferrocene ligands and synthesis of chiral synthetic intermediates, and will thus be useful for organic, catalytic and synthetic chemists working in academia, industrial research or process development.
Ferrocenes
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Author : Elisabeth S. Phillips
language : en
Publisher: Nova Science Publishers
Release Date : 2011
Ferrocenes written by Elisabeth S. Phillips and has been published by Nova Science Publishers this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011 with Ferrocene categories.
Ferrocene is an organometallic compound. It is the prototypical metallocene, a type of organometallic chemical compound consisting of two cyclopentadienyl rings bound on opposite sides of a central metal atom. Such organometallic compounds are also known as sandwich compounds. The rapid growth of organometallic chemistry is often attributed to the excitement arising from the discovery of ferrocene and its many analogues. This book presents current research from across the globe in the study of ferrocenes, including the synthesis of pristine and doped carbon nanotubes using ferrocene; the transition metal catalysed coupling and carbonylation reactions of ferrocene derivatives; and the exploitation of ferrocene for the development of mechanically interlocked and non-interlocked synthetic molecular machines.
Ferrocenes
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Author : Petr Stepnicka
language : en
Publisher: John Wiley & Sons
Release Date : 2008-04-15
Ferrocenes written by Petr Stepnicka and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-04-15 with Science categories.
Ferrocene—the prototypical metallocene—is a fascinating molecule. Even though it was first discovered over fifty years ago, research into ferrocene-containing compounds continues apace, largely stimulated by their successful applications in catalysis, materials science and bioorganometallic chemistry. Ferrocene derivatives are now recognised as useful starting materials for the preparation of new organometallic complexes and functional materials, efficient catalyst components, as well as redox-active modifiers to biomolecules. Ferrocenes: Ligands, Materials and Biomolecules provides the reader with a background overview and describes recent advances in the development and application of ferrocene compounds, including: synthesis and catalytic utilisation of chiral and non-chiral ferrocene ligands ferrocene-based sensors electrooptical materials ferrocene polymers liquid-crystalline materials crystal engineering with ferrocene compounds the bioorganometallic chemistry of ferrocene Ferrocenes: Ligands, Materials and Biomolecules is an essential guide for anyone working in the fields of organometallic synthesis and catalysis, materials science and bioorganometallic chemistry.
Metallocenes
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Author : Antonio Togni
language : en
Publisher: Wiley-VCH
Release Date : 1998-10-15
Metallocenes written by Antonio Togni and has been published by Wiley-VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998-10-15 with Science categories.
That terms like sandwich complexes or the concept of compounds without direct chemical bonds between the central metal atom and the ligating atoms are nowadays common knowledge can be attributed to the sensational discovery of ferrocene in the early 1950s. Although ferrocene is still at the forefront of research, this two-volume book highlights the development of metallocene chemistry, and emphasizes the similarities and differences between ferrocene and other metallocenes. Do you require a transition metal to build metallocenes? Must the planes of the cyclopentadienyl ligands be parallel to allow the compound to behave like a typical metallocene? Do zirconocenes react by the same mechanism as molybdenocenes? What are the (potential) applications of these substances? Let yourself be guided by the leading experts in this field, and learn all about the synthesis, reactivity, and unique properties of these sandwich complexes. If you are more interested in applications, there is a wealth of polymeric and dendritic materials with metallocene building blocks described herein. This book also focusses on metallocenes as catalysts in polymerization or asymmetric reactions. If you are graduate student or researcher in organic, inorganic, organometallic, polymer chemistry, and materials science you will find this book an inspiring source of ideas for your own research.
Transition Metal Catalyzed Carbene Transformations
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Author : Jianbo Wang
language : en
Publisher: John Wiley & Sons
Release Date : 2022-05-16
Transition Metal Catalyzed Carbene Transformations written by Jianbo Wang and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-05-16 with Science categories.
Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer. Highlights the dynamic nature of the field of transition-metal-catalyzed carbene transformations Summarizes the catalytic radical approach for selective carbene cyclopropanation, high enantioselectivity in X-H insertions, and bio-inspired carbene transformations Introduces chiral N,N'-dioxide and chiral guanidine-based catalysts and different transformations with gold catalysis Discusses approaches in cycloaddition reactions with metal carbenes and polymerization with carbene transformations Outlines multicomponent reactions through gem-difunctionalization and transition-metal-catalyzed cross-coupling using carbene precursors Transition Metal-Catalyzed Carbene Transformations is essential reading for all chemists involved in organometallics, including organic and inorganic chemists, catalytic chemists, and chemists working in industry.
Synthesis Of Metal Complexes Supported By Ferrocene Based Ligands For Tandem Catalysis And Applications Toward Liquid Cell Quantum Sensing
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Author : Yi Shen
language : en
Publisher:
Release Date : 2023
Synthesis Of Metal Complexes Supported By Ferrocene Based Ligands For Tandem Catalysis And Applications Toward Liquid Cell Quantum Sensing written by Yi Shen and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023 with categories.
Developing methodologies to synthesize high-value products efficiently from simple substrates with control over the reactivity and selectivity is highly favored by the chemical industry. Employing assisted tandem catalysis, where serial reactions can be carried out in one pot, to achieve streamlined complex syntheses significantly reduces the number of steps and waste. Harnessing spatial and temporal control in catalysis enables approaches toward one-pot transformations and allows the integration of several catalytic processes. Ferrocene-based ligand-supported metal complexes represent a promising class of catalysts that can incorporate redox control over catalytic processes. We have developed a redox-controlled selective hydroamination reaction catalyzed by (thiolfan*)Zr(NEt2)2 (thiolfan*= 1, 1'-bis (2,4-di-tert-butyl-6-thiophenoxy)ferrocene). In situ switching of the catalyst's state during the reaction enables selectivity toward different substrates (Chapter 2).Incorporating the greenhouse gas CO2 into N-carboxyanhydrides (NCAs) followed by subsequent NCA utilization illustrates the possibility of integrating two synthetic steps in one vessel to afford a valuable material with possible CO2 recycling. To demonstrate the immense potential of integrating multi-step transformations in one pot, we developed a set of sustainable conditions for NCA synthesis (Chapter 3). Moreover, several metal catalysts supported by ferrocene-based ligands were found to catalyze NCA polymerization in the presence of a co-catalyst. To establish an integrated system composed of two incompatible processes, we aimed to compartmentalize the active reagents for each step. The structure of the ferrocene-based pro-ligand was modified for surface anchoring. Our efforts toward immobilizing ferrocene-supported metal catalysts onto conductive surfaces pave the way of achieving spatiotemporal control over the processes of NCA synthesis and polymerization (Chapter 4). In addition to the redox-switchable characteristic, ferrocene-based compounds provide a unique platform to support lanthanides and engender distinctive optical properties to them. We synthesized and characterized a series of ytterbium complexes displaying an ultra-narrow absorption in the ultraviolet-visible (UV-Vis) region. The extraordinarily narrow linewidth observed for (thiolfan)YbCl(THF) (thiolfan = 1,1'-bis(2,4-di-tert-butyl-6-thiomethylenephenoxy)ferrocene) allows us to investigate its applications toward magnetic field and liquid cell quantum sensing (Chapter 5).
Transition Metals In Coordination Environments
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Author : Ewa Broclawik
language : en
Publisher: Springer
Release Date : 2019-03-16
Transition Metals In Coordination Environments written by Ewa Broclawik and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-03-16 with Science categories.
This book focuses on the electronic properties of transition metals in coordination environments. These properties are responsible for the unique and intricate activity of transition metal sites in bio- and inorganic catalysis, but also pose challenges for both theoretical and experimental studies. Written by an international group of recognized experts, the book reviews recent advances in computational modeling and discusses their interplay using experiments. It covers a broad range of topics, including advanced computational methods for transition metal systems; spectroscopic, electrochemical and catalytic properties of transition metals in coordination environments; metalloenzymes and biomimetic compounds; and spin-related phenomena. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in both fundamental and application-oriented research in the field of transition metal systems.
