Thermodynamics Of Polymer Blends Volume I
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Thermodynamics Of Polymer Blends Volume I
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Author : Anatoly E. Nesterov
language : en
Publisher: CRC Press
Release Date : 2020-02-03
Thermodynamics Of Polymer Blends Volume I written by Anatoly E. Nesterov and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-02-03 with Technology & Engineering categories.
Thermodynamics is an indispensable tool for developing a large and growing fraction of new polymers and polymer blends. These two volumes show the researcher how thermodynamics can be used to rank polymer pairs in order of immiscibility, including the search for suitable chemical structure of compatibilizers. Because of the great current commercial interest in this most dynamic sector of the polymer industry, there is high interest in studying their physical and mechanical properties, their structures, and the processes of their formation and manufacture. These Books are dedicated to Analysis of the Thermodynamics of Polymer Blends. Thermodynamic behavior of blends determines the compatibility of the components, their morphological features, rheological behavior, and microphase structures. As a result, the most important physical and mechanical characteristics of blends can be identified. The information in these two volumes will be useful to all those involved in polymer research, development, analysis and advanced process engineering.
Polymer Blends Volume 1
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Author : Donald R Paul
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Polymer Blends Volume 1 written by Donald R Paul and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Technology & Engineering categories.
Polymer Blends, Volume 1 highlights the importance of polymer blends as a major new branch of macromolecular science. Topics range from polymer-polymer compatibility and the statistical thermodynamics of polymer blends to the phase separation behavior of polymer-polymer mixtures, transport phenomena in polymer blends, and mechanical properties of multiphase polymer blends. The optical behavior, solid state transition behavior, and rheology of polymer blends are also discussed. This book is organized into 10 chapters and begins with an overview of polymer blends, with emphasis on terminology and the effect of molecular weight on the thermodynamics of polymer blends as well as phase equilibria and transitions. The discussion then turns to the miscibility of homopolymers and copolymers, in bulk and in solution, from the experimental and theoretical viewpoints. The chapters that follow explore the statistical thermodynamics of polymer blends, paying particular attention to the Flory and lattice fluid theories, along with the phase relationship in polymer mixtures. The interfacial energy, structure, and adhesion between polymers in relation to the properties of polymer blends are considered. The final chapter examines the phenomena of low molecular weight penetrant transport. Currently accepted models for unsteady-state and steady-state permeation of polymeric materials are presented. A discussion of unsteady-state absorption and desorption behavior observed in a variety of polymer blends complements the treatment of permeation behavior. This book is intended to provide academic and industrial research scientists and technologists with a broad background in current principles and practice concerning mixed polymer systems.
Concepts In Polymer Thermodynamics Volume Ii
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Author : Menno A. van Dijk
language : en
Publisher: CRC Press
Release Date : 2023-04-14
Concepts In Polymer Thermodynamics Volume Ii written by Menno A. van Dijk and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-04-14 with Technology & Engineering categories.
Thermodynamics is an indispensable tool for developing a large and growing fraction of new polymers and polymer blends. These two volumes show the researcher how thermodynamics can be used to rank polymer pairs in order of immiscibility, including the search for suitable chemical structure of compatibilizers. Because of the great current commercial interest in this most dynamic sector of the polymer industry, there is high interest in studying their physical and mechanical properties, their structures, and the processes of their formation and manufacture. These Books are dedicated to Analysis of the Thermodynamics of Polymer Blends. Thermodynamic behavior of blends determines the compatibility of the components, their morphological features, rheological behavior, and microphase structures. As a result, the most important physical and mechanical characteristics of blends can be identified.
Polymer Thermodynamics
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Author : Kal Renganathan Sharma
language : en
Publisher: CRC Press
Release Date : 2011-10-10
Polymer Thermodynamics written by Kal Renganathan Sharma and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-10-10 with Science categories.
Polymer Thermodynamics: Blends, Copolymers and Reversible Polymerization describes the thermodynamic basis for miscibility as well as the mathematical models used to predict the compositional window of miscibility and construct temperature versus volume-fraction phase diagrams. The book covers the binary interaction model, the solubility parameter
Thermodynamics Of Polymer Blends Volume I
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Author : Anatoly E. Nesterov
language : en
Publisher: CRC Press
Release Date : 2020-02-03
Thermodynamics Of Polymer Blends Volume I written by Anatoly E. Nesterov and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-02-03 with Science categories.
Thermodynamics is an indispensable tool for developing a large and growing fraction of new polymers and polymer blends. These two volumes show the researcher how thermodynamics can be used to rank polymer pairs in order of immiscibility, including the search for suitable chemical structure of compatibilizers. Because of the great current commercial interest in this most dynamic sector of the polymer industry, there is high interest in studying their physical and mechanical properties, their structures, and the processes of their formation and manufacture. These Books are dedicated to Analysis of the Thermodynamics of Polymer Blends. Thermodynamic behavior of blends determines the compatibility of the components, their morphological features, rheological behavior, and microphase structures. As a result, the most important physical and mechanical characteristics of blends can be identified. The information in these two volumes will be useful to all those involved in polymer research, development, analysis and advanced process engineering.
Polymer Blends
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Author : Donald R. Paul
language : en
Publisher:
Release Date : 1978
Polymer Blends written by Donald R. Paul and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1978 with Polymerization categories.
Thermodynamics Of Systems Containing Flexible Chain Polymers
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Author : V.J. Klenin
language : en
Publisher: Elsevier
Release Date : 1999-06-03
Thermodynamics Of Systems Containing Flexible Chain Polymers written by V.J. Klenin and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999-06-03 with Technology & Engineering categories.
This book deals with the problems of the thermodynamics of systems containing flexible-chain polymers as the basis of polymer material science. The main thermodynamic quantities and concepts are introduced and discussed in the order of the objects getting more and more complicated: gases, magnets, low-molecular-weight substances and mixtures, and finally, polymers and polymer blends. All topics are considered in a common clue, using the principle of universality. The stability conditions for the one-phase state of multi-component systems are given. Phase separation is regarded as a result of loss in stability. The critical state of a system, with the one-phase state being close to the boundary of stability conditions breaking, is discussed in detail. The effects of both light scattering (elastic and dynamic) and diffusion, as directly depending on the thermodynamic parameters characterizing the one-phase state stability, are considered in detail. One of the versions of colloid scattering, namely, the turbidity spectrum method, is described as useful for the characterization of various heterogeneous structures and for the phase analysis of polymer systems. In the approximation of mean field theories and advanced field theory, formalisms expound the following divisions of the thermodynamics of binary and polynary systems with flexible-chain polymers: conformation of the polymer coil, composition fluctuations, elastic and dynamic light scattering, diffusion in the one-phase state (including the critical range), phase separation, polymer fractionation, the coil-globule transition, phase equilibrium and separation in the system network polymer + low-molecular-weight liquid, polymer blends and multiphase separation.
Specific Interactions And The Miscibility Of Polymer Blends
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Author : Michael M. Coleman
language : en
Publisher: CRC Press
Release Date : 2017-11-13
Specific Interactions And The Miscibility Of Polymer Blends written by Michael M. Coleman and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-11-13 with Technology & Engineering categories.
This book with software provides powerful tools for the analysis, prediction and creation of new polymer blends, an area of significant commercial potential. The R&D approaches and methods described in the book have attracted the interest of polymer R&D leaders in industry, and have been put into use in several major chemical companies. The companion set of computer programs speeds and facilitates work in this area. FROM THE AUTHORS' PREFACE: During the 1980's a steadily increasing number of compatible systems [polymer blends] have been reported. We believe that miscible mixtures will prove to be fairly common and the purpose of this book is to explore the circumstances in which single phase materials can be obtained. We will also describe a model for the phase behavior of these mixtures which we believe to have a predictive value, or be used as a practical guide to polymer miscibility. Our approach is based on the use of association models which have until recently been largely ignored in treating hydrogen bonding in polymer mixtures. They have most frequently been applied to mixtures of alcohols with simple hydrocarbons, where the equilibrium constants used to describe association have most frequently been determined by a fit to thermodynamic data (e.g., vapor pressures, heat of mixing). In our work we have sought to, first, adapt this approach to a description of the phase behavior of polymer mixtures; second, develop spectroscopic methods that provide an independent measurement of the equilibrium constants. Our purpose in this book is to explore and describe this approach and illustrate its broad utility. We address two overlapping yet different audiences. One would be primarily interested in the broad nature of this approach and the practical applications of a simple model. The second would be more interested in the derivations of the equations and some of the fundamental aspects of the spectroscopy of these systems. Accor
Thermodynamics Of Polymer Blends
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Author : Dimitra Manda
language : en
Publisher:
Release Date : 1998
Thermodynamics Of Polymer Blends written by Dimitra Manda and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998 with categories.
Polymer Blends Volume 1
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Author : Donald R Paul
language : en
Publisher: Academic Press
Release Date : 1978-10-28
Polymer Blends Volume 1 written by Donald R Paul and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1978-10-28 with Technology & Engineering categories.
Polymer Blends, Volume 1 highlights the importance of polymer blends as a major new branch of macromolecular science. Topics range from polymer-polymer compatibility and the statistical thermodynamics of polymer blends to the phase separation behavior of polymer-polymer mixtures, transport phenomena in polymer blends, and mechanical properties of multiphase polymer blends. The optical behavior, solid state transition behavior, and rheology of polymer blends are also discussed. This book is organized into 10 chapters and begins with an overview of polymer blends, with emphasis on terminology and the effect of molecular weight on the thermodynamics of polymer blends as well as phase equilibria and transitions. The discussion then turns to the miscibility of homopolymers and copolymers, in bulk and in solution, from the experimental and theoretical viewpoints. The chapters that follow explore the statistical thermodynamics of polymer blends, paying particular attention to the Flory and lattice fluid theories, along with the phase relationship in polymer mixtures. The interfacial energy, structure, and adhesion between polymers in relation to the properties of polymer blends are considered. The final chapter examines the phenomena of low molecular weight penetrant transport. Currently accepted models for unsteady-state and steady-state permeation of polymeric materials are presented. A discussion of unsteady-state absorption and desorption behavior observed in a variety of polymer blends complements the treatment of permeation behavior. This book is intended to provide academic and industrial research scientists and technologists with a broad background in current principles and practice concerning mixed polymer systems.