Vibronic Processes In Inorganic Chemistry
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Vibronic Processes In Inorganic Chemistry
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Author : Colin D. Flint
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Vibronic Processes In Inorganic Chemistry written by Colin D. Flint and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
This volume reports the main lectures and seminars given at the NATO Advanced Study Institute on Vibronic Processes in Inorganic Chemistry held at Riva del Sole, Tuscany, Italy between 7th and 18th September 1988. In addition to the about 40 hours of lectures repres ented by this volume, a further fifteen lectures on current research topics were given by the other participants. Many factors contributed to the decision to hold this ASI but the final trigger was given at a meeeting in Padova when Marco Bettinelli, Lorenzo Disipio and Gianluigi Ingletto asked me to recommend a text where the diverse conceptual, spectroscopic and structural consequences of the impossibility of treating the motions of the electrons and nuclei independantly in inorganic compounds were presented. There seemed to be no suitable comprehensive text where the relationship between the relatively simple theoretical ideas and the huge range of their application in inorganic chemistry and physics was developed. The Institute and this text are a contribution to filling this gap. Seventy-nine participants from fifteen countries attended the Institute. Topics raised in the lectures and from the participants own research frequently led to discussions which went on long into the night.
Vibronic Processes In Inorganic Chemistry
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Author : Colin D Flint
language : en
Publisher:
Release Date : 1989-08-31
Vibronic Processes In Inorganic Chemistry written by Colin D Flint and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989-08-31 with categories.
Vibronic Coupling Density
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Author : Tatsuhisa Kato
language : en
Publisher: Springer Nature
Release Date : 2021-06-18
Vibronic Coupling Density written by Tatsuhisa Kato and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-06-18 with Science categories.
This book introduces vibronic coupling density and vibronic coupling constant analyses as a way to understand molecular structure and chemical reactions. After quantum study, the behavior of electrons circulating around nuclei led to the principal concept that underlies all explanations in chemistry. Many textbooks have given plausible explanations to clarify molecular structure—for example, the bond elongation of ethylene under anionization and the nonplanar structure of ammonia. Frontier molecular orbital concepts were proposed to visualize the path of chemical reactions, and conventional explanations gave students a familiarity with molecular structures in terms of the electronic state. By contrast, this book offers a more rational and more convincing path to understanding. It starts from the ab initio molecular Hamiltonian and provides systematic, rational approaches to comprehend chemical phenomena. In this way, the book leads the reader to a grasp of the quantitative evaluation of the force applied under the molecular deformation process. As well, guidelines are offered for integrating the traditional “hand-waving” approach of chemistry with more rational and general VCD and VCC alternatives along with the outlook for newly functionalized chemical systems.
Inorganic Vibrational Spectroscopy
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Author : Llewellyn H. Jones
language : en
Publisher:
Release Date : 1971
Inorganic Vibrational Spectroscopy written by Llewellyn H. Jones and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1971 with Science categories.
Transition Metal And Rare Earth Compounds
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Author : Hartmut Yersin
language : en
Publisher: Springer
Release Date : 2003-07-01
Transition Metal And Rare Earth Compounds written by Hartmut Yersin and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-07-01 with Science categories.
There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4– lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements.
Group Theory Applied To Chemistry
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Author : Arnout Jozef Ceulemans
language : en
Publisher: Springer Nature
Release Date :
Group Theory Applied To Chemistry written by Arnout Jozef Ceulemans and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on with categories.
Transition Metal And Rare Earth Compounds Iii
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Author : Hartmut Yersin
language : en
Publisher: Springer Science & Business Media
Release Date : 2004-11-18
Transition Metal And Rare Earth Compounds Iii written by Hartmut Yersin and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-11-18 with Science categories.
With contribution by numerous experts
The Jahn Teller Effect In C60 And Other Icosahedral Complexes
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Author : C. C. Chancey
language : en
Publisher: Princeton University Press
Release Date : 2021-02-09
The Jahn Teller Effect In C60 And Other Icosahedral Complexes written by C. C. Chancey and has been published by Princeton University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-02-09 with Science categories.
Because of the high symmetry involved, the Jahn-Teller effect is the natural starting point for considering electron-phonon (or vibronic) interactions in icosahedral molecules. This work is the first comprehensive theoretical analysis of the Jahn-Teller interaction in C60 and other icosahedral complexes. The importance of this research derives in part from the increasing, widespread interest in C60 and other molecular clusters and their application in science and industry. The electrical and spectroscopic properties of fullerene and fulleride compounds depend intimately on the coupling between the electronic and vibrational modes of these systems, and this book addresses the fundamental theoretical questions. In particular, a chapter is devoted to the connection between the theory and experimental observations, such as ESR (electron spin resonance) effects and molecular spectra. Earlier books have discussed the theory of Jahn-Teller interactions in lower symmetry structures (cubic, tetrahedral, tetragonal, trigonal,...); this is the first that focuses on the new icosahedral systems, whose most famous example is Buckminsterfullerene, C60. The book's authors have over fifty years of combined research experience into the theoretical aspects of the Jahn-Teller effect.
Excited States Of Transition Elements Proceedings Of The 2nd International School
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Author : Strek W
language : en
Publisher: World Scientific
Release Date : 1992-09-30
Excited States Of Transition Elements Proceedings Of The 2nd International School written by Strek W and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-09-30 with categories.
This book presents the recent advances in spectroscopy and theoretical modeling relevant to the interpretation of luminescence and laser phenomena in solid state materials. The available solid state matrices in crystalline and glassy states and the full range of activaters-transition metal ions, rare earth ions and actinides are considered here. Processes of activator excitation, energy transfer between activators and relaxation of excited states are particularly stressed.
Crystal Fields For Transition Metal Ions In Laser Host Materials
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Author : Clyde A. Morrison
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Crystal Fields For Transition Metal Ions In Laser Host Materials written by Clyde A. Morrison and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
A researcher trying to predict or interpret spectra of transition metal ionsin possible laser host materials is confronted with a variety of different methods of describing the same physical situation. This book provides a systematic approach to the applied theory of crystal-field interactions of transition metal ions in 49 crystalline hosts that are or show promise of being good laser materials. The tables that make up the main part of the book present the experimentally determined parameters of the 3dN, 4dN, and 5dN transition-metal ions in the second, third, and fourth ionization states. These parameters have been converted to Slater and crystal-field parameters. The book is a source for research workers in laser development and in crystal-field theory, and for graduate students of solid state chemistry and physics.