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Acetylene And Its Polymers


Acetylene And Its Polymers
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Acetylene And Its Polymers


Acetylene And Its Polymers
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Author : Seth C. Rasmussen
language : en
Publisher: Springer
Release Date : 2018-07-21

Acetylene And Its Polymers written by Seth C. Rasmussen and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-07-21 with Science categories.


This Brief presents for the first time a detailed historical overview of the development of acetylene polymers, beginning with the initial discovery of acetylene in 1836 and continuing up through the 2000 Nobel Prize in Chemistry. The polymerization of acetylene is most commonly associated with polyacetylene, which was found to be conductive when treated with oxidizing agents such as Br2 or I2 in the mid‐to‐late 1970s. In fact, under the right conditions, oxidized polyacetylenes can exhibit conductivities into the metallic regime, thus providing the first example of an organic polymer exhibiting metallic conductivity. As a consequence, the 2000 Nobel Prize in Chemistry was awarded to Hideki Shirakawa, Alan MacDiarmid, and Alan Heeger for this pioneering research, the award citation reading “for the discovery and development of electrically conductive polymers.” Because of this, most incorrectly view polyacetylene, as well as conducting polymers in general, to originate in the 1970s. In this work, the author examines the polymerization of acetylene from early thermal polymerization studies to the ultimate production of the fully conjugated polyacetylene. Although true polyacetylene was not successfully produced until the 1950s by Giulio Natta, the polymerization of acetylene dates back to 1866 with the work of Marcellin Berthelot. These initial efforts were continued by a range of scientists to produce a polymeric material collectively given the name cuprene in 1900 by Paul Sabatier. Between the initial cuprene studies and the production of true polyacetylene, two related materials were also studied, usually referred to as polyenes and polyvinylenes. Although both of these materials could be thought of as forms of polyacetylene, neither was actually generated from the direct polymerization of acetylene. Readers will gain insight into the fact that polyacetylene and conducting organic polymers have a much longer history than commonly believed and involved the work of a significant number of Nobel Laureates.



Polyacetylene


Polyacetylene
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Author : James C.W. Chien
language : en
Publisher: Elsevier
Release Date : 2012-12-02

Polyacetylene written by James C.W. Chien and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.


Polyacetylene: Chemistry, Physics, and Material Science reviews the chemistry, physics, and material science of polyacetylene. Topics covered include polymerization and crystal structure of polyacetylene, isomerization, neutral defects, and solitons. Globular morphology and the effect of heat of polymerization on polyacetylene are also discussed, along with doping and chemical reactions of polyacetylene. This book is comprised of 12 chapters and begins with an introduction to a few basic principles of polymer chemistry and solid-state physics, followed by an overview of charge-transfer salts and conducting polymers other than polyacetylene and a historical background on polyacetylene and a general description of its properties. The next chapter gives a detailed treatment of polymerization, with particular reference to the mechanisms and kinetics of acetylene polymerization and direct determination of polyacetylene molecular weight by radioquenching. The remaining chapters focus on the crystal structures and morphology of undoped polyacetylenes; methods of isomerization; spectroscopic, physical, and mechanical properties of undoped polyacetylene; and various chemical reactions of polyacetylene and polymethylacetylene. The probable mechanisms of doping are proposed and theoretical models for polyacetylene are presented. The final chapter considers a few technical applications of polyacetylene. This monograph will be of interest to chemists, physicists, and polymer scientists and engineers.



Manufacture Of Fine Chemicals From Acetylene


Manufacture Of Fine Chemicals From Acetylene
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Author : Sifang Li
language : en
Publisher: Walter de Gruyter GmbH & Co KG
Release Date : 2021-07-19

Manufacture Of Fine Chemicals From Acetylene written by Sifang Li and has been published by Walter de Gruyter GmbH & Co KG this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-07-19 with Science categories.


The book gives a complete overview on today’s research, development and industrialization of fine chemicals from acetylene. The author provides a comprehensive methodology by covering derivatives from acetylene reacting with formaldehyde, alcohol, ketone, halogen and acetic acid. The book offers extensive and practical reference work for chemists and chemical engineers as well as university teachers and students.



The Chemistry Of Acetylene


The Chemistry Of Acetylene
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Author : Julius Arthur Nieuwland
language : en
Publisher:
Release Date : 1945

The Chemistry Of Acetylene written by Julius Arthur Nieuwland and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1945 with Science categories.




Acetylene Chemistry


Acetylene Chemistry
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Author : François Diederich
language : en
Publisher: John Wiley & Sons
Release Date : 2006-03-06

Acetylene Chemistry written by François Diederich and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-03-06 with Science categories.


Acetylenes are an important and valuable class of compounds in organic synthesis. This book expands on this historically well-established concept, while incorporating the many new developments that have widened the number of applications in this field. It remains the only handbook available that embodies all the important facets of acetylene chemistry. Following the first section on synthesis, the leading authors deal with advanced materials before turning to the properties and theory of acetylenes, while a final section looks at the biological aspects. With its range of experimental procedures, this book is a practical aid for both organic and organometallic chemists, as well as for materials scientists, biochemists, and industrial chemists.



Styrene Its Polymers Copolymers And Derivatives


Styrene Its Polymers Copolymers And Derivatives
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Author : Ray H. Boundy
language : en
Publisher:
Release Date : 1952

Styrene Its Polymers Copolymers And Derivatives written by Ray H. Boundy and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1952 with Styrene categories.




Conductive Polymers


Conductive Polymers
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Author : Raymond B. Seymour
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Conductive Polymers written by Raymond B. Seymour and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


Those who recognize that our modern life style is dependent, to a large extent, on the use of organic polymers as thermal and elec trical insulators, may be surprised to learn that specific plastics may also be used as conductors of electricity. In addition to demon strating the versatility of polymers, this use as conductors will lead to developments which were not possible with other available materials of construction. This is a new field which is growing rapidly because of intensive research and developmental efforts by many different industrial, governmental and university investigators. Many of these researchers reported advances in this art at a symposium on conductive polymers sponsored by the American Chemical Society's Division of Organic Coatings and Plastics Chemistry held at the Second Chemical Congress of the North American Continent at Las Vegas, in August 1980. The proceedings of this timely symposium are presented in this book. The editor wishes to take this opportunity to express his grati tude to the authors who contributed to this book and to the ACS Organic Coatings and Plastics Division for sponsoring this effort. Raymond B. Seymour Department of Polymer Science University of Southern Mississippi Hattiesburg, MS 39401 v CONTENTS 1 New Horizons in Conductive Polymers Raymond B. Seymour Synthesis and Characterization of Conductive 7 Palladium Containing Polyimide Films • T.L. Wohlford. J. Schaff. L.T. Taylor.



Modern Acetylene Chemistry


Modern Acetylene Chemistry
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Author : Peter J. Stang
language : en
Publisher: John Wiley & Sons
Release Date : 2008-09-26

Modern Acetylene Chemistry written by Peter J. Stang and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-09-26 with Science categories.


This comprehensive handbook presents the full potential of modern acetylene chemistry, from organic synthesis through materials science to bioorganic chemistry. K. Houk, H. Hopf, P. Stang, K. M. Nicholas, N. Schore, M. Regitz, K. C. Nicolaou, R. Gleiter, L. Scott, R. Grubbs, H. Iwamura, J. Moore, and F. Diederich - internationally renowned authors introduce the reader, in a didactically skilful manner, to the state-of-the-art in alkyne chemistry. Emphasis is placed on presenting carefully selected and instructive examples as well as essential references to the original literature. Special benefits: Each chapter is rounded off by useful experimental procedures.



Acetylene Chemistry


Acetylene Chemistry
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Author : Walter Reppe
language : en
Publisher:
Release Date : 1949

Acetylene Chemistry written by Walter Reppe and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1949 with Science categories.




Comprehensive Polymer Science


Comprehensive Polymer Science
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Author : Geoffrey Allen
language : en
Publisher: Pergamon
Release Date : 1989

Comprehensive Polymer Science written by Geoffrey Allen and has been published by Pergamon this book supported file pdf, txt, epub, kindle and other format this book has been release on 1989 with Science categories.


Volume 3 and volume 4.