Alkene Polymerization Reactions With Transition Metal Catalysts
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Alkene Polymerization Reactions With Transition Metal Catalysts
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Author : Yury Kissin
language : en
Publisher: Elsevier
Release Date : 2008-03-10
Alkene Polymerization Reactions With Transition Metal Catalysts written by Yury Kissin and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-03-10 with Technology & Engineering categories.
During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.
Alkene Polymerization Reactions With Transition Metal Catalysts
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Author : Y. V. Kissin
language : en
Publisher: Elsevier Science & Technology
Release Date : 2008
Alkene Polymerization Reactions With Transition Metal Catalysts written by Y. V. Kissin and has been published by Elsevier Science & Technology this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008 with Science categories.
During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.
Transition Metal Catalyzed Polymerizations
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Author : Roderic P. Quirk
language : en
Publisher: CUP Archive
Release Date : 1988
Transition Metal Catalyzed Polymerizations written by Roderic P. Quirk and has been published by CUP Archive this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with Science categories.
This volume contains the proceedings of the Second International Symposium on Transition Metal Catalyzed Polymerizations held in 1986. The papers provide a broad-based perspective covering recent scientific and technological advances in Ziegler-Natta and metathesis polymerization, including olefin, diene, and acetylene polymerization, and copolymerization. The emphasis on reaction kinetics of polymerizations in different reagent and catalyst environments makes this volume of interest to both academic and industrial researchers.
Organometallic Reactions And Polymerization
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Author : Kohtaro Osakada
language : en
Publisher: Springer
Release Date : 2014-07-15
Organometallic Reactions And Polymerization written by Kohtaro Osakada and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-07-15 with Technology & Engineering categories.
This compilation provides advanced graduate students and researchers with a structured overview of olefin polymerization. Divided into eight chapters written by international experts, this book covers polymerization using various organotransition-metal catalysts, including early and late transition metal complexes, new trends in olefin oligomerization and related reactions. All authors address the historic and scientific backgrounds of the field as well as current research progress and potential for further research. The complete book is designed to present eight independent lectures and, because all authors are well versed in organometallic chemistry, each is based on a profound understanding of the reactions and structures of organotransition metal complexes. This book is an ideal accompaniment for researchers taking courses in olefin polymerization and also serves as a valuable resource for teachers and lecturers of chemistry when planning and researching material for advanced lecture courses.
Transition Metal Catalyzed Polymerizations
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Author : Roderic P. Quirk
language : en
Publisher: Taylor & Francis
Release Date : 1983
Transition Metal Catalyzed Polymerizations written by Roderic P. Quirk and has been published by Taylor & Francis this book supported file pdf, txt, epub, kindle and other format this book has been release on 1983 with Science categories.
Transition Metals And Organometallics As Catalysts For Olefin Polymerization
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Author : Walter Kaminsky
language : en
Publisher: Springer
Release Date : 1988
Transition Metals And Organometallics As Catalysts For Olefin Polymerization written by Walter Kaminsky and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with Alkenes categories.
Metal Catalysts In Olefin Polymerization
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Author : Zhibin Guan
language : en
Publisher: Springer Science & Business Media
Release Date : 2009-03-31
Metal Catalysts In Olefin Polymerization written by Zhibin Guan and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-03-31 with Science categories.
Polyolefin is a major industry that is important for our economy and impacts every aspect of our lives. The discovery of new transition metal-based catalysts is one of the driving forces for the further advancement of this field. Whereas the classical heterogeneous Ziegler-Natta catalysts and homogeneous early transition metal metallocene catalysts remain the workhorses of the polyolefin industry, in roughly the last decade, tremendous progress has been made in developing non-metallocene-based olefin polymerization catalysts. Particularly, the discovery of late transition metal-based olefin polymerization catalysts heralds a new era for this field. These late transition metal complexes not only exhibit high activities rivaling their early metal counterparts, but more importantly they offer unique properties for polymer architectural control and copolymerization with polar olefins. In this book, the most recent major breakthroughs in the development of new olefin polymerization catalysts, including early metal metallocene and non-metallocene complexes and late transition metal complexes, are discussed by leading experts. The authors highlight the most important discoveries in catalysts and their applications in designing new polyolefin-based functional materials.
Handbook Of Transition Metal Polymerization Catalysts
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Author : Ray Hoff
language : en
Publisher: John Wiley & Sons
Release Date : 2018-05-08
Handbook Of Transition Metal Polymerization Catalysts written by Ray Hoff and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-05-08 with Technology & Engineering categories.
Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization
Olefin Metathesis And Polymerization Catalysts
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Author : Yavuz Imamogammalu
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Olefin Metathesis And Polymerization Catalysts written by Yavuz Imamogammalu and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Olefin metathesis reaction can be considered as one of the most successful organic reactions with many applications in the low molecular weight range and also in the polymer field. The use of catalysts with their selective and effective transformation properties in olefin metathesis I polymerization systems is a growing interest. There has been great effort and competition in developing active and commercially useful catalysts. The main aim of this ASI was to gather several research groups and also the people from industry. to present existing knowledge and latest results in the field. A wide range of topics through homogeneous and heterogeneous aspects have been considered. Attention has been drawn to the metal-carbene and metallacyclobutane complexes as active species, the initiation mechanisms, the stereochemistry and thermodynamics of these reactions. New catalytic systems for the metathesis of alkenes and alkynes and fot' ring opening polymeriZation I block copolymerization reactions have been introduced. Spectroscopic studies for the characteriZation of catalysts, simulation studies explaining the function of chain carrier species and polymer degradation have also been covered. A detailed industrial report concerning the patents and applications in olefin metathesis I cyc1001efin polymerization area, fabrication and derivation has been presented. This volume contains the main lectures and seminars given at the NATO Advanced Study Institute on " Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization", held at Akcay. Babkesir. Turkey between 10th and 22nd September 1989.
Early Main Group Metal Catalysis
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Author : Sjoerd Harder
language : en
Publisher: John Wiley & Sons
Release Date : 2020-04-06
Early Main Group Metal Catalysis written by Sjoerd Harder and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-04-06 with Technology & Engineering categories.
Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.