Applications Of Porous Coordination Polymers And Metal Organic Frameworks Mofs
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Applications Of Porous Coordination Polymers And Metal Organic Frameworks Mofs
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Author : Hemanta Kalita
language : en
Publisher: GRIN Verlag
Release Date : 2022-08-09
Applications Of Porous Coordination Polymers And Metal Organic Frameworks Mofs written by Hemanta Kalita and has been published by GRIN Verlag this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-08-09 with Science categories.
Document from the year 2022 in the subject Chemistry - Macromolecular Chemistry, Polymer Chemistry, grade: 17, Gauhati University, language: English, abstract: Porous coordination polymers, also known as metal organic frameworks are a new type of hybrid material constructed via self-assembly of metal ions/metal clusters which function as nodes and organic ligands which act as bridges or linkers. They are one of the earliest developed classes of metal containing polymers. They extend infinitely one, two or three dimensional framework through coordination bonding, hydrogen bonding, π–π stacking, C-H-π interactions as well as van der Waal forces. These weaker non-covalent interactions, are important for the packing of the one dimensional chains, two-dimensional nets and three-dimensional frameworks. In view of the tunable structures and promising properties shown by these systems various complexities have been prepared and thoroughly investigated over last decade. MOFs are currently flourishing fields of research owing to their intriguing structural motifs and various potential applications, in the field of gas storage, gas separation, catalysis, ion exchange, microelectronics, non linear optics, sensors, medicine and molecular magnetism etc. They possess structural regularity, high porosity, high surface area resulting in greater potential applications than conventional zeolites or activated carbons and mesoporous silica. For the construction of porous coordination polymers with diverse structures and properties selection of the special inorganic and organic building blocks is one of the important factors. Multicarboxylate organic ligands have proved to be an excellent choice for the construction of MOFs of higher nuclearity due to their different coordination modes with the metals, molecular flexibilities and structural stabilities. Metal carboxylate linker in combination with cross linked or pillered polypyridine have generated many interesting coordination architecture. Making use of transition metal carboxylate and linear bridging auxiliary ligands it is possible to construct 1-D, 2-D and 3-D porous coordination polymer of different pore structures and porosities. Aside from coordination bonding interactions, various non-covalent bonding or some weak intra- or intermolecular interactions, such as hydrogen-bonding, π–π stacking and C–H–π interactions or van der Waals interactions also influence the formation of final architectures.
Applications Of Metal Organic Frameworks And Their Derived Materials
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Author : Inamuddin
language : en
Publisher: John Wiley & Sons
Release Date : 2020-05-04
Applications Of Metal Organic Frameworks And Their Derived Materials written by Inamuddin and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-05-04 with Science categories.
Metal–organic frameworks (MOFs) are porous crystalline polymers constructed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable morphology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down-to-earth applications in fields such as biomedical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strategies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.
Metal Organic Frameworks Mofs For Environmental Applications
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Author : Sujit K. Ghosh
language : en
Publisher: Elsevier
Release Date : 2019-06-07
Metal Organic Frameworks Mofs For Environmental Applications written by Sujit K. Ghosh and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-06-07 with Science categories.
Metal-Organic Frameworks for Environmental Applications examines this important topic, looking at potential materials and methods for the remediation of pressing pollution issues, such as heavy-metal contaminants in water streams, radioactive waste disposal, marine oil-spillage, the treatment of textile and dye industry effluents, the clean-up of trace amounts of explosives in land and water, and many other topics. This survey of the cutting-edge research and technology of MOFs is an invaluable resource for researchers working in inorganic chemistry and materials science, but it is also ideal for graduate students studying MOFs and their applications. Examines the applications of metal-organic frameworks for the remediation of environmental pollutants Features leading experts who research the applications of MOFs from around the world, including contributions from the United States, India and China Explores possible solutions to some of today’s most pressing environmental challenges, such as heavy-metal contamination in bodies of water, oil spills and clean-up of explosives hidden in land and water Provides an excellent reference for researchers and graduate students studying in the areas of inorganic chemistry, materials chemistry and environmental science
Metal Organic Frameworks
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Author : David Farrusseng
language : en
Publisher: John Wiley & Sons
Release Date : 2011-09-19
Metal Organic Frameworks written by David Farrusseng and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-09-19 with Science categories.
An international and interdisciplinary team of leading experts from both academia and industry report on the wide range of hot applications for MOFs, discussing both the advantages and limits of the material. The resulting overview covers everything from catalysis, H2 and CH4 storage and gas purification to drug delivery and sensors. From the Contents: - Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future - Design of Functional Metal-Organic Frameworks by Post-Synthetic Modification - Thermodynamic Methods for Prediction of Gas Separation in Flexible Frameworks - Separation and purification of gases by MOFs - Opportunities for MOFs in CO2 capture from flue gases, natural gas and syngas by adsorption - Manufacture of MOF thin films on structured supports for separation and catalysis - Research status of Metal-Organic Frameworks for on-board cryo-adsorptive hydrogen storage applications - Separation of xylene isomers - Metal-Organic Frameworks as Catalysts for Organic Reactions - Biomedical applications of Metal Organic Frameworks - Metal Organic Frameworks for Biomedical Imaging - Luminescent Metal-Organic Frameworks - Deposition of thin films for sensor applications - Industrial MOF Synthesis - MOF shaping and immobilisation A must-have for every scientist in the field.
Pillared Metal Organic Frameworks
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Author : Lida Hashemi
language : en
Publisher: John Wiley & Sons
Release Date : 2019-04-08
Pillared Metal Organic Frameworks written by Lida Hashemi and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-04-08 with Science categories.
In the last two decades, metal-organic frameworks (MOFs) have provoked considerable interest due to their potential applications in different fields such as catalysis, gas storage and sensing. The most important advantages of MOFs over other porous materials is the ability of tailoring their pore size, functionality and even the topology of the framework by rational selection of the molecular building blocks. Therefore, many chemists have tried to engineer the structure of MOFs to achieve specific functions. Pillared metal organic frameworks are a class of MOFs composed of inorganic secondary building units (SBUs) and two sets of organic linkers, generally oxygen- and nitrogen-donor ligands. Typically, in the structure of pillared MOFs, the oxygen-donor struts link the metal clusters into a two-dimensional (2D) sheet and the N-donor struts pillar the sheets to generate a three-dimensional (3D) framework. Thus, the construction of MOFs by utilizing two sets of organic linkers could provide an extra possibility for further tuning of MOF’s pore walls. A variety of functional groups including imine, amide and heterocycles were successfully incorporated into bidentate pillar ligand skeleton. Interestingly, by using pillaring linkers with different length, a wide diversity of metal-organic frameworks with tunable pore dimensions and topologies can be obtained. In this book, we introduce pillared metal organic frameworks with their properties and applications.
Porous Coordination Polymers
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Author : Nidhi Goel
language : en
Publisher: Elsevier
Release Date : 2024-01-26
Porous Coordination Polymers written by Nidhi Goel and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-01-26 with Technology & Engineering categories.
Porous Coordination Polymers: From Fundamentals to Advanced Applications brings together the latest advances in Porous Coordination Polymers (PCPs) for cutting-edge applications. The book begins by introducing PCPs, highlighting their structure, chemistry, basic properties and design approaches. This is followed by a chapter focusing on synthesis methods and mechanical properties. Subsequent chapters provide in-depth coverage of specific target applications, explaining the preparation of PCPs for areas including catalysis and photocatalysis, environmental remediation, gas storage and separation, energy storage and conversion, new generation magnets, nanocarriers in therapeutics, and biomedical imaging. Finally, current challenges and future developments are considered in detail. Porous Coordination Polymers are gaining increasing interest due to their attractive properties, such as structural flexibility, large surface area, tailorable pore size, and functional tunability, in turn enabling a wide range of possible applications which this book aims to highlight and to elucidate. This is a valuable resource for researchers and advanced students across polymer science, inorganic chemistry, environmental science, and materials science and engineering, as well as engineers, scientists, and R&D professionals with an interest in porous coordination polymers (PCPs) and novel polymeric materials for advanced industrial applications. Explores porous coordination polymers in detail while highlighting key ideas. Provides in-depth discussion of the design and development of new porous coordination polymers. Addresses present issues and looks at potential future developments in this innovative field.
Metal Organic Frameworks
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Author : Leonard R. MacGillivray
language : en
Publisher: John Wiley & Sons
Release Date : 2010-12-17
Metal Organic Frameworks written by Leonard R. MacGillivray and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010-12-17 with Science categories.
Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.
Metal Organic Frameworks With Heterogeneous Structures
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Author : Ali Morsali
language : en
Publisher: John Wiley & Sons
Release Date : 2021-10-12
Metal Organic Frameworks With Heterogeneous Structures written by Ali Morsali and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-10-12 with Science categories.
METAL-ORGANIC FRAMEWORKS WITH HETEROGENEOUS STRUCTURES A unique book that sheds light on Metal-Organic Frameworks complex systems that often display behaviors that surprise and cannot be easily described. In this book, MOF-based heterostructures technology with key characteristics is completely analyzed and the current state-of-the-art is discussed. The authors focus on the complex heterostructures promoted by MOFs with advantage of their recent new advances for various applications with particular emphasis on their design. As an extension of the design and synthesis, the shaping technology of heterostructure MOFs is also of great significance to the future practical applications in industry (adsorption/desorption, gas storage, catalysis, conductivity, optical activity) of this class of complex porous materials. As this unique book covers all of the aspects of complexity in MOFs with heterogeneous structures, it serves as an essential reference to the concepts of introducing complexity to designing the future new platforms of materials with advanced and superior properties. This important compact book provides the reader with: The principal aspects of heterogeneity that produce complexity in MOFs, their effects in the structure chemistry, performance and applications The effects of complexities on the structure of metal-organic frameworks The roles of complexities on metal-organic frameworks applications Explanation of synthesis strategies of the complex heterostructure MOFs. Audience This book will be beneficial for chemists, materials engineers, advanced postgraduate and graduate students, researchers and specialists who are working in the area of materials design and their chemistry, porous crystalline materials, coordination polymers, hybrid and functional materials, as well as industry professionals, such as those working on selective catalysis and adsorption-separation, optics, gas capture, processes of biological and pharmaceutical.
Porous Organic Frameworks
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Author : Guangshan Zhu
language : en
Publisher: Springer
Release Date : 2014-11-28
Porous Organic Frameworks written by Guangshan Zhu and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-11-28 with Technology & Engineering categories.
This book describes the design, synthesis, characterization and applications of porous organic frameworks (POFs). Special emphasis is placed on the utilization of porous materials for CO2 capture and CH4 and H2 storage, which have promising potential for addressing the issues of environmental degradation and climate change. It also includes two chapters introducing the properties of POFs and defining the principles of synthesis, as well as a chapter dealing with post-modified POFs. This book is intended for those readers who are interested in porous materials and their applications. Guangshan Zhu is a professor at the College of Chemistry, Jilin University, China.
Elaboration And Applications Of Metal Organic Frameworks
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Author : Ma Shengqian
language : en
Publisher: World Scientific
Release Date : 2018-01-29
Elaboration And Applications Of Metal Organic Frameworks written by Ma Shengqian and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-01-29 with Science categories.