Porous Coordination Polymers
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Applications Of Porous Coordination Polymers And Metal Organic Frameworks Mofs
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Author : Hemanta Kalita
language : en
Publisher: GRIN Verlag
Release Date : 2022-08-09
Applications Of Porous Coordination Polymers And Metal Organic Frameworks Mofs written by Hemanta Kalita and has been published by GRIN Verlag this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-08-09 with Science categories.
Document from the year 2022 in the subject Chemistry - Macromolecular Chemistry, Polymer Chemistry, grade: 17, Gauhati University, language: English, abstract: Porous coordination polymers, also known as metal organic frameworks are a new type of hybrid material constructed via self-assembly of metal ions/metal clusters which function as nodes and organic ligands which act as bridges or linkers. They are one of the earliest developed classes of metal containing polymers. They extend infinitely one, two or three dimensional framework through coordination bonding, hydrogen bonding, π–π stacking, C-H-π interactions as well as van der Waal forces. These weaker non-covalent interactions, are important for the packing of the one dimensional chains, two-dimensional nets and three-dimensional frameworks. In view of the tunable structures and promising properties shown by these systems various complexities have been prepared and thoroughly investigated over last decade. MOFs are currently flourishing fields of research owing to their intriguing structural motifs and various potential applications, in the field of gas storage, gas separation, catalysis, ion exchange, microelectronics, non linear optics, sensors, medicine and molecular magnetism etc. They possess structural regularity, high porosity, high surface area resulting in greater potential applications than conventional zeolites or activated carbons and mesoporous silica. For the construction of porous coordination polymers with diverse structures and properties selection of the special inorganic and organic building blocks is one of the important factors. Multicarboxylate organic ligands have proved to be an excellent choice for the construction of MOFs of higher nuclearity due to their different coordination modes with the metals, molecular flexibilities and structural stabilities. Metal carboxylate linker in combination with cross linked or pillered polypyridine have generated many interesting coordination architecture. Making use of transition metal carboxylate and linear bridging auxiliary ligands it is possible to construct 1-D, 2-D and 3-D porous coordination polymer of different pore structures and porosities. Aside from coordination bonding interactions, various non-covalent bonding or some weak intra- or intermolecular interactions, such as hydrogen-bonding, π–π stacking and C–H–π interactions or van der Waals interactions also influence the formation of final architectures.
Porous Coordination Polymers
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Author : Nidhi Goel
language : en
Publisher: Elsevier
Release Date : 2024-01-26
Porous Coordination Polymers written by Nidhi Goel and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-01-26 with Technology & Engineering categories.
Porous Coordination Polymers: From Fundamentals to Advanced Applications brings together the latest advances in Porous Coordination Polymers (PCPs) for cutting-edge applications. The book begins by introducing PCPs, highlighting their structure, chemistry, basic properties and design approaches. This is followed by a chapter focusing on synthesis methods and mechanical properties. Subsequent chapters provide in-depth coverage of specific target applications, explaining the preparation of PCPs for areas including catalysis and photocatalysis, environmental remediation, gas storage and separation, energy storage and conversion, new generation magnets, nanocarriers in therapeutics, and biomedical imaging. Finally, current challenges and future developments are considered in detail. Porous Coordination Polymers are gaining increasing interest due to their attractive properties, such as structural flexibility, large surface area, tailorable pore size, and functional tunability, in turn enabling a wide range of possible applications which this book aims to highlight and to elucidate. This is a valuable resource for researchers and advanced students across polymer science, inorganic chemistry, environmental science, and materials science and engineering, as well as engineers, scientists, and R&D professionals with an interest in porous coordination polymers (PCPs) and novel polymeric materials for advanced industrial applications. Explores porous coordination polymers in detail while highlighting key ideas. Provides in-depth discussion of the design and development of new porous coordination polymers. Addresses present issues and looks at potential future developments in this innovative field.
The Modification Of Porous Coordination Polymers Or Metal Organic Frameworks For Photocatalytic Applications
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Author : Dominic Tilgner
language : en
Publisher:
Release Date : 2018
The Modification Of Porous Coordination Polymers Or Metal Organic Frameworks For Photocatalytic Applications written by Dominic Tilgner and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018 with Alcohols categories.
Coordination Polymers
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Author : Stuart R. Batten
language : en
Publisher: Royal Society of Chemistry
Release Date : 2009
Coordination Polymers written by Stuart R. Batten and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009 with Science categories.
The field of coordination polymer research is now vast, & one of the fastest growing areas of chemistry in recent times, with important work being done on a variety of different aspects. This book provides a broad overview of all the major facets of modern coordination polymer science in the one place.
Functional Materials Based On Porous Coordination Polymers
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Author : Mikhail Meilikhov
language : en
Publisher:
Release Date : 2011
Functional Materials Based On Porous Coordination Polymers written by Mikhail Meilikhov and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011 with categories.
Novel Multifunctional Porous Coordination Polymers From Pre Synthetically Modified Organophosphorus Ligands
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Author : Alisha Marie Bohnsack
language : en
Publisher:
Release Date : 2015
Novel Multifunctional Porous Coordination Polymers From Pre Synthetically Modified Organophosphorus Ligands written by Alisha Marie Bohnsack and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015 with categories.
Phosphine-based Porous Coordination Polymers (PCPs) have shown promising results as gas storage, gas separations, and molecular sensing materials due the versatility of the P(III)/P(V) chemistry, coupled with the inherent 3-dimensionality of the ligands. A variety of pre-synthetically modified organophosphine linkers have been reacted with alkali earth metals, early transition metals, and lanthanides to produce a series of Phosphine Coordination Materials (PCMs) with a wide array of topologies and pore functionalities. A p-carboxylated triphenylphosphine oxide linker, tctpoH3, has been reacted with Mg(II) to form the thermally robust PCM-11, which possesses superior room-temperature CO2 adsorption capacity at 12 bar. A new tetrahedral phosphonium salt, tctp+H3, has been synthesized by the Pd(II)-catalyzed reaction of p-carboxylated triphenylphosphine with 4-iodobenzoic acid to produce a zwitterionic monophosphine precursor. Upon examination of its crystal structure, it was found that tctp+H3 possesses a high degree of hydrogen-bonding between neighboring carboxylic acid groups, which causes it to polymerize into a porous, metal-free, ionically-bonded coordination polymer, iPCM-1. This phosphonium linker has been reacted with a series of Ln(III) precursors to form an isostructural set of PCMs that exhibit characteristic lanthanide luminescence properties. Several PCPs have been developed from a new bis(phosphine)MCl2 (M = Pd, Pt) complex upon reaction with early transition metals. Zn(II)-based PCM-18 exhibits unusual and fully reversible H2 adsorption at 150 °C, as well as post-synthetic reactivity inside the pores of the material. Co(II)-based PCM-24 also displays similar high-temperature H2 sorption behavior, along with a reversible pink to blue color change upon activation, indicative of a symmetry transformation from O [subscript h] to T [subscript d] about the metal node.
Assembly Of Porous Coordination Polymers For H2 Storage
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Author : Junhua Jia
language : en
Publisher:
Release Date : 2007
Assembly Of Porous Coordination Polymers For H2 Storage written by Junhua Jia and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007 with Coordination compounds categories.
Synthesis And Characterization Of Porous Coordination Polymers Loaded With Metal And Metal Oxide Nano Particles
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Author : Maike Müller
language : en
Publisher:
Release Date : 2011
Synthesis And Characterization Of Porous Coordination Polymers Loaded With Metal And Metal Oxide Nano Particles written by Maike Müller and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011 with categories.
Metal Organic Frameworks Porous Coordination Polymers And Zeolites
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Author : Lars Öhrström
language : en
Publisher:
Release Date : 2013
Metal Organic Frameworks Porous Coordination Polymers And Zeolites written by Lars Öhrström and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013 with categories.
Porous Coordination Polymers For H2 Storage And Gas Adsorption
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Author : Wenbin Yang
language : en
Publisher:
Release Date : 2009
Porous Coordination Polymers For H2 Storage And Gas Adsorption written by Wenbin Yang and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009 with Coordination polymers categories.