Aqueous Solutions Of Simple Electrolytes

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Aqueous Solutions Of Simple Electrolytes

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Author : Felix Franks
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Aqueous Solutions Of Simple Electrolytes written by Felix Franks and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.

The chapters making up this volume had originally been planned to form part of a single volume covering solid hydrates and aqueous solutions of simple molecules and ions. However, during the preparation of the manu scripts it became apparent that such a volume would turn out to be very unwieldy and I reluctantly decided to recommend the publication of sepa rate volumes. The most sensible way of dividing the subject matter seemed to lie in the separation of simple ionic solutions. The emphasis in the present volume is placed on ion-solvent effects, since a number of excellent texts cover the more general aspects of electrolyte solutions, based on the classical theories of Debye, Huckel, On sager, and Fuoss. It is interesting to speculate as to when a theory becomes "classical." Perhaps this occurs when it has become well known, well liked, and much adapted. The above-mentioned theories of ionic equilibria and transport certainly fulfill these criteria. There comes a time when the refinements and modifications can no longer be related to physical significance and can no longer hide the fact that certain fundamental assumptions made in the development of the theory are untenable, especially in the light of information obtained from the application of sophisticated molecular and thermodynamic techniques.

Aqueous Solutions Of Simple Electrolytes

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Author : Felix Franks
language : en
Publisher: Springer
Release Date : 2012-07-15

Aqueous Solutions Of Simple Electrolytes written by Felix Franks and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-07-15 with Science categories.

The chapters making up this volume had originally been planned to form part of a single volume covering solid hydrates and aqueous solutions of simple molecules and ions. However, during the preparation of the manu scripts it became apparent that such a volume would turn out to be very unwieldy and I reluctantly decided to recommend the publication of sepa rate volumes. The most sensible way of dividing the subject matter seemed to lie in the separation of simple ionic solutions. The emphasis in the present volume is placed on ion-solvent effects, since a number of excellent texts cover the more general aspects of electrolyte solutions, based on the classical theories of Debye, Huckel, On sager, and Fuoss. It is interesting to speculate as to when a theory becomes "classical." Perhaps this occurs when it has become well known, well liked, and much adapted. The above-mentioned theories of ionic equilibria and transport certainly fulfill these criteria. There comes a time when the refinements and modifications can no longer be related to physical significance and can no longer hide the fact that certain fundamental assumptions made in the development of the theory are untenable, especially in the light of information obtained from the application of sophisticated molecular and thermodynamic techniques.

Water In Crystalline Hydrates Aqueous Solutions Of Simple Nonelectrolytes

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Author : Felix Franks
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-04-18

Water In Crystalline Hydrates Aqueous Solutions Of Simple Nonelectrolytes written by Felix Franks and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-04-18 with Science categories.

vi the information collected and discussed in this volume may help toward the achievement of such an objective. I should like to express my debt of gratitude to the authors who have contributed to this volume. Editing a work of this nature can strain long established personal relationships and I thank my various colleagues for bearing with me and responding (sooner or later) to one or several letters or telephone calls. My special thanks once again go to Mrs. Joyce Johnson, who bore the main brunt of this seemingly endless correspondence and without whose help the editorial and referencing work would have taken several years. F. FRANKS Biophysics Division Unilever Research Laboratory Colworth/ Welwyn Colworth House, Sharnbrook, Bedford January, 1973 Contents Contents of Volume 1 ............................. . . . . . .. . . .. xv Contents of Volume 3 ........................ '. . . . . . . . . . . . xvi . . . . Contents of Volume 4 . . . . . . . . . . . . . . . . . . . . . . . . .. . . . xvii . . . . . . . . . . . Chapter 1 The Solvent Properties of Water F. Franks 1. Water, the Universal Solvent-the Study of Aqueous Solutions 2. Aqueous Solutions of Nonelectrolytes ................. . 5 2.1. Apolar Solutes ................................. . 6 2.2. Polar Solutes .................................. . 19 2.3. Ionic Solutes Containing Alkyl Residues-"Apolar Electrolytes" ................................... . 38 3. Aqueous Solutions of Electrolytes .................... . 42 3.1. Single Ion Properties ............................ . 42 3.2. Ion-Water Interactions ......................... . 43 3.3. Interionic Effects ............................... . 47 4. Complex Aqueous Mixtures 48 Chapter 2 Water in Stoichiometric Hydrates M. Falk and O. Knop 1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 . . . . . . . . . . . . . 2. Symmetry and Types of Environment of the H0 Molecule 2 in Crystals .......................................... 57 vii Contents viii 2.1. Site Symmetry. . . . . . . . . . . . . . . . . . . . . . . . . 57 . . . . . . . . . .

Electrolyte Solutions

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Author : R.A. Robinson
language : en
Publisher: Courier Corporation
Release Date : 2002-07-24

Electrolyte Solutions written by R.A. Robinson and has been published by Courier Corporation this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002-07-24 with Science categories.

Classic text deals primarily with measurement, interpretation of conductance, chemical potential, and diffusion in electrolyte solutions. Detailed theoretical interpretations, plus extensive tables of thermodynamic and transport properties. 1970 edition.

Properties Of Aqueous Solutions Of Electrolytes

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Author : Ivan D. Zaytsev
language : en
Publisher: CRC Press
Release Date : 1992-08-24

Properties Of Aqueous Solutions Of Electrolytes written by Ivan D. Zaytsev and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-08-24 with Science categories.

Properties of Aqueous Solutions of Electrolytes is a handbook that systematizes the information on physico-chemical parameters of multicomponent aqueous electrolyte solutions. This important data collection will be invaluable for developing new methods for more efficient chemical technologies, choosing optimal solutions for more effective methods of using raw materials and energy resources, and other such activities. This edition, the first available in English, has been substantially revised and augmented. Many new tables have been added because of a significantly larger list of electrolytes and their properties (electrical conductivity, boiling and freezing points, pressure of saturated vapors, activity and diffusion coefficients). The book is divided into two sections. The first section provides tables that list the properties of binary aqueous solutions of electrolytes, while the second section deals with the methods for calculating their properties in multicomponent systems. All values are given in PSI units or fractional and multiple units. Metrological characteristics of the experimental methods used for the determination of physico-chemical parameters are indicated as a relative error and those of the computational methods as a relative error or a root-mean square deviation.

Handbook Of Aqueous Electrolyte Solutions

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Author : Ari L. Horvath
language : en
Publisher:
Release Date : 1985

Handbook Of Aqueous Electrolyte Solutions written by Ari L. Horvath and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1985 with Electrolyte solutions categories.

Equilibrium Properties Of Aqueous Solutions Of Single Strong Electrolytes

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Author : Edward Armand Guggenheim
language : en
Publisher: Pergamon
Release Date : 1969

Equilibrium Properties Of Aqueous Solutions Of Single Strong Electrolytes written by Edward Armand Guggenheim and has been published by Pergamon this book supported file pdf, txt, epub, kindle and other format this book has been release on 1969 with Science categories.

An Introduction To Aqueous Electrolyte Solutions

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Author : Margaret Robson Wright
language : en
Publisher: John Wiley & Sons
Release Date : 2007-06-05

An Introduction To Aqueous Electrolyte Solutions written by Margaret Robson Wright and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-06-05 with Science categories.

An Introduction to Aqueous Electrolyte Solutions is a comprehensive coverage of the subject including the development of key concepts and theory that focus on the physical rather than the mathematical aspects. Important links are made between the study of electrolyte solutions and other branches of chemistry, biology, and biochemistry, making it a useful cross-reference tool for students studying this important area of electrochemistry. Carefully developed throughout, each chapter includes intended learning outcomes and worked problems and examples to encourage student understanding of this multidisciplinary subject. * a comprehensive introduction to aqueous electrolyte solutions including the development of key concepts and theories * emphasises the connection between observable macroscopic experimental properties and interpretations made at the molecular level * key developments in concepts and theory explained in a descriptive manner to encourage student understanding * includes worked problems and examples throughout An invaluable text for students taking courses in chemistry and chemical engineering, this book will also be useful for biology, biochemistry and biophysics students required to study electrochemistry.

Complex Ions In Aqueous Solutions

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Author : Arthur Jaques
language : en
Publisher:
Release Date : 1914

Complex Ions In Aqueous Solutions written by Arthur Jaques and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1914 with Complex ions categories.

Structure Of Aqueous Electrolyte Solutions And The Hydration Of Ions

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Author : Oleg I︠A︡kovlevich Samoĭlov
language : en
Publisher:
Release Date : 1965

Structure Of Aqueous Electrolyte Solutions And The Hydration Of Ions written by Oleg I︠A︡kovlevich Samoĭlov and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1965 with Electrolyte solutions categories.