Biomimetic Oxidations Catalyzed By Transition Metal Complexes
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Biomimetic Oxidations Catalyzed By Transition Metal Complexes
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Author : Bernard Meunier
language : en
Publisher: World Scientific
Release Date : 2000-03-08
Biomimetic Oxidations Catalyzed By Transition Metal Complexes written by Bernard Meunier and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-03-08 with Science categories.
Since the classic work Metal-Catalyzed Oxidations of Organic Compounds (edited by R A Sheldon and J K Kochi, 1991), no book has been devoted to advances in the field of biomimetic oxidations, which was created nearly 18 years ago. This expanding research field is covered in this volume. All the different aspects of the modeling of oxidations catalyzed by metalloenzymes are dealt with. This invaluable book will be useful to postgraduates as well as researchers in academia and industry, and will also benefit second year university students. Contents:Thermodynamic Influences of C–H Bond Oxidation (J M Mayer)Distinguishing Biomimetic Oxidations from Oxidations Mediated by Freely Diffusing Radicals (K U Ingold & P A MacFaul)Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates (J L McLain et al.)Models of Heme Peroxidases and Catalases (B Meunier)Non-Heme Peroxidases and Catalases: Mechanistic Implications from the Studies of Manganese and Vanadium Model Compounds (C Slebodnick et al.)Methane Monooxygenase Models (Z-B Hu & S M Gorun)Models of Copper Enzymes and Heme-Copper Oxidases (M A Kopf & K D Karlin)Iron-Containing Models of Catechol Dioxygenases (H-J Krüger)Biomimetic Chemistry of Molybdenum (C G Young)Models of Superoxide Dismutases (D E Cabelli et al.)Modeling the Oxygen-Evolving Complex in Photosystem II (J Limburg et al.)Asymmetric Biomimetic Oxidations (A Robert & B Meunier)Bioinspired Oxidations Catalyzed by Ruthenium Complexes (S-I Murahashi & N Komiya)Biocatalytic and Biomimetic Oxidations from an Industrial Perspective (R A Sheldon) Readership: Postgraduate students and researchers in biochemistry and chemistry. Keywords:EPR Spectroscopy;Functional Model Chemistry;Isotope Labeling;Manganese Complexes;Mechanism;Oxygen Evolution;Photosystem II;Redox Chemistry;Water Splitting Chemistry;X-Ray Spectroscopy;Oxidation;Oxygenation;Transition Metal Complexes;Asymmetric Oxidation;Oxidase;Oxygenase;Metal-Oxo;Peroxide, Peroxo;Metalloporphyrin;MMO Models;P450 Models
Mechanisms In Homogeneous And Heterogeneous Epoxidation Catalysis
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Author : S. Ted Oyama
language : en
Publisher: Elsevier
Release Date : 2011-10-13
Mechanisms In Homogeneous And Heterogeneous Epoxidation Catalysis written by S. Ted Oyama and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-10-13 with Technology & Engineering categories.
The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. * Comprehensive listing of epoxide products * Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts * Analysis of the general strengths and weaknesses of varied catalytic systems * Detailed description of the mechanisms of reaction for classical and emerging catalysts
Advances In Inorganic Chemistry
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Author :
language : en
Publisher: Elsevier
Release Date : 2004-05-06
Advances In Inorganic Chemistry written by and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-05-06 with Science categories.
Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry ranging from bio-inorganic to solid state studies. Thisacclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced. Comprehensive reviews written by leading experts in the field An indispensable reference to advanced researchers Includes 7 contributions covering important advances in inorganic chemistry
Advances In Inorganic Chemistry
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Author : Rudi van Eldik
language : en
Publisher: Elsevier
Release Date : 2006-01-18
Advances In Inorganic Chemistry written by Rudi van Eldik and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-01-18 with Science categories.
Advances in Inorganic Chemistry Volume 58 focuses on homogeneous biomimetic oxidation catalysis. Contributions by leading experts in the field cover important advances in inorganic and bioinorganic chemistry. Contributions include diversity-based approaches to selective biomimetic oxidation catalysis; the selective conversion of hydrocarbons with H2O2 using biomimetic non-heme iron and manganese oxidation catalysis; DNA oxidation by copper and manganese complexes; influences of the ligand in copper-dioxygen complex-formation and substrate oxidations; biomimetic oxidations by dinuclear and trinuclear copper complexes. In the final contribution the authors focus on green oxidation of alcohols using biomimetic copper complexes and enzymes as catalysts. Volume 58 provides another welcomed addition to the widely acclaimed series, Advances in Inorganic Chemistry. * Includes new information on the important advances in inorganic and bioinorganic chemistry * Each chapter is fully referenced * Contains comprehensive reviews written by leading experts in the field
Alkane C H Activation By Single Site Metal Catalysis
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Author : Pedro J. Pérez
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-09-15
Alkane C H Activation By Single Site Metal Catalysis written by Pedro J. Pérez and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-09-15 with Science categories.
Over the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C−H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. Alkane C-H Activation by Single-Site Metal Catalysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions. Chapter 1 offers a comprehensive summary of the main discoveries realized so far. Chapter 2 reviews the so-called electrophilic activation, initiated by Shulpín in the late 60s, and the base for the Catalytica system. Chapter 3 examines the catalytic borylation of alkanes, discovered by Hartwig, whereas chapter 4 provides an updated vision of the alkane dehydrogenation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. The history of C-H bond activation, and the current research described in this book, highlight the current research and present the reader with an outlook of this field which continues to be explored by an increasingly visionary and enthusiastic group of organic, organometallic, biological and physical chemists.
Environmentally Sustainable Catalytic Asymmetric Oxidations
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Author : Konstantin Bryliakov
language : en
Publisher: CRC Press
Release Date : 2014-09-17
Environmentally Sustainable Catalytic Asymmetric Oxidations written by Konstantin Bryliakov and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-09-17 with Science categories.
Catalysis plays a vital role in chemical, petroleum, agriculture, polymer, electronics, pharmaceutical, and other industries. Over 90 percent of chemicals originate from catalytic processes. Toughening economic and environmental constraints have proven to be a challenge for meeting the demand of novel efficient and sustainable regio- and stereoselective catalyst systems. Environmentally Sustainable Catalytic Asymmetric Oxidations provides a comprehensive overview of existing ecologically friendly catalyst systems for various asymmetric oxidation processes. Topics include: A survey of existing transition metal-based catalyst systems for asymmetric epoxidations (AEs) with O2 and H2O2 Asymmetric sulfoxidations with H2O2 on chiral metal complexes An overview of various transition metal-catalyzed oxidative transformations with H2O2 or O2 used as the terminal oxidant Organocatalytic asymmetric oxidations Catalytic processes of stereospecific oxidations of C-H functional groups The role that oxoiron(V) intermediates play in chemo- and stereoselective oxidations catalyzed by non-heme iron complexes The book concludes with a discussion of the opportunities and problems associated with the industrial application of stereoselective processes of catalytic oxidation with H2O2 and O2. It also provides examples of processes with industrial potential. Some of the catalysts presented in this book may serve as promising alternatives for existing catalysts—progressively replacing them in manufacturing processes and ultimately making the chemical industry greener and cleaner.
Metal Catalyzed Oxidations Of Organic Compounds
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Author : Roger Sheldon
language : en
Publisher: Academic Press
Release Date : 1981-10-28
Metal Catalyzed Oxidations Of Organic Compounds written by Roger Sheldon and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1981-10-28 with Science categories.
Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation-reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds. This book is intended for chemists involved in organic synthesis, catalysis, and organometallic chemistry, both in academic institutions and in industrial laboratories.
Innovations In Green Chemistry And Green Engineering
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Author : Paul T. Anastas
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-13
Innovations In Green Chemistry And Green Engineering written by Paul T. Anastas and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-13 with Science categories.
Processes that meet the objectives of green chemistry and chemical engineering minimize waste and energy use, and eliminate toxic by-products. Given the ubiquitous nature of products from chemical processes in our lives, green chemistry and chemical engineering are vital components of any sustainable future. Gathering together ten peer-reviewed articles from the Encyclopedia of Sustainability Science and Technology, Innovations in Green Chemistry and Green Engineering provides a comprehensive introduction to the state-of-the-art in this key area of sustainability research. Worldwide experts present the latest developments on topics ranging from organic batteries and green catalytic transformations to green nanoscience and nanotoxicology. An essential, one-stop reference for professionals in research and industry, this book also fills the need for an authoritative course text in environmental and green chemistry and chemical engineering at the upper-division undergraduate and graduate levels.
New Trends In Enzyme Catalysis And Biomimetic Chemical Reactions
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Author : Gertz I. Likhtenshtein
language : en
Publisher: Springer Science & Business Media
Release Date : 2007-05-08
New Trends In Enzyme Catalysis And Biomimetic Chemical Reactions written by Gertz I. Likhtenshtein and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-05-08 with Science categories.
"This book is a view of enzyme catalysis by a physico-chemist with long-term experience in the investigation of structure and action mechanism of biological catalysts. This book is not intended to provide an exhaustive survey of each topic but rather a discussion of their theoretical and experimental background, and recent developments. The literature of enzyme catalysis is so vast and many scientists have made important contribution in the area, that it is impossible in the space allowed for this book to give a representative set of references. The author has tried to use reviews, and general principles of articles. He apologizes to those he has not been able to include. . ... The monograph is intended for scientists working on enzyme catalysis and adjacent areas such as chemical modeling of biological processes, homogeneous catalysis, biomedical research and biotechnology. The book can be use as a subsidiary manual for instructors, graduate and undergraduate students of university biochemistry and chemistry departments."--Pages ix-x.
Advances In Catalytic Activation Of Dioxygen By Metal Complexes
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Author : László I. Simándi
language : en
Publisher: Springer Science & Business Media
Release Date : 2006-04-11
Advances In Catalytic Activation Of Dioxygen By Metal Complexes written by László I. Simándi and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-04-11 with Science categories.
The subject of dioxygen activation and homogeneous catalytic oxidation by metal complexes has been in the focus of attention over the last 20 years. The widespread interest is illustrated by its recurring presence among the sessions and subject areas of important international conferences on various aspects of bioinorganic and coordination chemistry as well as catalysis. The most prominent examples are ICCC, ICBIC, EUROBIC, ISHC, and of course the ADHOC series of meetings focusing on the subject itself. Similarly, the number of original and review papers devoted to various aspects of dioxygen activation are on the rise. This trend is due obviously to the relevance of catalytic oxidation to biological processes such as dioxygen transport, and the action of oxygenase and oxidase enzymes related to metabolism. The structural and functional modeling of metalloenzymes, particularly of those containing iron and copper, by means of low-molecular complexes of iron, copper, ruthenium, cobalt, manganese, etc., have provided a wealth of indirect information helping to understand how the active centers of metalloenzymes may operate. The knowledge gained from the study of metalloenzyme models is also applicable in the design of transition metal complexes as catalytsts for specific reactions. This approach has come to be known as biomimetic or bioinspired catalysis and continues to be a fruitful and expanding area of research.