Boron Hydride Chemistry
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Boron Hydride Chemistry
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Author : Earl Muetterties
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Boron Hydride Chemistry written by Earl Muetterties and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
Boron Hydride Chemistry covers the significant contributions of boron hydride research in the subjects of bonding, structure, and stereochemistry. This book contains 12 chapters that illustrate the merging of certain areas of boron hydride chemistry with other disciplines, such as organic, organometallic, and transition metal chemistry. After providing an overview of the general geometric, stereochemical, and dynamic stereochemical features of boron hydrides, this book goes on exploring the bonding theory and theoretical research on boron hydrides, with an emphasis on boron hydrides that have open polyhedral structures. These topics are followed by discussions on gas phase and solution reactions of borane and substituted boranes. A chapter focuses on the chemistry of cations containing boron atoms bonded to hydrogen. The remaining chapters examine the syntheses, structures, bonding, spectral properties, and chemistry of specific boron hydrides, including borazines, closo-boron hydrides, carboranes, icosahedral carboranes, and close- and nido-heteroboranes. Inorganic chemists and researchers, teachers, and undergraduate inorganic chemistry students will find this book invaluable.
Boron Hydrides
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Author : William N. Lipscomb
language : en
Publisher: Courier Corporation
Release Date : 2013-05-13
Boron Hydrides written by William N. Lipscomb and has been published by Courier Corporation this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-05-13 with Science categories.
In this classic monograph, Nobel Prize–winning chemist William N. Lipscomb elucidates his area of expertise: the general structural principles and reactions of boron hydrides and related compounds. Lipscomb's work appeared only a decade after the structures of boron hydrides were first elucidated and their chemistry formulated into a widely applicable framework. His observations led to a major reconsideration of how atoms bond to form stable molecules. A concise treatment of the many separate parts of the structural theory and its relation to chemistry, this volume begins with an overview of boron hydrides and related structures, progressing to three-center bonds and their applications, molecular orbitals, nuclear magnetic resonance studies of boron hydrides and related compounds, and reactions of the boron hydrides. More than 120 diagrams and figures illustrate a variety of structures.
Hydrides Of Boron And Silicon
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Author : Alfred Stock
language : en
Publisher:
Release Date : 1957
Hydrides Of Boron And Silicon written by Alfred Stock and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1957 with Borane categories.
Progress In Boron Chemistry
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Author : R. J. Brotherton
language : en
Publisher: Elsevier
Release Date : 2016-10-12
Progress In Boron Chemistry written by R. J. Brotherton and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-10-12 with Science categories.
Progress in Boron Chemistry, Volume 2 presents the chemistry and applications of boron and its compounds. This book provides a critical treatment of six areas of boron chemistry, including polyhedral borane ions, carboranes, polymers, hydrogen, metal borides, and elemental boron. Organized into six chapters, this volume begins with an overview of the structures as well as the synthesis of polyhedral borane anions. This text then examines the various types of classes and series of the carboranes. Other chapters consider the relatively intramolecular rearrangements and intramolecular exchange reactions concerning the various closo-carboranes and nido-carboranes. This book discusses as well the formation and the historical significance of a higher boron hydride polymer. The final chapter deals with the structural utilization of boron filaments, which promises to be the first large-scale use for comparatively high purity elemental boron. This book is intended to be suitable for boron chemists, chemical engineers, scientists, and research workers.
New Horizons In Boron Hydride Chemistry
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Author : Joan Cecilia Kunz
language : en
Publisher:
Release Date : 1985
New Horizons In Boron Hydride Chemistry written by Joan Cecilia Kunz and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1985 with Boranes categories.
Electron Deficient Compounds
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Author : K. Wade
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Electron Deficient Compounds written by K. Wade and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
This book is about compounds such as the boron hydrides and associated metal hydrides and alkyls which acquired the label 'electron deficient' when they were thought to contain too few valence electrons to hold together. Though they are now recognized as containing the numbers of bonding electrons appropriate for their structures, the term 'electron deficient' is still commonly applied to many substances that contain too few valence electrons to provide a pair for every pair of atoms close enough to be regarded as covalently bonded. The study of such substances has contributed much to chemistry. Techniques for the vacuum manipulation of volatile substances were devised specifically for their study; developments in valence theory resulted from considerations of their bonding; and the reactivity of several (for example, diborane and complex metal hydrides, lithium and aluminium alkyls) has made them valuable reagents. The purpose of this book is to provide an introduction to the chemistry of these fascinating compounds. The experimental and spectroscopic methods by which they can be studied are outlined, the various types of structure they adopt are described and profusely illustrated, and the relative merits of extended valence bond and simple molecular orbital treatments of their bonding are discussed, with as liberal use of diagrams and as limited recourse to the Greek alphabet as possible. A recurring theme is the importance attached to considerations of molecular sym metry. Their reactions are treated in sufficient detail to show whether these reflect any deficiency of electrons.
Boranes And Metallaboranes
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Author : Catherine E. Housecroft
language : en
Publisher:
Release Date : 1994
Boranes And Metallaboranes written by Catherine E. Housecroft and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994 with Science categories.
This concise introduction to boranes and metalloboranes employs an informal and straightforward style. The author establishes facts first, and rationalization and theories follow. Ideas of cluster bonding are presented, and the author surveys different approaches to the bonding in clusters, emphasizing the use of frontier molecule orbitals and the construction of clusters from fragments. The application of spectroscopic techniques to the elucidation of cluster structure is discussed, with an emphasis on multinuclear NMR spectroscopy. The second edition includes an update on structural data for boranes and their anions. Sections on spectroscopy and the reactivity of metalloboranes have been slightly expanded and references have been updated.
Progress In Boron Chemistry
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Author : H. Steinberg
language : en
Publisher: Elsevier
Release Date : 2013-09-03
Progress In Boron Chemistry written by H. Steinberg and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-09-03 with Science categories.
Progress in Boron Chemistry, Volume I is a 10-chapter text that covers the advances in the chemistry of various boron compounds and their applications. The opening chapter deals with the chemistry of compounds containing boron-boron bonds, followed by a brief overview of some aspects of the coordination chemistry of boron. The subsequent chapters discuss the molecular structures of boron hydrides and the chemotherapeutic potential of boron compounds. Other chapters explore the chemistry of other boron compounds, including heteroaromatic boron compounds, organoperoxyboranes, organoboron heterocycles, and boronic acids. The concluding chapter describes the NMR studies of boron compounds. This book is of value to organic, inorganic, and analytical chemists.
Boron Hydrides High Potential Hydrogen Storage Materials
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Author : Umit B. Demirci
language : en
Publisher:
Release Date : 2011
Boron Hydrides High Potential Hydrogen Storage Materials written by Umit B. Demirci and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011 with Boranes categories.
Boron Chemistry 3
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Author : H. Nöth
language : en
Publisher: Elsevier
Release Date : 2013-10-22
Boron Chemistry 3 written by H. Nöth and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Science categories.
Boron Chemistry contains the selected lectures presented at the Third International Meeting on Boron Chemistry held at Munich & Ettal, FRG on July 5-9, 1976. Separating nine papers as chapters, this book discusses effects of orbital vacancies in boron compounds, the aminoboronation reaction, and the cyclic coordination of boron compounds. This text also explores the organoboranes in synthesis and analysis; the synthesis, structure, and chemical reactions of metalloboranes; and studies of the smaller boron hydrides and their derivatives.