Carbon Monoxide In Organic Synthesis

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Carbon Monoxide In Organic Synthesis

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Author : Jürgen Falbe
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-03-14

Carbon Monoxide In Organic Synthesis written by Jürgen Falbe and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-03-14 with Science categories.

This book reviews some important reactions of carbon monoxide in organic chemistry: hydroformylation, metal carbonyl- and acid catalyzed carbonylation and ring closure reactions with carbon monoxide. It is not merely a translation of the German edition which appeared in 1967 but the text has been completely revised. This was necessary because this chemistry is rapidly developing in research as well as in technical application, which is underlined by the increase of production of e. g. oxo chemicals from about 1.4 million tons in 1967 to 2.7 million tons in 1969, nearly a doubling within 2 years. Quite a number of new research results were published during the last two years, and these additional references have been cited in the English edition. Most of the new papers cited deal with hydroformylation reactions: however, a number of the papers reviewed also report important new aspects in carboxylation and ring closure reactions. The author is indebted to a number of colleagues who helped to collect these new data and have given him valuable hints and would like to thank Miss 1. Forster, Dr. B. Cornils, Dr. D. Hahn, Dr. P. Schneller, Dr. H. Tummes, and Dr. J. Weber for their cooperation, and to Prof. Dr. F. Piacenti (University of Pisa, Italy) for discussions on reaction mecha nisms. The author is especially grateful to Dr. Charles R. Adams of the Shell Development Company, Emeryville, California, for his cooperation in translating the German text.

Carbon Monoxide In Organic Synthesis

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Author : Bartolo Gabriele
language : en
Publisher: John Wiley & Sons
Release Date : 2022-01-10

Carbon Monoxide In Organic Synthesis written by Bartolo Gabriele and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-01-10 with Technology & Engineering categories.

Carbon Monoxide in Organic Synthesis A thoroughly up-to-date overview of carbonylation reactions in the presence of carbon monoxide In Carbon Monoxide in Organic Synthesis: Carbonylation Chemistry, expert researcher and chemist Bartolo Gabriele delivers a robust summary of the most central advances in the field of carbonylation reactions in the presence of carbon monoxide. Beginning with a brief introduction on the importance of carbon monoxide as a building block in modern organic synthesis, the author goes on to describe metal-catalyzed carbonylations utilizing iron, cobalt, nickel, copper, and manganese. Descriptions of palladium, ruthenium, and rhodium-catalyzed reactions follow, as do discussions of metal-free carbonylation processes. The book is organized by metal to make the book useful as a guide for researchers from both academia and industry whose work touches on the direct synthesis of carbonyl compounds, carboxylic acid derivatives, and heterocycles. It aims to stimulate further discoveries in this rapidly developing field. Readers will also enjoy: A thorough introduction to carbonylations promoted by first row transition metal catalysts, including cobalt-catalyzed and nickel-catalyzed carbonylations An exploration of carbonylations promoted by second row transition metal catalysts, including ruthenium-, rhodium-, palladium(0)-, and palladium (II)-catalyzed carbonylations Practical discussions of miscellaneous carbonylation reactions, including carbonylations promoted by third row transition metal catalysts and metal-free carbonylation processes Perfect for catalytic and organic chemists, Carbon Monoxide in Organic Synthesis: Carbonylation Chemistry is also an indispensable resource for chemists working with organometallics and industrial chemists seeking a summary of important processes used to synthesize value-added products.

New Syntheses With Carbon Monoxide

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Author : J. Falbe
language : en
Publisher: Springer
Release Date : 1980-08

New Syntheses With Carbon Monoxide written by J. Falbe and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1980-08 with Science categories.

More than a decade has passed since the appearance of the last edition of the book "Carbon Monoxide in Organic Synthesis". During the intervening period, the signi ficance of carbon monoxide chemistry has become even more evident. The oil crisis and the ever-present awareness of the constant depletion of the oil reserves have both contributed to a surge in activity. The fact that coal will once again replace oil in the near future as a feedstock source has been an impetus for new efforts in the field of carbon monoxide chemistry. Moreover, older almost neglected processes such as the Fischer-Tropsch synthesis have become a focal point for new activities. Therefore, the time was ripe to fundamentally revise "Carbon Monoxide in Organic Synthesis" and to complete its coverage by introducing the chapters "Homo logation" and "Carbon Monoxide Hydrogenation". However, other important sectors of carbon monoxide chemistry such as the con version of synthesis gas to methanol or higher alcohols were excluded. These are treated in the book "Chemierohstoffe aus Kohle", which devotes considerable attention to these syntheses. I would like to thank Drs. Bahrmann, Comils, Frohning, Mullen and Tummes, who had the task of compiling and critically evaluating the large volume of literature which has appeared during the last decade.

New Syntheses With Carbon Monoxide

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Author : J. Falbe
language : en
Publisher: Springer
Release Date : 1980

New Syntheses With Carbon Monoxide written by J. Falbe and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1980 with Science categories.

More than a decade has passed since the appearance of the last edition of the book "Carbon Monoxide in Organic Synthesis". During the intervening period, the signi ficance of carbon monoxide chemistry has become even more evident. The oil crisis and the ever-present awareness of the constant depletion of the oil reserves have both contributed to a surge in activity. The fact that coal will once again replace oil in the near future as a feedstock source has been an impetus for new efforts in the field of carbon monoxide chemistry. Moreover, older almost neglected processes such as the Fischer-Tropsch synthesis have become a focal point for new activities. Therefore, the time was ripe to fundamentally revise "Carbon Monoxide in Organic Synthesis" and to complete its coverage by introducing the chapters "Homo logation" and "Carbon Monoxide Hydrogenation". However, other important sectors of carbon monoxide chemistry such as the con version of synthesis gas to methanol or higher alcohols were excluded. These are treated in the book "Chemierohstoffe aus Kohle", which devotes considerable attention to these syntheses. I would like to thank Drs. Bahrmann, Comils, Frohning, Mullen and Tummes, who had the task of compiling and critically evaluating the large volume of literature which has appeared during the last decade.

Carbonylation

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Author : H.M. Colquhoun
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-06-29

Carbonylation written by H.M. Colquhoun and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-06-29 with Science categories.

Since the publication of our earlier book on transition metal mediated organic synthesis, * there has been a widespread increase of interest in this topic, and transition metal based methodology has become firmly established in many areas of organic chemistry. The direct, catalytic formation of organic carbonyl compounds using carbon monoxide as the source of the carbonyl group has seen exceptional progress, and this carbonylation chemistry is being used increasingly in research and on a larger scale for fine chemicals production. In view of these developments, there is a need for a modem, practi cally oriented book dealing with transition metal based carbonylation chemistry. The present monograph should help fulfill this need, since it is intended specifically to foster the adoption of catalytic carbonylation as a general tool in synthetic organic chemistry. It deals exclusively with reactions involving the interconversion of carbon monoxide and organic carbonyl compounds, and although the majority of the reactions discussed involve catalytic formation of carbonyl compounds, potentially valuable syntheses requiring stoichiometric quantities of transition metal are also included. In addition, a chapter is devoted to the remarkably useful reverse transformation (decarbonylation), in which an organic carbonyl group is eliminated in the form of carbon monoxide.

Catalytic Carbonylation Reactions

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Author : Matthias Beller
language : en
Publisher: Springer
Release Date : 2006-09-08

Catalytic Carbonylation Reactions written by Matthias Beller and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-09-08 with Science categories.

In this book, leading experts from academia and industry offer a comprehensive presentation and discussion of the major reaction types of carbon monoxide. The authors highlight important carbonylation reactions such as hydroformylation, alkoxy-carbonylations, co/olefin-copolymerization, Pauson-Khand reactions and others. They illustrate applications in organic synthesis and give industrial examples. This volume is designed to provide graduate students and researchers with essential information on the use of carbon monoxide in organic synthesis.

Chemicals From Synthesis Gas

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Author : R.A. Sheldon
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-04-18

Chemicals From Synthesis Gas written by R.A. Sheldon and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-04-18 with Science categories.

The origins of the petrochemical industry can be traced back to the 1920s when simple organic chemicals such as ethanol and isopropanol were first prepared on an industrial scale from by-products (ethylene and propylene) of oil refining. This oil-based petrochemical industry, with lower olefms and aromatics as the key building blocks, rapidly developed into the enormous industry it is today. A multitude of products that are indispensible to modern day society, from plastics to pharmaceuticals, are derived from oil and natural gas-based hydro carbons. The industry had its heyday in the '50s and '60s when predictions of future growth rates tended to be exponential curves. However, two developments that took place in the early '70s disturbed this simplistic and optimistic view of the future. Firstly, the publication of the report for the Cub of Rome on the 'Limits to Growth' emphasized the finite nature of non-renewable fossil fuel resources. Secondly, the Oil Crisis of 1973 emphasized the vulnerability of an energy and chemicals industry that is based largely on a single raw material.

Transition Metal Catalyzed Carbonylation Reactions

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Author : Matthias Beller
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-08-13

Transition Metal Catalyzed Carbonylation Reactions written by Matthias Beller and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-08-13 with Science categories.

Transition Metal Catalyzed Carbonylation Reactions is a comprehensive monograph focusing on carbon monoxide usage. This book provides students and researchers in organic synthesis with a detailed discussion of carbonylation from the basics through to applications. The authors have structured the book around the types of reactions, based on the different nucleophiles involved. Scientists working in carbonylation or with carbon monoxide, as well as teachers of organic synthesis can use this book to become familiar with this important area of organic chemistry.

Hydroformylation

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Author : Armin Börner
language : en
Publisher: John Wiley & Sons
Release Date : 2016-04-25

Hydroformylation written by Armin Börner and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-04-25 with Technology & Engineering categories.

Filling a gap in the market for an up-to-date work on the topic, this unique and timely book in 2 volumes is comprehensive in covering the entire range of fundamental and applied aspects of hydroformylation reactions. The two authors are at the forefront of catalysis research, and unite here their expertise in synthetic and applied catalysis, as well as theoretical and analytical chemistry. They provide a detailed account of the catalytic systems employed, catalyst stability and recovery, mechanistic investigations, substrate scope, and technical implementation. Chapters on multiphase hydroformylation procedures, tandem hydroformylations and other industrially applied reactions using syngas and carbon monoxide are also included. The result is a must-have reference not only for synthetic chemists working in both academic and industrial research, but also for theoreticians and analytical chemists.

Carbon Dioxide And Organometallics

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Author : Xiao-Bing Lu
language : en
Publisher: Springer
Release Date : 2015-08-26

Carbon Dioxide And Organometallics written by Xiao-Bing Lu and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-08-26 with Science categories.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal