Catalytic Polymerization Of Cycloolefins
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Catalytic Polymerization Of Cycloolefins
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Author : V. Dragutan
language : en
Publisher: Elsevier
Release Date : 2000-06-26
Catalytic Polymerization Of Cycloolefins written by V. Dragutan and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-06-26 with Technology & Engineering categories.
This book covers the most important topics concerning cationic Ziegler-Natta and ring-opening metathesis polymerization of cycloolefins. The work describes the major pathways that cycloolefins can follow under the action of specific catalytic systems, essentially vinyl and ring-opening polymerization, both reaction types allowing the manufacture of distinct products with wide applicability in modern technologies. The comprehensive data available on this subject are logically and systematically selected and reviewed throughout 18 chapters, according to the basic catalytic processes involved, types of monomers and catalysts employed, reaction conditions and application fields. The modern trends in design of chiral metallocene catalysts, well-defined living metathesis catalysts, catalysts tolerant toward functionalities and water systems are highlighted. The book discusses in detail the relevant aspects of these processes including reaction thermodynamics, kinetics, mechanisms and stereochemistry and correlates the structure of produced polymers with their chemical and physical-mechanical properties. Related important topics include Ziegler-Natta polymerization of olefins and dienes, atom transfer radical polymerization of vinyl compounds, metathesis of olefins and acetylenes, acyclic diene metathesis reaction, carbonyl olefination reaction, metathesis polymerization of acetylenes, metathesis degradation of polymers and ring-opening polymerization of heterocycles. Special emphasis is laid upon the manufacture of commerical products, new polymers and copolymers of potential interest for industry and design and synthesis of speciality polymers with particular structures and architectures and desired properties. The book critically evaluates the most recent achievements reported in this field and outlines the modern trends on the research and application of the catalytic processes for cycloolefin polymerization. For the first time, comprehensive information about the published data on the subject up to now is provided for both academic and industrial researchers working in the areas of polymer chemistry, organic and organometallic chemistry, surface science and catalysis, petrochemistry and chemical engineering. This stimulating book offers an enlightening introduction and a quick documentation on the subject as well as a solid background in this field. Moreover, the work offers a wealth of useful information for specialists applying polymers in various scientific and industrial areas.
Olefin Metathesis And Ring Opening Polymerization Of Cyclo Olefins
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Author : Valerian Drăguțan
language : en
Publisher:
Release Date : 1985
Olefin Metathesis And Ring Opening Polymerization Of Cyclo Olefins written by Valerian Drăguțan and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1985 with Science categories.
Catalytic Polymerization Of Olefins
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Author : T. Keii
language : en
Publisher: Elsevier
Release Date : 1986-04-01
Catalytic Polymerization Of Olefins written by T. Keii and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1986-04-01 with Technology & Engineering categories.
This book covers the proceedings of a symposium which was attended by researchers from all over the world who reported on and discussed recent advances in the field of catalytic polymerization of olefins. Over two decades have elapsed since the discovery of the Ziegler-Natta catalyst. Tremendous research effort has been aimed at improving this marvelous catalyst. In twenty-five years since the first publication, more than 15,000 papers and patents on the subject and on related subjects have appeared. This effort has yielded new generations of Ziegler-Natta catalysts with superior activity and stereospecificity. The complexities arising from the heterogeneity of the catalyst, however, have hindered understanding of the catalytic processes which take place on the catalyst surface. Nevertheless, many fundamental features of the catalyst system have now been clarified reasonably well. Recently a highly active homogeneous catalytic system has been developed, which is capable of catalyzing even isotactic polymerization of propene. There is no doubt that this finding will not only contribute to our understanding of the detailed mechanism of polymerization but also stimulate the development of various kinds of tailored polymers. Thus this subject will remain of paramount importance in the development of chemistry and polymer science for a long time to come.
Stereoselective Polymerization With Single Site Catalysts
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Author : Lisa S. Baugh
language : en
Publisher: CRC Press
Release Date : 2007-11-29
Stereoselective Polymerization With Single Site Catalysts written by Lisa S. Baugh and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-11-29 with Science categories.
New synthetic techniques allow chemists to modify polymer microstructures more precisely than ever, making it possible to design materials that meet increasingly demanding performance requirements. Written and edited by experts in the field, Stereoselective Polymerization with Single-Site Catalysts reviews how the relative stereochemistry of
Metathesis Polymerization Of Olefins And Polymerization Of Alkynes
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Author : Yavuz Imamogammalu
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Metathesis Polymerization Of Olefins And Polymerization Of Alkynes written by Yavuz Imamogammalu and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The first NATO Advanced Study Institute on Olefin Metathesis and Polymerization Catalysts was held on September 10-22, 1989 in Akcay, Turkey. Based on the fundamental research of RRSchrock, RGrubbs and K.B.Wagener in the field of ring opening metathesis polymerization (ROMP), acyclic diene metathesis (ADMET) and alkyne polymerization, these areas gained growing interest within the last years. Therefore the second NATO-ASI held on metathesis reactions was on Ring Opening Metathesis Po lymerization of Olefins and Polymerization of Alkynes on September 3-16, 1995 in Akcay, Turkey. The course joined inorganic, organic and polymer chemists to exchange their knowledge in this field. This volume contains the main and short lectures held in Akcay. To include ADMET reactions better into the title of this volume we changed it into: Metathesis Polymerization of Olefins and Alkyne Polymerization. This volume is addressed to research scientists, but also to those who start to work in the area of olefin metathesis and alkyne polymerization. The topics of the course were: mechanism of ROMP reactions/ new catalysts for ROMP/ new products by ROMP/ new catalysts for ADMET/ new products by ADMETI degradation of polymer by metathesis reactions/ alkyne polymerization and metathesis/ industrial application of metathesis reactions. The Advanced Study Institute was generously sponsored by the Scientific Affairs Division of NATO and the editor gratefully acknowledges this sponsorship. We also thank the Members of the Local Organizing Committee for their engagement on a successful NATO-AS!.
Transition Metals And Organometallics As Catalysts For Olefin Polymerization
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Author : Walter Kaminsky
language : en
Publisher: Springer
Release Date : 1988
Transition Metals And Organometallics As Catalysts For Olefin Polymerization written by Walter Kaminsky and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with Alkenes categories.
Ring Opening Metathesis Polymerisation And Related Chemistry
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Author : Ezat Khosravi
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Ring Opening Metathesis Polymerisation And Related Chemistry written by Ezat Khosravi and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Since the last ASI in Turkey in Sept. 1995, the olefin metathesis has made remarkable strong developments with an incredible speed in various directions. New catalyst systems have been developed which have resulted in the synthesis of novel materials. Other fascinating developments have been the new catalysts for stereoselective metathesis and catalysts with considerable functional group tolerance. These new catalysts in addition to Ring Opening Metathesis Polymerisation (ROMP) and Acyclic Diene Metathesis (ADMET) are now powerful tools for Ring Closing Metathesis (RCM) and have found many applications in the synthesis of natural products. A lot of information has been established about all aspects of the olefin metathesis and there is a vast literature concerning the process, covering the initiators, mechanistic features and applications of this reaction in organic and polymer synthesis. The NATO ASI on rd th ROMP and Related Chemistry took place in Polanica-Zdroj, Poland during 3 to 15 Sept. 2000, to highlight the developments in this area and to discuss the prospects and visions for the year 2000 and beyond. The aims of the ASI were: to provide a platform for dissemination of knowledge; to promote communication between people who have a serious interest in this field of chemistry; to help establishing international scientific contacts and to provide an opportunity for the scientists with an appropriate scientific background to learn of recent developments in this field of science. There were 15 lecturers and 67 participants in this NATO ASI.
Polymers From Cycloolefins
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Author : Valerian Dragutan
language : en
Publisher: Marcel Dekker Incorporated
Release Date : 2009-10-14
Polymers From Cycloolefins written by Valerian Dragutan and has been published by Marcel Dekker Incorporated this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-10-14 with Technology & Engineering categories.
Characterized as a closed ring of carbon atoms with one or more double bonds, cycloolefins can be polymerized into a variety of linear polymers with applications in microelectronics, medicine, textiles, and more. Compiling a wealth of recent literature in this area, Polymers from Cycloolefins offers an up-to-date, comprehensive, and well-organized analysis of the synthesis, properties, and commercial applications cycloolefin-derived polymers. The book examines the types of monomers, catalysts, initiators, and solvents used for various cycloolefin polymerization reactions. It concludes with a review of cutting-edge commercial products and of future prospects for the design of new polymers.
Isospecific Polymerization Of Olefins
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Author : Y.V. Kissin
language : en
Publisher: Springer
Release Date : 1985-08-07
Isospecific Polymerization Of Olefins written by Y.V. Kissin and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1985-08-07 with Science categories.
The discoveries of organometallic catalysts for olefin polymerization by Karl Ziegler and that of stereoregular olefin polymers by Giulio Natta are probably the two most important achievements in the areas of catalysis and polymer chemistry in the second half of this century. They led to the development of a new branch of chemical industry, and to a large volume production of high-density and linear low-density polyethylene, isotactic polypropylene, ethylene-propylene rubbers, isotactic poly I-butene, and poly-4-methyl-l-pentene. These discoveries merited the Nobel prize, which was awarded to K. Ziegler and G. Natta in 1963. The initial works of Ziegler and Natta were followed by an "explosion" of scientific papers and patents covering all aspects of polymerization chemistry, catalyst synthesis, and polymerization kinetics as well as the structural, chemical, physical, and technological characteristics of stereo regular polyolefins, polydienes, and olefin copolymers. It is sufficient to say that in the twenty-five years after the first publications more than 15,000 papers and patents appeared on subjects related to the area. . The development brought about the establishment of several prominent groups of scientists occupied with the study of olefin polymerization. The most important of these were scientific schools in Italy, Germany, England, the United States, Japan, the Soviet Union, Czechoslovakia, and Venezuela. In addition, many major chemical and petrochemical corporations throughout the world established labora tories devoted to the development of the technology of catalyst synthesis and olefin polymerization.
Transition Metal Catalyzed Polymerizations
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Author : Roderic P. Quirk
language : en
Publisher: CUP Archive
Release Date : 1988
Transition Metal Catalyzed Polymerizations written by Roderic P. Quirk and has been published by CUP Archive this book supported file pdf, txt, epub, kindle and other format this book has been release on 1988 with Science categories.
This volume contains the proceedings of the Second International Symposium on Transition Metal Catalyzed Polymerizations held in 1986. The papers provide a broad-based perspective covering recent scientific and technological advances in Ziegler-Natta and metathesis polymerization, including olefin, diene, and acetylene polymerization, and copolymerization. The emphasis on reaction kinetics of polymerizations in different reagent and catalyst environments makes this volume of interest to both academic and industrial researchers.