Controlled And Living Polymerizations


Controlled And Living Polymerizations
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Controlled And Living Polymerizations


Controlled And Living Polymerizations
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Author : Krzysztof Matyjaszewski
language : en
Publisher: John Wiley & Sons
Release Date : 2009-12-23

Controlled And Living Polymerizations written by Krzysztof Matyjaszewski and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-12-23 with Science categories.


Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.



Controlled And Living Polymerizations


Controlled And Living Polymerizations
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Author : Krzysztof Matyjaszewski
language : en
Publisher: John Wiley & Sons
Release Date : 2009-09-28

Controlled And Living Polymerizations written by Krzysztof Matyjaszewski and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-09-28 with Science categories.


Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.



Fundamentals Of Controlled Living Radical Polymerization


Fundamentals Of Controlled Living Radical Polymerization
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Author : Nicolay V. Tsarevsky
language : en
Publisher: Royal Society of Chemistry
Release Date : 2013

Fundamentals Of Controlled Living Radical Polymerization written by Nicolay V. Tsarevsky and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013 with Science categories.


Provides an in-depth history, description, and mechanistic understanding of each of the controlled/living radical polymerization techniques and practical details necessary to carry out the reactions.



Living And Controlled Polymerization


Living And Controlled Polymerization
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Author : Joseph Jagur-Grodzinski
language : en
Publisher: Nova Publishers
Release Date : 2006

Living And Controlled Polymerization written by Joseph Jagur-Grodzinski and has been published by Nova Publishers this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006 with Science categories.


The living/controlled polymerisation techniques opened new vistas in polymer chemistry. The leading authorities in this field and its pioneers contributed chapters to this collective volume. The controlled polymerisation techniques have enabled preparation of polymers, copolymers, and block copolymers with predetermined molecular weights and narrow polydispersity, in which functional groups or biologically active molecules could be placed at well defined locations. They have also enabled preparation of advanced polymeric structures with precisely determined architectures and improved properties. Moreover, they have provided opportunities for preparation of novel polymeric materials from monomers, which before have not been suitable or accessible for such purposes. Properties of some of these polymeric materials may be significantly different from those of the existing ones. They provide opportunities for new applications. Several patents have already been approved for such speciality applications as, drug delivery, biocompatible surfaces, thermoplastic elastomers, moisture curable sealants, and so on. Many more products, based on polymers fabricated by the living/ controlled polymerisation techniques, will certainly emerge in such specialised areas as, nanotechnology, medical devices, "smart polymers", sensors , smart separation technologies, optical fibres and other optical applications, various biomaterials, etc.



Synthesis Of Controlled Polymeric Structures Through Living Polymerizations And Related Processes


Synthesis Of Controlled Polymeric Structures Through Living Polymerizations And Related Processes
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Author : William J. Brittain
language : en
Publisher:
Release Date : 1995

Synthesis Of Controlled Polymeric Structures Through Living Polymerizations And Related Processes written by William J. Brittain and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1995 with Polymerization categories.




Controlled Radical Polymerization


Controlled Radical Polymerization
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Author : Krzysztof Matyjaszewski
language : en
Publisher:
Release Date : 1998

Controlled Radical Polymerization written by Krzysztof Matyjaszewski and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998 with Science categories.


Recent work in polymer chemistry has allowed scientists to control the polymerization reaction and produce increasingly well-defined polymers. This volume examines current work in the field and describes the synthesis of new materials. It includes discussions of nitroxide-mediated and metal-mediated radical polymerizations. It also includes an overview of the fundamentals of radical chemistry, making it accessible to a wide range of chemists and materials scientists.



Advances In Controlled Living Radical Polymerization


Advances In Controlled Living Radical Polymerization
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Author : Krzysztof Matyjaszewski
language : en
Publisher:
Release Date : 2003

Advances In Controlled Living Radical Polymerization written by Krzysztof Matyjaszewski and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003 with Science categories.


Advances in Controlled/Living Radical Polymerization presents new developments in controlled/living radical polymerization in three areas: atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation transfer (RAFT). This book also includes synthesis and characterization of many new materials.



Statistical Gradient Block And Graft Copolymers By Controlled Living Radical Polymerizations


Statistical Gradient Block And Graft Copolymers By Controlled Living Radical Polymerizations
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Author : Kelly A. Davis
language : en
Publisher: Springer Science & Business Media
Release Date : 2007-11-02

Statistical Gradient Block And Graft Copolymers By Controlled Living Radical Polymerizations written by Kelly A. Davis and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-11-02 with Technology & Engineering categories.


The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions cannot be excluded completely, they are limited in their extent and consequently the mol ecular weight is controlled, the polydispersity index is small and functionalities can be attached to the macromolecules. These features are indicative of the real isation of well defined polymer architectures such as block copolymers, star shaped and comb shaped copolymers.



Controlled Living Radical Polymerization


Controlled Living Radical Polymerization
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Author : Krzysztof Matyjaszewski
language : en
Publisher: ACS Symposium
Release Date : 2009

Controlled Living Radical Polymerization written by Krzysztof Matyjaszewski and has been published by ACS Symposium this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009 with Language Arts & Disciplines categories.


This book is focused on recent progress in the dynamically developing field of controlled/living radical polymerization. It is a sequel to ACS Symposium Series 685, 768, 854, and 944. The volume contains 24 chapters on other controlled/living radical polymerization techniques including kinetics and mechanism of RAFT, DT, NMP, and OMRP, macromolecular architecture by RAFT, DT, and NMP, materials prepared by RAFT and NMP, and industriral aspects of RAFT and NMP.



Monitoring Polymerization Reactions


Monitoring Polymerization Reactions
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Author : Wayne F. Reed
language : en
Publisher: John Wiley & Sons
Release Date : 2014-01-21

Monitoring Polymerization Reactions written by Wayne F. Reed and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-01-21 with Technology & Engineering categories.


Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant.