Cryptands And Cryptates
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Cryptands And Cryptates
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Author : Fabbrizzi Luigi
language : en
Publisher: World Scientific
Release Date : 2017-11-08
Cryptands And Cryptates written by Fabbrizzi Luigi and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-11-08 with Science categories.
Cryptands were introduced by Jean-Marie Lehn in 1969 as cage-shaped selective ligands for alkali and alkaline-earth metal ions, which lie at the heart of supramolecular chemistry. This book reports on much of the research in the field since the '70s, and looks at, amongst other topics, metal coordination chemistry, anion coordination chemistry, the encapsulation and taming of reactive anions, the formation of cascade complexes and the design of fluorescent sensors for ionic analytes. Cryptands and Cryptates has been written as a coursebook, structured as a series of lectures for graduate students or advanced researchers in chemistry, materials science, chemical biology and nanotechnology. It is fully illustrated to show experiments and results, and is intended to stimulate further interest in this fertile field of supramolecular chemistry. Chapters are preceded by a Foreword by Jean-Marie Lehn. Contents: The Beginning of the Story: Crown EthersThe Birth of Cryptands and CryptatesRecognition of the Radius of s-Block Metal Ions by CryptandsCompetitive Hosts for Alkali Metal Ions: Spherands and DerivativesThe Coordination Chemisty of Ammonium and OxoniumThe Age of Anion Coordination ChemistryThe Appearance of Bistren CryptandsBistren Cryptands Grow and MultiplyThe Formation of Dicopper(II) Bistren Cryptates and the Nature of Their Cavity Anion Recognition by Dicopper(II) Bistren Cryptates: The Geometrical FactorAnion Fluorescence Sensing by Dimetallic Bistren Cryptates: The Fluorophore–Spacer–Receptor ParadigmAnion Fluorescence Sensing by Dimetallic Bistren Cryptates: The Indicator Displacement ParadigmNucleotide Recognition and Sensing by a Dicopper(II) Bistren CryptateAnion Inclusion by Hexaprotonated Bistrens: HalidesAnion Inclusion by Hexaprotonated Bistrens: OxoanionsRecognition of Linear Dicarboxylates: The Hydrogen Bonding vs Metal–Ligand Interactions ContestBistren Amides: Neutral Receptors That Recognise Anions Only Through Hydrogen Bonding InteractionsThe Taming of Peroxide (By a Bistren Amide Cryptand)Coordination Chemistry of the Smallest Bistren CryptandSize Exclusion Selectivity: The Case of FluoridePseudo-Cryptands: Closing the Receptor's Cavity with a Transition MetalUse of Cryptands to Make Automatic Molecular BurettesCages in Everyday Life, Chemistry and Art Readership: Graduate students or advanced researchers in chemistry, materials science, chemical biology and nanotechnology. Keywords: Supramolecular Chemistry;Coordination Chemistry of Alkali Metal Ions;Transition Metal Coordination Chemistry;Anion Coordination Chemistry;Crown Ethers;Cryptands;Bistren Cryptands;Recognition of Anions and of Metal Ions;Fluorescent Sensing of Anions and Metal Ions;Encapsulation of Reactive AnionsReview: Key Features: While review articles have been published on partial aspects of this topic, no books have been devoted to an overall and homogeneous treatment of 'cryptands and cryptates'
Macrobicyclic Cryptands
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Author : Parimal K. Bharadwaj
language : en
Publisher: Cambridge Scholars Publishing
Release Date : 2024-01-09
Macrobicyclic Cryptands written by Parimal K. Bharadwaj and has been published by Cambridge Scholars Publishing this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-01-09 with Juvenile Nonfiction categories.
Cryptands, soon after their introduction in early 1970s, have proven enormously useful in several areas of chemistry, biology, and materials science. This is continuously growing and venturing into newer fields of supramolecular chemistry research. There is no other book available that attempts to explore all aspects of cryptand chemistry. This book provides a good account of synthetic methods for different types of cryptands, especially chiral cryptands, which remain mostly unexplored. Using the cryptand cavity for homogeneous catalysis, reversible fluorescence sensing, FRET, optically nonlinear materials and construction of molecular level photonic devices – are all discussed. This book also gives an account of using cryptands for a new generation of amphiphiles for Langmuir-Blodgett films and stable vesicles besides the stabilization of metal nanoparticles. This book will be useful for senior university students interested in supramolecular chemistry, as well as budding researchers in this area.
Inorganic Biochemistry
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Author : H A O Hill
language : en
Publisher: Royal Society of Chemistry
Release Date : 2007-10-31
Inorganic Biochemistry written by H A O Hill and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-10-31 with Science categories.
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Transition Metals In Supramolecular Chemistry
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Author : L. Fabbrizzi
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-03-09
Transition Metals In Supramolecular Chemistry written by L. Fabbrizzi and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-03-09 with Science categories.
Since the pioneering publications on coordination chemistry by Lehn and Pedersen in the late 1960s, coupled with the more orthodox interest from the transition metal chemists on template reactions (Busch, 1964), the field of supramolecular chemistry has grown at an astonishing rate. The use of transition metals as essential constituents of multi-component assemblies has been especially sharp in recent years, since the metals are prone to quick and reversible redox changes, and there is a wide variety of metal--ligand interactions. Such properties make supramolecular complexes of transition metal ions suitable candidates for exploration as light--energy converters and signal processors. Transition Metals in Supramolecular Chemistry focuses on the following main topics: (1) metal controlled organization of novel molecular assemblies and shapes; (2) design of molecular switches and devices operating through metal centres; (3) supramolecular catalysts that mimic metalloenzymes; (4) metal-containing sensory reagents and supramolecular recognition; and (5) molecular materials that display powerful electronic, optoelectronic and magnetic properties.
Comprehensive Supramolecular Chemistry Ii
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Author : George W. Gokel
language : en
Publisher: Elsevier
Release Date : 2017-06-22
Comprehensive Supramolecular Chemistry Ii written by George W. Gokel and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-06-22 with Science categories.
Comprehensive Supramolecular Chemistry II, Second Edition, Nine Volume Set is a ‘one-stop shop’ that covers supramolecular chemistry, a field that originated from the work of researchers in organic, inorganic and physical chemistry, with some biological influence. The original edition was structured to reflect, in part, the origin of the field. However, in the past two decades, the field has changed a great deal as reflected in this new work that covers the general principles of supramolecular chemistry and molecular recognition, experimental and computational methods in supramolecular chemistry, supramolecular receptors, dynamic supramolecular chemistry, supramolecular engineering, crystallographic (engineered) assemblies, sensors, imaging agents, devices and the latest in nanotechnology. Each section begins with an introduction by an expert in the field, who offers an initial perspective on the development of the field. Each article begins with outlining basic concepts before moving on to more advanced material. Contains content that begins with the basics before moving on to more complex concepts, making it suitable for advanced undergraduates as well as academic researchers Focuses on application of the theory in practice, with particular focus on areas that have gained increasing importance in the 21st century, including nanomedicine, nanotechnology and medicinal chemistry Fully rewritten to make a completely up-to-date reference work that covers all the major advances that have taken place since the First Edition published in 1996
Encyclopedia Of Supramolecular Chemistry Two Volume Set Print
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Author : Jerry L. Atwood
language : en
Publisher: CRC Press
Release Date : 2013-10-09
Encyclopedia Of Supramolecular Chemistry Two Volume Set Print written by Jerry L. Atwood and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-09 with Science categories.
The two-volume Encyclopedia of Supramolecular Chemistry offers authoritative, centralized information on a rapidly expanding interdisciplinary field. User-friendly and high-quality articles parse the latest supramolecular advancements and methods in the areas of chemistry, biochemistry, biology, environmental and materials science and engineering, physics, computer science, and applied mathematics. Designed for specialists and students alike, the set covers the fundamentals of supramolecular chemistry and sets the standard for relevant future research.
Bulletin Of The Chemical Society Of Japan
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Author : Nihon Kagakkai
language : en
Publisher:
Release Date : 1996
Bulletin Of The Chemical Society Of Japan written by Nihon Kagakkai and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996 with Chemistry categories.
Optical Methods
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Author : Larry J. Kricka
language : en
Publisher: Amer. Assoc. for Clinical Chemistry
Release Date : 2003
Optical Methods written by Larry J. Kricka and has been published by Amer. Assoc. for Clinical Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003 with Science categories.
Stereochemical And Stereophysical Behaviour Of Macrocycles
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Author : Gerard Meurant
language : en
Publisher: Elsevier
Release Date : 2012-12-02
Stereochemical And Stereophysical Behaviour Of Macrocycles written by Gerard Meurant and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.
Stereochemical and Stereophysical Behavior of Macrocycles deals with the stereochemical and stereophysical properties of macrocyclic ligands and their coordination compounds. More specifically, the stereochemistry of metallic macrocyclics is discussed, along with the relationship between the thermodynamics and stereochemistry of macrocyclics and cryptates. The stereochemical aspects of the macrocycles of second and third row transition elements are also examined. Comprised of three chapters, this volume begins with an introduction to the stereochemistry of metallic macrocyclics as well as their structure, together with the conformation of their chemical rings and the steric effects of their coordination geometry. The next chapter considers the relationship between the thermodynamics and stereochemistry of macrocyclics and cryptates, with particular reference to the macrocyclic and cryptate effect. Cation-ligand interactions and solvent effects upon complex formation are described, along with macrocyclic and macrobicyclic ligands having different donor atoms. The final chapter is devoted to the stereochemical aspects of the macrocycles of transition metal ions, with additional comments on the stereochemistry of copper and nickel in unusual oxidation states. This book will be of interest to inorganic chemists.
Lanthanide Luminescence
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Author : Pekka Hänninen
language : en
Publisher: Springer Science & Business Media
Release Date : 2011-06-21
Lanthanide Luminescence written by Pekka Hänninen and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-06-21 with Science categories.
Lanthanides have fascinated scientists for more than two centuries now, and since efficient separation techniques were established roughly 50 years ago, they have increasingly found their way into industrial exploitation and our everyday lives. Numerous applications are based on their unique luminescent properties, which are highlighted in this volume. It presents established knowledge about the photophysical basics, relevant lanthanide probes or materials, and describes instrumentation-related aspects including chemical and physical sensors. The uses of lanthanides in bioanalysis and medicine are outlined, such as assays for in vitro diagnostics and research. All chapters were compiled by renowned scientists with a broad audience in mind, providing both beginners in the field and advanced researchers with comprehensive information on on the given subject.