Cycloaddition Reactions In Organic Synthesis
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Cycloaddition Reactions In Organic Synthesis
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Author : W. Carruthers
language : en
Publisher: Elsevier
Release Date : 2013-10-22
Cycloaddition Reactions In Organic Synthesis written by W. Carruthers and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Science categories.
Demonstrates the wide scope of cycloaddition reactions, including the Diels-Alder reaction, the ene reaction, 1,3-dipolar cycloadditions and [2+2] cycloadditions in organic synthesis. The author, a leading exponent of the subject, illustrates the ways in which they can be employed in the synthesis of a wide range of carbocyclic and heterocyclic compounds, including a variety of natural products of various types. Special attention is given to intramolecular reactions, which often provide a rapid and efficient route to polycyclic compounds, and to the stereochemistry of the reactions, including recent and developing work on enantioselective synthesis.
Cycloaddition Reactions In Organic Synthesis
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Author : Shu Kobayashi
language : en
Publisher: John Wiley & Sons
Release Date : 2002
Cycloaddition Reactions In Organic Synthesis written by Shu Kobayashi and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002 with Science categories.
Cyclo additions are among the most important tools for synthesis in organic chemistry, since this type of reaction is vital to the modern synthesis of natural products and biologically effective substances; Catalysis with metals plays an increasingly important role in these reactions, often allowing several sterocenters to be selectively integrated in the subsequent target molecule. Kobayashi and Jorgensen's manual provides numerous examples of cyclopropanes, [2+2], [3+2] and [4+2] cycloadditions and 1,3-dipolar additions. A number of experimental procedures give a concrete idea of the use of metal-catalytic cyclo additions in modern synthesis.; The book is aimed at all chemists working in synthesis laboratories, whether in industry or academia, who want to effectively use cyclo additions for their reactions.
Methods And Applications Of Cycloaddition Reactions In Organic Syntheses
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Author : Nagatoshi Nishiwaki
language : en
Publisher: John Wiley & Sons
Release Date : 2013-12-17
Methods And Applications Of Cycloaddition Reactions In Organic Syntheses written by Nagatoshi Nishiwaki and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-12-17 with Science categories.
Advanced tools for developing new functional materials and applications in chemical research, pharmaceuticals, and materials science Cycloadditions are among the most useful tools for organic chemists, enabling them to build carbocyclic and heterocyclic structures. These structures can then be used to develop a broad range of functional materials, including pharmaceuticals, agrochemicals, dyes, and optics. With contributions from an international team of leading experts and pioneers in cycloaddition chemistry, this book brings together and reviews recent advances, trends, and emerging research in the field. Methods and Applications of Cycloaddition Reactions in Organic Syntheses focuses on two component cycloadditions, with chapters covering such topics as: N1 unit transfer reaction to C–C double bonds [3+2] Cycloaddition of α, β-unsaturated metal-carbene complexes Formal [3+3] cycloaddition approach to natural product synthesis Development of new methods for the construction of heterocycles based on cycloaddition reaction of 1,3-dipoles Cycloreversion approach for preparation of large π-conjugated compounds Transition metal-catalyzed or mediated [5+1] cycloadditions Readers will learn methods for seamlessly executing important reactions such as Diels-Alder and stereoselective dipolar reactions in order to fabricate heterocyclic compounds, natural products, and functional molecules. The book not only features cutting-edge topics, but also important background information, such as the contributors’ process for developing new methodologies, to help novices become fully adept in the field. References at the end of each chapter lead to original research papers and reviews for facilitating further investigation of individual topics. Covering the state of the science and technology, Methods and Applications of Cycloaddition Reactions in Organic Syntheses enables synthetic organic chemists to advance their research and develop new functional materials and applications in chemical research, pharmaceuticals, and materials science.
Cycloaddition Reactions In Organic Synthesis
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Author : William Carruthers
language : en
Publisher:
Release Date : 1990
Cycloaddition Reactions In Organic Synthesis written by William Carruthers and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1990 with categories.
Cobalt Catalysis In Organic Synthesis
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Author : Marko Hapke
language : en
Publisher: John Wiley & Sons
Release Date : 2020-04-06
Cobalt Catalysis In Organic Synthesis written by Marko Hapke and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-04-06 with Technology & Engineering categories.
Provides a much-needed account of the formidable "cobalt rush" in organic synthesis and catalysis Over the past few decades, cobalt has turned into one of the most promising metals for use in catalytic reactions, with important applications in the efficient and selective synthesis of natural products, pharmaceuticals, and new materials. Cobalt Catalysis in Organic Synthesis: Methods and Reactions provides a unique overview of cobalt-catalysed and -mediated reactions applied in modern organic synthesis. It covers a broad range of homogeneous reactions, like cobalt-catalysed hydrogenation, hydrofunctionalization, cycloaddition reactions, C-H functionalization, as well as radical and biomimetic reactions. First comprehensive book on this rapidly evolving research area Covers a broad range of homogeneous reactions, such as C-H activation, cross-coupling, synthesis of heterocyclic compounds (Pauson-Khand), and more Chapters on low-valent cobalt complexes as catalysts in coupling reactions, and enantioselective cobalt-catalyzed transformations are also included Can be used as a supplementary reader in courses of advanced organic synthesis and organometallic chemistry Cobalt Catalysis in Organic Synthesis is an ideal book for graduates and researchers in academia and industry working in the field of synthetic organic chemistry, catalysis, organometallic chemistry, and natural product synthesis.
Click Reactions In Organic Synthesis
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Author : Srinivasan Chandrasekaran
language : de
Publisher: John Wiley & Sons
Release Date : 2016-06-22
Click Reactions In Organic Synthesis written by Srinivasan Chandrasekaran and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-06-22 with Science categories.
Endlich ein Buch zu Click-Reaktionen mit Schwerpunkt auf der organischen Synthese. Beschrieben werden das Click-Konzept, die zugrunde liegenden Mechanismen und Hauptanwendungsgebiete. NÜTZLICH: Die Click-Chemie ist ein wirkungsvoller Ansatz, um auf einfache Weise komplexe organische Moleküle aus verfügbaren Ausgangsmaterialien zu erzeugen ? der Traum jedes Organikers. EINZIGARTIGER SCHWERPUNKT: Aufgrund des besonderen Schwerpunkts auf der organischen Synthese ist dieses Buch für jeden Synthesechemiker von hohem Interesse. HILFREICH: Click-Reaktionen sind stereospezifisch, einfach durchzuführen, hoch ergiebig und lassen sich in einfach zu entfernenden oder nicht schädlichen Lösungsmitteln durchführen. INTERDISZIPLINÄR: Das Click-Konzept ist bei der Herstellung natürlicher Produkte, bioaktiver Verbindungen, von Kohlenhydraten, Arzneimitteln, Polymeren, supramolekularer Strukturen und Materialien weit verbreitet.
Cycloaddition Reactions Of Heterocumulenes
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Author : Henri Ulrich
language : en
Publisher:
Release Date : 1967
Cycloaddition Reactions Of Heterocumulenes written by Henri Ulrich and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1967 with Cumulenes categories.
Essentials Of Pericyclic And Photochemical Reactions
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Author : Biswanath Dinda
language : en
Publisher: Springer
Release Date : 2016-11-18
Essentials Of Pericyclic And Photochemical Reactions written by Biswanath Dinda and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-11-18 with Science categories.
This book provides a concise introduction to pericyclic and photochemical reactions for organic synthesis. In the first part about pericyclic reactions, the author explains electrocyclic reactions, cycloaddition reactions, sigmatropic rearrangements, and group transfer reactions. The second part on photochemistry is dedicated to photochemical reactions of a variety of compound classes, including alkenes, dienes, and polyenes, carbonyl compounds, and aromatic compounds. Additionally, photofragmentation reactions are described in a dedicated chapter. The last chapter gives an outlook on applications of photochemistry and natural photochemical phenomena. Both parts start with a comprehensive presentation of the general principles of the pericyclic and photochemical reactions. All chapters are rich in examples, which help illustrate the explained principles and establish ties to results and trends in recent research. Additionally, each chapter offers exercises for students, and solutions to the problems are provided in a separate appendix. This book nicely illustrates the utility of pericyclic and photochemical reactions and provides students and researchers with the tools to apply them routinely for an efficient synthesis of complex organic molecules. It will therefore appeal to advanced undergraduate students, graduate and postgraduate students, and even to practitioners and scientists in the field of organic synthesis. The rich examples and exercises will also make it a versatile tool for teachers and lecturers.
Mechanochemical Organic Synthesis
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Author : Davor Margetic
language : en
Publisher: Elsevier
Release Date : 2016-04-23
Mechanochemical Organic Synthesis written by Davor Margetic and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-04-23 with Science categories.
Mechanochemical Organic Synthesis is a comprehensive reference that not only synthesizes the current literature but also offers practical protocols that industrial and academic scientists can immediately put to use in their daily work. Increasing interest in green chemistry has led to the development of numerous environmentally-friendly methodologies for the synthesis of organic molecules of interest. Amongst the green methodologies drawing attention, mechanochemistry is emerging as a promising method to circumvent the use of toxic solvents and reagents as well as to increase energy efficiency. The development of synthetic strategies that require less, or the minimal, amount of energy to carry out a specific reaction with optimum productivity is of vital importance for large-scale industrial production. Experimental procedures at room temperature are the mildest reaction conditions (essentially required for many temperature-sensitive organic substrates as a key step in multi-step sequence reactions) and are the core of mechanochemical organic synthesis. This green synthetic method is now emerging in a very progressive manner and until now, there is no book that reviews the recent developments in this area. - Features cutting-edge research in the field of mechanochemical organic synthesis for more sustainable reactions - Integrates advances in green chemistry research into industrial applications and process development - Focuses on designing techniques in organic synthesis directed toward mild reaction conditions - Includes global coverage of mechanochemical synthetic protocols for the generation of organic compounds
The Diels Alder Reaction
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Author : Francesco Fringuelli
language : en
Publisher: John Wiley & Sons
Release Date : 2002-01-21
The Diels Alder Reaction written by Francesco Fringuelli and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002-01-21 with Science categories.
This is the first book to collect together 70 years worth of experimental procedures that have been developed to perfom the Diels-Alder reaction. It begins with the fundamental principles and contains numerous graphical abstracts to present the basic concepts in a concise and pictorial way. Covering the theory and synthetic applications of the experimental methods it describes the procedures and techniques and includes reports on industrial applications. * Illustrates the fundamental principles and summarises experimental methods used to carry out the Diels-Alder reaction * Contains physical and catalytic methods to enhance the selectivity of the Diels-Alder reaction * Includes procedures for cycloaddition accomplished in conventional and unconventional media * Outlines the practical procedures * Focuses on clean syntheses and green chemistry * Provides a single source for relevant information and includes over 1,000 references The Diels-Alder reaction mechanism was first published in 1928 and in the last 70 years has become the most commonly used and studied mechanism in organic chemistry.