Direct Synthesis Of Metal Complexes
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Direct Synthesis Of Metal Complexes
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Author : B.I. Kharisov
language : en
Publisher: Elsevier
Release Date : 2018-04-19
Direct Synthesis Of Metal Complexes written by B.I. Kharisov and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-04-19 with Science categories.
Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn't require organic solvents), with special attention paid to 'greener' methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. - Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more - Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water - Includes experimental procedures, with examples of direct synthesis, at the end of each chapter
Direct Synthesis Of Coordination And Organometallic Compounds
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Author : A.D. Garnovskii
language : en
Publisher: Elsevier
Release Date : 1999-08-13
Direct Synthesis Of Coordination And Organometallic Compounds written by A.D. Garnovskii and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999-08-13 with Science categories.
This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail.Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result of ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In these methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under the conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed. These methods have become the basis of a new field in synthetic chemistry - the direct synthesis of coordination and organometallic compounds from zero-valent metals.Particular aspects of the above problem have been described in a series of reviews and monographs. However, on the whole these main parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions.Some methods of direct synthesis have been developed in the former USSR (in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis) but, in spite of their novelty and/or wide applicability, they are practically unknown elsewhere due to the language barrier. Thus, another objective of this book is to acquaint the readers with the mentioned achievements.Every chapter contains the tables which describe all the reported data on direct reaction between metal atoms, metal particles or bulk metals with (in)organic ligans. There are some illustrations also (for example, the scheme of the reactor for gas-phase reaction between metal small particles and &bgr;-diketones).
Synthesis Of Organometallic Compounds
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Author : Sanshiro Komiya
language : en
Publisher: John Wiley & Sons
Release Date : 1997-05-28
Synthesis Of Organometallic Compounds written by Sanshiro Komiya and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 1997-05-28 with Science categories.
Inorganic Chemistry: Inorganic Chemistry: A Textbook Series This series reflects the breadth of modern research in inorganic chemistry and fulfils the need for advanced texts. The series covers the whole range of inorganic and physical chemistry, solid state chemistry, coordination chemistry, main group chemistry and bioinorganic chemistry. Synthesis of Organometallic Compounds A Practical Guide Edited by Sanshiro Komiya Tokyo University of Agriculture and Technology, Japan. This book describes the concepts of organometallic chemistry and provides an overview of the chemistry of each metal including the synthesis and handling of its important organometallic compounds. Synthesis of Organometallic Compounds: A Practical Guide provides: an excellent introduction to organometallic synthesis detailed synthetic protocols for the most important organometallic syntheses an overview of the reactivity, applications and versatility of organometallic compounds a survey of metals and their organometallic derivatives The purpose of this book is to serve as a practical guide to understanding the general concepts of organometallics for graduate students and scientists who are not necessarily specialists in organometallic chemistry.
Metal Complexes Environmental And Biomedical Applications
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Author : Rojalin Sahu
language : en
Publisher: Bentham Science Publishers
Release Date : 2024-11-20
Metal Complexes Environmental And Biomedical Applications written by Rojalin Sahu and has been published by Bentham Science Publishers this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-11-20 with Science categories.
Metal Complexes: Environmental and Biomedical Applications offers a comprehensive exploration of the role of metal complexes in diverse fields, including biomedicine, energy, and environmental protection. This book provides insights into the synthesis, properties, and applications of metal complexes, covering topics such as their use in therapeutics, diagnostics, energy materials, and catalysis. It also examines their antibacterial, antifungal, and sensor applications. With a systematic approach, the book is ideal for students, researchers, and professionals interested in the growing relevance of metal complexes in scientific and industrial applications. Key Features: - Overview of metal complexes and oxidation states. - Synthesis of metal complexes from N-heterocyclic carbene and Schiff base ligands. - Biomedical applications, including therapeutics and diagnostics. - Use of metal complexes in energy storage and catalysis. - Applications in antibacterial and antifungal treatments. - Metal complexes as sensors and in analytical chemistry.
Synthetic Coordination And Organometallic Chemistry
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Author : Alexander D. Garnovskii
language : en
Publisher: CRC Press
Release Date : 2003-04-25
Synthetic Coordination And Organometallic Chemistry written by Alexander D. Garnovskii and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-04-25 with Science categories.
This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.
N Heterocyclic Carbenes
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Author : Steven P. Nolan
language : en
Publisher: Wiley-VCH
Release Date : 2014-11-03
N Heterocyclic Carbenes written by Steven P. Nolan and has been published by Wiley-VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-11-03 with Science categories.
This comprehensive reference and handbook covers in depth all major aspects of the use of N-heterocyclic carbene-complexes in organic synthesis: from the theoretical background to characterization, and from cross-coupling reactions to olefin metathesis. Edited by a leader and experienced scientist in the field of homogeneous catalysis and use of NHCs, this is an essential tool for every academic and industrial synthetic chemist.
Frustrated Lewis Pairs I
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Author : Gerhard Erker
language : en
Publisher: Springer
Release Date : 2014-07-08
Frustrated Lewis Pairs I written by Gerhard Erker and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-07-08 with Science categories.
Discovery of Frustrated Lewis Pairs: Intermolecular FLPs for Activation of Small Molecules, by Douglas W. Stephan Intramolecular Frustrated Lewis Pairs: Formation and Chemical Features, by Gerald Kehr, Sina Schwendemann, Gerhard Erker Frustrated Lewis Pair Mediated Hydrogenations, by Douglas W. Stephan, Gerhard Erker Amine-Borane Mediated Metal-Free Hydrogen Activation and Catalytic Hydrogenation, by Victor Sumerin, Konstantin Chernichenko, Felix Schulz, Markku Leskelä, Bernhard Rieger, Timo Repo Hydrogen Activation by Frustrated Lewis Pairs: Insights from Computational Studies, by Tibor András Rokob, Imre Pápai Quantum Chemistry of FLPs and Their Activation of Small Molecules: Methodological Aspects, by Birgitta Schirmer, Stefan Grimme Computational Design of Metal-Free Molecules for Activation of Small Molecules, Hydrogenation, and Hydroamination, by Zhi-Xiang Wang, Lili Zhao, Gang Lu, Haixia Li, Fang Huang Computational Studies of Lewis Acidity and Basicity in Frustrated Lewis Pairs, by Thomas M. Gilbert Solid-State NMR as a Spectroscopic Tool for Characterizing Phosphane - Borane Frustrated Lewis Pairs, by Thomas Wiegand, Hellmut Eckert, Stefan Grimme
Inorganic And Organometallic Transition Metal Complexes With Biological Molecules And Living Cells
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Author : Kenneth Kam-Wing Lo
language : en
Publisher: Academic Press
Release Date : 2016-12-30
Inorganic And Organometallic Transition Metal Complexes With Biological Molecules And Living Cells written by Kenneth Kam-Wing Lo and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-12-30 with Science categories.
Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells provides a complete overview of this important research area that is perfect for both newcomers and expert researchers in the field. Through concise chapters written and edited by esteemed experts, this book brings together a comprehensive treatment of the area previously only available through scattered, lengthy review articles in the literature. Advanced topics of research are covered, with particular focus on recent advances in the biological applications of transition metal complexes, including inorganic medicine, enzyme inhibitors, antiparasital agents, and biological imaging reagents. - Geared toward researchers and students who seek an introductory overview of the field, as well as researchers working in advanced areas - Focuses on the interactions of inorganic and organometallic transition metal complexes with biological molecules and live cells - Foscuses on the fundamentals and their potential therapeutic and diagnostic applications - Covers recent biological applications of transition metal complexes, such as anticancer drugs, enzyme inhibitors, bioconjugation agents, chemical biology tools, and bioimaging reagents
Inorganic Chemistry
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Author : Egon Wiberg
language : en
Publisher: Academic Press
Release Date : 2001
Inorganic Chemistry written by Egon Wiberg and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001 with Chemistry, Inorganic categories.
Reaction Mechanisms Of Metal Complexes
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Author : R W Hay
language : en
Publisher: Elsevier
Release Date : 2000-03-01
Reaction Mechanisms Of Metal Complexes written by R W Hay and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-03-01 with Technology & Engineering categories.
This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. - Provides a general background as a course module in the area of inorganic reaction mechanisms, which has important research applications in the metallurgical industry - Contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands