Direct Synthesis Of Metal Complexes

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Direct Synthesis Of Metal Complexes

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Author : B.I. Kharisov
language : en
Publisher: Elsevier
Release Date : 2018-04-19

Direct Synthesis Of Metal Complexes written by B.I. Kharisov and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-04-19 with Science categories.

Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter

Direct Synthesis Of Coordination And Organometallic Compounds

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Author : A.D. Garnovskii
language : en
Publisher: Elsevier
Release Date : 1999-08-13

Direct Synthesis Of Coordination And Organometallic Compounds written by A.D. Garnovskii and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999-08-13 with Science categories.

This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result of ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In these methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under the conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed. These methods have become the basis of a new field in synthetic chemistry - the direct synthesis of coordination and organometallic compounds from zero-valent metals. Particular aspects of the above problem have been described in a series of reviews and monographs. However, on the whole these main parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions. Some methods of direct synthesis have been developed in the former USSR (in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis) but, in spite of their novelty and/or wide applicability, they are practically unknown elsewhere due to the language barrier. Thus, another objective of this book is to acquaint the readers with the mentioned achievements. Every chapter contains the tables which describe all the reported data on direct reaction between metal atoms, metal particles or bulk metals with (in)organic ligans. There are some illustrations also (for example, the scheme of the reactor for gas-phase reaction between metal small particles and &bgr;-diketones).

Carbonylation

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Author : H.M. Colquhoun
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-06-29

Carbonylation written by H.M. Colquhoun and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-06-29 with Science categories.

Since the publication of our earlier book on transition metal mediated organic synthesis, * there has been a widespread increase of interest in this topic, and transition metal based methodology has become firmly established in many areas of organic chemistry. The direct, catalytic formation of organic carbonyl compounds using carbon monoxide as the source of the carbonyl group has seen exceptional progress, and this carbonylation chemistry is being used increasingly in research and on a larger scale for fine chemicals production. In view of these developments, there is a need for a modem, practi cally oriented book dealing with transition metal based carbonylation chemistry. The present monograph should help fulfill this need, since it is intended specifically to foster the adoption of catalytic carbonylation as a general tool in synthetic organic chemistry. It deals exclusively with reactions involving the interconversion of carbon monoxide and organic carbonyl compounds, and although the majority of the reactions discussed involve catalytic formation of carbonyl compounds, potentially valuable syntheses requiring stoichiometric quantities of transition metal are also included. In addition, a chapter is devoted to the remarkably useful reverse transformation (decarbonylation), in which an organic carbonyl group is eliminated in the form of carbon monoxide.

The Direct Synthesis Of Optically Active Complexes Of The Alkaline Earth Metals

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Author : Billy Thomas Upchurch
language : en
Publisher:
Release Date : 1967

The Direct Synthesis Of Optically Active Complexes Of The Alkaline Earth Metals written by Billy Thomas Upchurch and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1967 with categories.

Transition Metal Organometallics In Organic Synthesis

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Author : Howard Alper
language : en
Publisher: Elsevier
Release Date : 2012-12-02

Transition Metal Organometallics In Organic Synthesis written by Howard Alper and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.

Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis. The book is recommended as a reference for chemists and inorganic chemists who would like to learn the applications of organometallic complexes as reagents and catalysts.

Synthetic Coordination And Organometallic Chemistry

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Author : Alexandr D. Garnovskii
language : en
Publisher: CRC Press
Release Date : 2003-04-25

Synthetic Coordination And Organometallic Chemistry written by Alexandr D. Garnovskii and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-04-25 with Science categories.

This reference offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system.

Schiff Base Metal Complexes

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Author : Pranjit Barman
language : en
Publisher: John Wiley & Sons
Release Date : 2023-05-11

Schiff Base Metal Complexes written by Pranjit Barman and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-05-11 with Science categories.

Schiff Base Metal Complexes Schiff bases are compounds created from a condensed amino compounds, which frequently form complexes with metal ions. They have diverse applications in biology, catalysis, material science and industry. Understanding these compounds, their properties, and the available methods for synthesizing them is a key to unlocking industrial innovation. Schiff Base Metal Complexes provides a comprehensive overview of these compounds. It introduces the compounds and their properties before discussing their various synthesizing methods. A survey of existing and potential applications gives a complete picture and makes this a crucial guide for researchers and industry professionals looking to work with Schiff base complexes. Schiff Base Metal Complexes readers will also find: A systematic and organized structure designed to make information instantly accessible Detailed coverage of thermal synthesis, photochemical synthesis, and more Challenges with different methods described in order to help readers make the correct choice for their own work Schiff Base Metal Complexes is a useful reference for organic chemists, materials scientists, and researchers or industry professionals working with organometallics.

Development Of A Room Temperature Molecular Electronics

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Author : Laura Mary Cleary
language : en
Publisher:
Release Date : 2011

Development Of A Room Temperature Molecular Electronics written by Laura Mary Cleary and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011 with categories.

Synthetic Coordination And Organometallic Chemistry

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Author : Alexander D. Garnovskii
language : en
Publisher: CRC Press
Release Date : 2003-04-25

Synthetic Coordination And Organometallic Chemistry written by Alexander D. Garnovskii and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-04-25 with Science categories.

This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.

Molecular Electrochemistry Of Inorganic Bioinorganic And Organometallic Compounds

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Author : A.J.L. Pombeiro
language : en
Publisher: Springer Science & Business Media
Release Date : 1993

Molecular Electrochemistry Of Inorganic Bioinorganic And Organometallic Compounds written by A.J.L. Pombeiro and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 1993 with Science categories.

Proceedings of the NATO Advanced Research Workshop, Sintra, Portugal, March 25-29, 1992