Electron Paramagnetic Resonance Of D Transition Metal Compounds
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Electron Paramagnetic Resonance Of D Transition Metal Compounds
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Author : F.E. Mabbs
language : en
Publisher: Elsevier
Release Date : 2013-10-22
Electron Paramagnetic Resonance Of D Transition Metal Compounds written by F.E. Mabbs and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Science categories.
Electron paramagnetic resonance (epr) spectroscopy is a sensitive and versatile method of studying paramagnets, which is finding increasing use in chemistry, biochemistry, earth and materials sciences. The technique is treated both qualitatively and quantitatively, with a progressive increase in sophistication in each succeeding chapter. Following a general introductory chapter, the first half of the book deals with single unpaired electron systems and considers both metal and ligand Zeeman, hyperfine and quadrupole interactions. The simulation of these spectra is discussed, followed by the relationship between spin-Hamiltonian parameters and models of the electronic structures of paramagnets. The second half of the book treats multiple unpaired electron systems using the same philosophy. An introduction to the epr properties of cluster compounds and of extended exchanging systems is also given. There is a chapter on linewidths and lineshapes, and an extensive appendix containing much additional information. A wide-ranging library of simulated and experimental spectra is given, as well as graphical data which should aid spectrum interpretation. Each chapter contains key references and there is a substantial subject and keyword index. This book is designed to teach epr spectroscopy to students without any previous knowledge of the technique. However, it will also be extremely useful to researchers dealing with paramagnetic d transition metals.
Electron Paramagnetic Resonance
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Author : Bruce C Gilbert
language : en
Publisher: Royal Society of Chemistry
Release Date : 2007-10-31
Electron Paramagnetic Resonance written by Bruce C Gilbert and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-10-31 with Science categories.
Electron Paramagnetic Resonance (EPR) Volume 18 highlights major developments in this area reported in 2001 and 2002, with results being set into the context of earlier work and presented as a set of critical yet coherent overviews. The topics covered describe contrasting types of application ranging from biological areas such as EPR studies of free-radical reactions in biology and medically-related systems to experimental developments and applications involving EPR imaging the use of very high fields and time-resolved methods. Critical and up-to-the-minute reviews of advances involving the design of spin-traps advances in spin-labelling paramagnetic centres on solid surfaces exchange-coupled oligomers metalloproteins and radicals in flavoenzymes are also included. As EPR continues to find new applications in virtually all areas of modern science including physics chemistry biology and materials science this series caters not only for experts in the field but also those wishing to gain a general overview of EPR applications in a given area.
Metal Oxide Catalysis 2 Volume Set
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Author : S. David Jackson
language : en
Publisher: John Wiley & Sons
Release Date : 2008-11-24
Metal Oxide Catalysis 2 Volume Set written by S. David Jackson and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-11-24 with Science categories.
With its two-volume structure, this handbook and ready reference allows for comprehensive coverage of both characterization and applications, while uniform editing throughout ensures that the structure remains consistent. The result is an up-to-date review of metal oxides in catalysis. The first volume covers a range of techniques that are used to characterize oxides, with each chapter written by an expert in the field. Volume 2 goes on to cover the use of metal oxides in catalytic reactions. For all chemists and engineers working in the field of heterogeneous catalysis.
Electronic Energy Levels Of Transition Metal Complexes
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Author : Roman Boča
language : en
Publisher: Elsevier
Release Date : 2024-11-15
Electronic Energy Levels Of Transition Metal Complexes written by Roman Boča and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-11-15 with Science categories.
Electronic Energy Levels of Transition Metal Complexes guides the reader to understand how to comprehensively calculate (predict, reconstruct) electronic energy levels of separation between 0,1 to 30,000 cm-1 in d1 to d9 transition metal complexes. The applied apparatus helps to understand the individual effect of the interelectron repulsion, crystal field strength, spin-orbit coupling and the magnetic field for any symmetry. Symmetry labels can be attached to energy levels (eigenvalues) by analyzing the eigenvectors of the model Hamiltonian either at the level of crystal-field terms or crystal-field multiplets.This book includes basic formulae for matrix elements of the model Hamiltonian and a huge number of results presented as graphs identifying the order of the energy levels and their labelling using the group (double group) irreducible representations. Utilization of the generated energy levels in electron spectroscopy, electron spin resonance and magnetochemistry is presented. Massive modelling was done using the desktop computers. - Covers advanced methodology for general cases, electronic terms and spin-orbit multiplets in the crystal field of any symmetry, and extensive modelling - Analyzes extensive modeling of energy levels and magnetic functions fo complexes of lower symmetry - Presents energy level diagrams and magnetic functions are presented for the most important cases, such as the octahedron, elongated tetragonal pyramid, compressed tetragonal pyramid, tetrahedron, prolate bisphenoid, flattened bisphenoid, trigonal bipyramid, tetragonal bipyramid, and o-rhombic bypyramid for d1 to d9 systems
Electron Spin Resonance
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Author : Bruce C. Gilbert
language : en
Publisher: Royal Society of Chemistry
Release Date : 1994
Electron Spin Resonance written by Bruce C. Gilbert and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994 with Medical categories.
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Electron Paramagnetic Resonance
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Author : Marina Brustolon
language : en
Publisher: John Wiley & Sons
Release Date : 2009-02-25
Electron Paramagnetic Resonance written by Marina Brustolon and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-02-25 with Science categories.
This book offers a pragmatic guide to navigating through the complex maze of EPR/ESR spectroscopy fundamentals, techniques, and applications. Written for the scientist who is new to EPR spectroscopy, the editors have prepared a volume that de-mystifies the basic fundamentals without weighting readers down with detailed physics and mathematics, and then presents clear approaches in specific application areas. The first part presents basic fundamentals and advantages of electron paramagnetic resonance spectrscopy. The second part explores severalapplication areas including chemistry, biology, medicine, materials and geology. A frequently-asked-questions sections focuses on practicalquestions, such as the size of sample, etc. It's an ideal, hands-on reference for chemists and researchers in the pharmaceutical and materials (semiconductor) industries who are looking for a basic introduction to EPR spectroscopy.
Multifrequency Electron Paramagnetic Resonance
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Author : Sushil K. Misra
language : en
Publisher: John Wiley & Sons
Release Date : 2014-03-19
Multifrequency Electron Paramagnetic Resonance written by Sushil K. Misra and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-03-19 with Science categories.
This handbook is aimed to deliver an up-to-date account of some of the recently developed experimental and theoretical methods in EPR, as well as a complete up-to-date listing of the experimentally determined values of multifrequency transition-ion spin Hamiltonian parameters by Sushil Misra, reported in the past 20 years, extending such a listing published by him in the Handbook on Electron Spin Resonance, volume 2. This extensive data tabulation makes up roughly 60% of the book`s content. It is complemented by the first full compilation of hyperfine splittings and g-factors for aminoxyl (nitroxide) radicals since 197 by Larry Berliner, a world expert on spin labeling, helping to identify and interpret substances and processes by means of EPR techniques. The book also includes coverage of the recently developed experimental technique of rapid-scan EPR by Sandra Eaton and Gareth Eaton, and a thorough review of computational modeling in EPR by Stefan Stoll, author of Easy Spin.
Electron Spin Resonance
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Author : Philip Henri Rieger
language : en
Publisher: Royal Society of Chemistry
Release Date : 2007
Electron Spin Resonance written by Philip Henri Rieger and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007 with Medical categories.
This book describes in mathematical terms the extraction of useful information from ESR spectra as applied to paramagnetic organic, inorganic and organometalic molecules. It lays a firm groundwork for understanding more sophisticated experiments, which the availability of newer commercial instruments has made possible. It takes the reader step by step through obtaining and interpretating ESR spectra of paramagnetic molecules. The mathematical basis of each observed phenomena are detailed and examples given. In particular there is a detailed discussion of 2nd order pertubation theory treatment of the Spin Hamiltonian for non-coincident G and A axes.
Principles Of Pulse Electron Paramagnetic Resonance
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Author : Arthur Schweiger
language : en
Publisher:
Release Date : 2001
Principles Of Pulse Electron Paramagnetic Resonance written by Arthur Schweiger and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001 with Medical categories.
This book explains the foundations of pulse EPR, a field of spectroscopy which has now come of age and has found widespread application in investigations of structure, dynamics, and function of biological systems and synthetic materials. For the first time a systematic overview of the whole field is given, including coverage of Fourier-transform EPR, relaxation measurements, electron spin echo envelope modulation (ESEEM), pulse electron- nuclear double resonance (ENDOR), pulse electron-electron double resonance (ELDOR), transient nutation, and a number of advanced techniques. Researchers approaching the field will find here the basic theory as well as a description and critical evaluation of the existing methods needed for selecting the proper experiment, conducting it, and analysing the results. The experienced researcher active in the field should find this book a useful reference and a guide to adapting EPR pulse sequences to new problems.
Epr In The 21st Century
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Author : Asako Kawamori
language : en
Publisher: Elsevier
Release Date : 2002-07-01
Epr In The 21st Century written by Asako Kawamori and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2002-07-01 with Science categories.
The Proceedings in this volume are a refereed selection of presentations from The Third Asia-Pacific EPR/ESR Symposium (APES'01), held in Kobe, Japan from October 29 to November 1, 2001. Participants from 20 countries from Asia, Australia, Europe, North and South America presented 210 papers, of which 132 are included here.These Proceedings are also a blueprint for development of electron paramagnetic resonance (EPR) / electron spin resonance (ESR) in the Asia-Pacific region in the 21st century. The Symposium reflected a variety of research fields developed over half a century and focuses especially on the most recent developments, such as high-field and high-frequency EPR, which are envisaged to be further developed and applied to various fields in the 21st century.All sessions consisted of Plenary, Invited and Contributed presentations. The Plenary presentations aimed at summarizing the overall developments. Invited presentations, reviewing the most recent developments, and Contributed ones, dealing with original research recently carried out in the EPR/ESR area, were given in one of three parallel sessions. The unique research works presented cover various fields and reflect the existing diversity of applications of the EPR/ESR techniques.