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Encyclopedia Of Radicals In Chemistry Biology And Materials

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Encyclopedia Of Radicals In Chemistry Biology And Materials Polymers And Materials

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Author :
language : en
Publisher:
Release Date : 2012

Encyclopedia Of Radicals In Chemistry Biology And Materials Polymers And Materials written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012 with SCIENCE categories.

"In recent years, free radicals have played an important role in various disciplines, ranging from organic synthesis to biology and medicine, polymer chemistry and materials science. The aim of this handbook is to offer for the first time a description of free radicals within an interdisciplinary and multidisciplinary context, connecting structural characteristics and chemical properties to their applications in different areas of chemistry and related disciplines. The Handbook covers not only basic concepts and chemical synthesis, but also touches on various aspects concerning the role of free radicals in materials and life sciences. The reader will find a balanced contribution of topics related to free radicals covering for example, their role in proteomics, genomics and lipidomics as well as their enormous potential in synthesis and technology. The Handbook will be interesting for anybody working in the field of free radicals in the broadest sense. It will address scientists who want to enter the interdisciplinary field of free radicals. In particular, it is aimed primarily at chemists and life science researchers who want to gain a wider and deeper understanding of free radicals which will allow them to apply free radicals in their own scientific field. The book consists of four themed volumes: Basic Concepts & Methodologies, Synthetic Strategies & Applications, Chemical Biology, Polymers & Materials. Within the volumes the chapters will also be thematically structured"--

Encyclopedia Of Radicals In Chemistry Biology And Materials

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Author :
language : en
Publisher:
Release Date : 2012

Encyclopedia Of Radicals In Chemistry Biology And Materials written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012 with SCIENCE categories.

Radical Reactions

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Author : Nathan Price
language : en
Publisher: American Chemical Society
Release Date : 2023-03-31

Radical Reactions written by Nathan Price and has been published by American Chemical Society this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-03-31 with Science categories.

Radical Reactions provides the reader a brief overview of radical reactions, an overview overlooked in most undergraduate chemistry curriculums. Most of the exciting developments in the field of radical and radical ion chemistry came about because someone understood the fundamentals and was able to design new chemistry based upon that understanding. The target audience is individuals who have had at least one semester of organic chemistry.

Stable Radicals

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Author : Robin Hicks
language : en
Publisher: John Wiley & Sons
Release Date : 2011-08-02

Stable Radicals written by Robin Hicks and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-08-02 with Science categories.

Stable radicals - molecules with odd electrons which are sufficiently long lived to be studied or isolated using conventional techniques - have enjoyed a long history and are of current interest for a broad array of fundamental and applied reasons, for example to study and drive novel chemical reactions, in the development of rechargeable batteries or the study of free radical reactions in the body. In Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds a team of international experts provide a broad-based overview of stable radicals, from the fundamental aspects of specific classes of stable neutral radicals to their wide range of applications including synthesis, materials science and chemical biology. Topics covered include: triphenylmethyl and related radicals polychlorinated triphenylmethyl radicals: towards multifunctional molecular materials phenalenyls, cyclopentadienyls, and other carbon-centered radicals the nitrogen oxides: persistent radicals and van der Waals complex dimers nitroxide radicals: properties, synthesis and applications the only stable organic sigma radicals: di-tert-alkyliminoxyls. delocalized radicals containing the hydrazyl [R2N-NR] unit metal-coordinated phenoxyl radicals stable radicals containing the thiazyl unit: synthesis, chemical, and materials properties stable radicals of the heavy p-block elements application of stable radicals as mediators in living-radical polymerization nitroxide-catalyzed alcohol oxidations in organic synthesis metal-nitroxide complexes: synthesis and magneto-structural correlations rechargeable batteries using robust but redox-active organic radicals spin labeling: a modern perspective functional in vivo EPR spectroscopy and imaging using nitroxides and trityl radicals biologically relevant chemistry of nitroxides Stable Free Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds is an essential guide to this fascinating area of chemistry for researchers and students working in organic and physical chemistry and materials science.

Organosilicon Compounds

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Author : Vladimir Ya Lee
language : en
Publisher: Academic Press
Release Date : 2017-08-22

Organosilicon Compounds written by Vladimir Ya Lee and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-08-22 with Science categories.

Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry Covers important breakthroughs in the field, along with the historically significant achievements of the past Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology

Redox Polymers For Energy And Nanomedicine

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Author : Nerea Casado
language : en
Publisher: Royal Society of Chemistry
Release Date : 2020-10-20

Redox Polymers For Energy And Nanomedicine written by Nerea Casado and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-10-20 with Science categories.

Redox Polymers for Energy and Nanomedicine highlights trends in the chemistry, characterization and application of polymers with redox properties.

Organosilicon Compounds Two Volume Set

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Author : Vladimir Ya Lee
language : en
Publisher: Academic Press
Release Date : 2017-10-01

Organosilicon Compounds Two Volume Set written by Vladimir Ya Lee and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-10-01 with Science categories.

Organosilicon Compounds provides readers with the state-of-the-art status of organosilicon chemistry, including its theoretical, synthetic, physico-chemical and applied aspects. By including high quality content in a key strategic signing area, this work is a strong addition to chemistry offerings in organic, main group and organometallic research. Organosilicon chemistry deals with compounds containing carbon–silicon bonds, an essential part of organic and organometallic chemistry. This book presents the many milestone in the field that have been discovered during the last few years, also detailing its usage in commercial products, such as sealants, adhesives and coatings. Features valuable contributions from prominent experts who cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects Covers important breakthroughs in the field, along with historically significant achievements Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) working in organometallic, organosilicon, main group element, transition metal, industrial silicon chemistry, and more

Photoinitiators

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Author : Jean-Pierre Fouassier
language : en
Publisher: John Wiley & Sons
Release Date : 2021-06-08

Photoinitiators written by Jean-Pierre Fouassier and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-06-08 with Technology & Engineering categories.

Photoinitiators A comprehensive text that covers everything from the processes and mechanisms to the reactions and industrial applications of photoinitiators Photoinitiators offers a wide-ranging overview of existing photoinitiators and photoinitiating systems and their uses in ever-growing green technologies. The authors—noted experts on the topic—provide a concise review of the backgrounds in photopolymerization and photochemistry, explain the available structures, and examine the excited state properties, involved mechanisms, and structure, reactivity, and efficiency relationships. The text also contains information on the latest developments and trends in the design of novel tailor-made systems. The book explores the role of current systems in existing and emerging processes and applications. Comprehensive in scope, it covers polymerization of thick samples and in-shadow areas, polymerization under LEDs, NIR light induced thermal polymerization, photoinitiators for novel specific and improved properties, and much more. Written by an experienced and internationally renowned team of authors, this important book: Provides detailed information about excited state processes, mechanisms and design of efficient photoinitiator systems Discusses the performance of photoinitiators of polymerization by numerous examples of reactions and application Includes information on industrial applications Presents a review of current developments and challenges Offers an introduction to the background information necessary to understand thefield The role played by photoinitiators in a variety of different polymerization reactions Written for polymer chemists, photochemists, and materials scientists, Photoinitiators will also earn a place in the libraries of photochemists seeking an authoritative, one-stop guide to the processes, mechanisms, and industrial applications of photoinitiators.

Ti Iii Catalyzed Synthesis Of Exocyclic Allenes And Development Of New Titanocene Complexes

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Author : Carmen Hernández Cervantes
language : en
Publisher: Universidad Almería
Release Date : 2016-01-25

Ti Iii Catalyzed Synthesis Of Exocyclic Allenes And Development Of New Titanocene Complexes written by Carmen Hernández Cervantes and has been published by Universidad Almería this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-01-25 with categories.

This thesis deals with the Ti(III) catalyzed synthesis of exocyclic allenes and the development of new titanocene complexes. It is structured in six chapters: Chapter 1 is a general introduction about the generation and reactivity of [TiCp2Cl]. A review about the different [TiCp2Cl] catalyzed or promoted reactions reported to date, is included. Chapter 2 is divided in introduction and results and discussion. In the introduction, an overview about the promoted or catalyzed methodologies, already available for the synthesis of α-allenols, is included. Results and discussion section is sub-divided in other two parts. The first one describes the synthesis of carbocyclic or nitrogen heterocyclic precursors bearing a propargyl halide and a carbonyl group. Next, the [TiCp2Cl] catalyzed synthesis of exocyclic allenols is studied. Additionally, a mechanistic study through deuterium incorporation and reaction of secondary propargyl halide precursors is performed. In the second part, the preparation of oxygen precursors and its cyclization are studied. In chapter 3, there is an introduction about enantioselective syntheses using chiral titanocene catalysts. The results and discussion section deals with the enantioselective cyclization of some of the precursors previously prepared using precatalyst (R,R)-ethylenebis(4,5,6,7-tetrahydro-1-indenyl) titanium(IV), also known as Brintzinger complex. A formal synthesis of the alkaloid (})-stemoamide is carried out in chapter 4, being the key step for this synthesis the generation of an α-allenol derivative through a [TiCp2Cl] catalyzedcyclization. This chapter is also divided in an introduction, in which a review about the different methods of synthesis of stemoamide are included, and results and discussion. Chapter 5 compiles the project that I have developed during my research stay at University of Bonn, under the supervision of Prof. Gansauer. The target of this project was to develop an azide functionalized short linker titanocene derivative with the aim of linking it to a surface by click chemistry. The chapter is divided in introduction and results and discussion. In the introduction the different methodologies for the synthesis of titanocene derivatives are reviewed. This section also includes the background in which this project is based. Chapter 6 includes the experimental part. In this chapter all reactions performed during the development of this thesis, as well as the spectroscopic characterization of compounds, are compiled.

Encyclopedia Of Physical Organic Chemistry 6 Volume Set

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Author : Zerong Wang
language : en
Publisher: John Wiley & Sons
Release Date : 2017-04-17

Encyclopedia Of Physical Organic Chemistry 6 Volume Set written by Zerong Wang and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-04-17 with Science categories.

Winner of 2018 PROSE Award for MULTIVOLUME REFERENCE/SCIENCE This encyclopedia offers a comprehensive and easy reference to physical organic chemistry (POC) methodology and techniques. It puts POC, a classical and fundamental discipline of chemistry, into the context of modern and dynamic fields like biochemical processes, materials science, and molecular electronics. Covers basic terms and theories into organic reactions and mechanisms, molecular designs and syntheses, tools and experimental techniques, and applications and future directions Includes coverage of green chemistry and polymerization reactions Reviews different strategies for molecular design and synthesis of functional molecules Discusses computational methods, software packages, and more than 34 kinds of spectroscopies and techniques for studying structures and mechanisms Explores applications in areas from biology to materials science The Encyclopedia of Physical Organic Chemistry has won the 2018 PROSE Award for MULTIVOLUME REFERENCE/SCIENCE. The PROSE Awards recognize the best books, journals and digital content produced by professional and scholarly publishers. Submissions are reviewed by a panel of 18 judges that includes editors, academics, publishers and research librarians who evaluate each work for its contribution to professional and scholarly publishing. You can find out more at: proseawards.com Also available as an online edition for your library, for more details visit Wiley Online Library

Encyclopedia Of Radicals In Chemistry Biology And Materials

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