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Excited States In Organic Chemistry And Biochemistry


Excited States In Organic Chemistry And Biochemistry
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Excited States In Organic Chemistry And Biochemistry


Excited States In Organic Chemistry And Biochemistry
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Author : Bernard Pullman
language : en
Publisher: Springer Science & Business Media
Release Date : 1977-10-31

Excited States In Organic Chemistry And Biochemistry written by Bernard Pullman and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 1977-10-31 with Science categories.


Proceedings of the 10th Jerusalem Symposium on Quantum Chemistry and Biochemistry held in Jerusalem, Israel, March 28-31, 1977



Excited States In Organic Chemistry And Biochemistry


Excited States In Organic Chemistry And Biochemistry
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Author : B. Pullman
language : en
Publisher:
Release Date : 1977

Excited States In Organic Chemistry And Biochemistry written by B. Pullman and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1977 with categories.




Excited States In Organic Chemistry


Excited States In Organic Chemistry
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Author : J. A. Barltrop
language : en
Publisher: John Wiley & Sons
Release Date : 1975

Excited States In Organic Chemistry written by J. A. Barltrop and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 1975 with Chemistry, Organic categories.




Excited States In Organic Chemistry


Excited States In Organic Chemistry
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Author : John Alfred Barltrop
language : en
Publisher:
Release Date : 1992

Excited States In Organic Chemistry written by John Alfred Barltrop and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992 with Photochemistry categories.




Rearrangements In Ground And Excited States


Rearrangements In Ground And Excited States
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Author : Paul de Mayo
language : en
Publisher: Academic Press
Release Date : 2013-10-22

Rearrangements In Ground And Excited States written by Paul de Mayo and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Science categories.


Rearrangement in ground and excited states, Volume 1 covers essays on the rearrangements of carbocations; gas-phase ion rearrangements; and rearrangements of carbenes and nitrenes. The book also includes essays on the free-radical rearrangements; hypothetical biradical pathways in thermal unimolecular rearrangements; and rearrangements in carbanions. Chemists and people involved in the study of rearrangements will find the book invaluable.



Chemical And Biological Generation Of Excited States


Chemical And Biological Generation Of Excited States
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Author : Waldermar Adam
language : en
Publisher: Elsevier
Release Date : 2012-12-02

Chemical And Biological Generation Of Excited States written by Waldermar Adam and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.


Chemical and Biological Generation of Excited States discusses major aspects of chemical and biological generation of electronic excitation. This book is organized into 11 chapters that focus on both chemi- and bioenergized processes. This book first discusses some of the fundamental aspects of the description of excited state behavior in condensed media. It then examines the field of gas-phase dioxetane chemiluminescence both by itself and in relation to solution-phase studies. The presented analysis is based on statistical mechanics and supported by a very simple limiting case calculation. Chapter 4 describes the state-of-the-art of how excitation yields are determined experimentally in chemienergized processes. This is followed by a discussion on activation parameters and stability trends, focusing on solution-phase data. Chapters 6 and 7 examine solution-phase chemiluminescence resulting from high-energy electron-transfer reaction, often involving aromatic radical ions, and the mechanism of excitation step. The next chapters cover the generation of electronic excited states in bioluminescence and the evaluation of luminescent oxidation mechanisms using oxygen tracers. The chapters also explain the formation of electronically excited products in dark biological processes and the mechanism of chemiexcitation as it relates to redox metabolism. Specific examples of biological oxygenation reactions yielding luminescence are also presented. Furthermore, this book discusses the concept and applicability of chemiluminigenic probing for the quantification and differentiation of oxygenation activities in mammalian phagocytes. The concluding chapter is devoted to the possible formation of singlet oxygen in various systems and processes that mimic singlet oxygen reactions. The book intends to attract young scientists as well as established research workers to broaden the horizons of this rapidly growing and potentially very important field.



Hydrogen Bonding And Transfer In The Excited State


Hydrogen Bonding And Transfer In The Excited State
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Author : Ke-Li Han
language : en
Publisher: John Wiley & Sons
Release Date : 2011-03-16

Hydrogen Bonding And Transfer In The Excited State written by Ke-Li Han and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-03-16 with Science categories.


This book gives an extensive description of the state-of-the-art in research on excited-state hydrogen bonding and hydrogen transfer in recent years. Initial chapters present both the experimental and theoretical investigations on the excited-state hydrogen bonding structures and dynamics of many organic and biological chromophores. Following this, several chapters describe the influences of the excited-state hydrogen bonding on various photophysical processes and photochemical reactions, for example: hydrogen bonding effects on fluorescence emission behaviors and photoisomerization; the role of hydrogen bonding in photosynthetic water splitting; photoinduced electron transfer and solvation dynamics in room temperature ionic liquids; and hydrogen bonding barrier crossing dynamics at bio-mimicking surfaces. Finally, the book examines experimental and theoretical studies on the nature and control of excited-state hydrogen transfer in various systems. Hydrogen Bonding and Transfer in the Excited State is an essential overview of this increasingly important field of study, surveying the entire field over 2 volumes, 40 chapters and 1200 pages. It will find a place on the bookshelves of researchers in photochemistry, photobiology, photophysics, physical chemistry and chemical physics.



Molecular Distortions In Ionic And Excited States


Molecular Distortions In Ionic And Excited States
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Author : Peter V. Schastnev
language : en
Publisher: CRC Press
Release Date : 1995-08-25

Molecular Distortions In Ionic And Excited States written by Peter V. Schastnev and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1995-08-25 with Science categories.


This book discusses the achievements in the study on the structure of active species being formed at the change of molecule charge or electronic state. It gives a systematic outline of the problem of molecular structure distortions in radical ionic and excited states involving experimental and theoretical material. The text focuses on analyzing the physical reasons for structural distortion occurrences at a model level and also with results of detailed quantum-chemical calculations. The book presents numerous facts on the structural distortions in ions of various types of organic molecules. Data is presented for the first time on distortions in radical ions of polyfluoroaromatics and other conjugated molecules.



Excited States Of Proteins And Nucleic Acids


Excited States Of Proteins And Nucleic Acids
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Author : Robert Steiner
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Excited States Of Proteins And Nucleic Acids written by Robert Steiner and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


The choice of title for this collective volume reflects the desire of the editors and authors to make clear that, while the bulk of the material is concerned with luminescence, other aspects of the excited state have not been excluded. In the five years which have elapsed since the publication of the classical monograph of Konev, a wealth of new information has ap peared on the emission properties of proteins and nucleic acids. Indeed, since new publications in this area appear to be proliferating in a geometric ratio, this may be the last opportunity to provide a comprehensive summary of the field in a book which is not of prohibitive length. This is what we have attempted to do here. While the orientation of each chapter naturally reflects the interests and point of view of the author, there has been a general effort to present .a critical assessment of existing results and interpretations, rather than a compendium of data with minimal comment. Finally, it should be stressed that the rapid evolution of the subject at the time of writing makes it inevitable that the book will age to some degree over the next few years, although this will occur at differing rates for the various chapters. We can only hope that most of the material in this interim summing-up will prove resistant to the erosion of time and provide a solid foundation for further progress.



Excited States Of Biopolymers


Excited States Of Biopolymers
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Author : Robert Steiner
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Excited States Of Biopolymers written by Robert Steiner and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


During the past decade, fluorescence techniques have come to occupy a position of central importance in biochemistry. Such areas as laser techniques, radiation less energy transfer, and nanosecond fluorometry have evolved from esoteric research specialties into standard procedures that are applied routinely to bio chemical problems. Indeed, discussion of the above three areas occupies the greater part of this book. Its level and approach are appropriate for the bio logical or physical scientist who is interested in applying fluorescence techniques, but is not necessarily an expert in this area. The coverage of the literature has, in general, been selective rather than exhaustive. It is likely that what is summarized here will prove resistant to the erosion of time and provide a basis for the future evolution of this rapidly developing area of science. Robert F. Steiner Catonsville, Maryland vii Contents Chapter 1 Some Principles Governing the Luminescence of Organic Molecules R. M Hochstrasser 1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 2. Spontaneous Emission . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 2. 1. General Considerations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 2. 2. Luminescence from Nearby States . . . . . . . . . . . . . . . . . . . . . . . . . 4 2. 3. Multiple State Decay . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 3. Molecular Luminescence Characteristics . . . . . . . . . . . . . . . . . . . . . . . . . 5 3. 1. The Transition Dipole Moment . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 3. 2. Determination of Transition-Moment Directions from Fluorescence . . . 8 3. 3. Polarization of Fluorescence from Crystals. . . . . . . . . . . . . . . . . . . . 9 4. Principles of Luminescence Experiments Carried Out with Lasers. . . . . . . 12 4. 1. Nonlinear Processes and Optical Pumping . . . . . . . . . . . . . . . . . . . 12 5. Coherent Interactions of Molecules and Light . . . . . . . . . . . . . . . . . . . . 16 5. 1. The Distinctions between Fluorescence and Resonance Raman Effects 17 6. Ultrafast Fluorescence Decay . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .