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First Principles Predictions Of Thermodynamic Properties And Phase Equilibria For Pure And Mixture Fluids


First Principles Predictions Of Thermodynamic Properties And Phase Equilibria For Pure And Mixture Fluids
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First Principles Predictions Of Thermodynamic Properties And Phase Equilibria For Pure And Mixture Fluids


First Principles Predictions Of Thermodynamic Properties And Phase Equilibria For Pure And Mixture Fluids
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Author : 謝介銘
language : en
Publisher:
Release Date : 2010

First Principles Predictions Of Thermodynamic Properties And Phase Equilibria For Pure And Mixture Fluids written by 謝介銘 and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010 with categories.




Molecular Thermodynamics Of Fluid Phase Equilibria


Molecular Thermodynamics Of Fluid Phase Equilibria
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Author : John M. Prausnitz
language : en
Publisher: Pearson Education
Release Date : 1998-10-22

Molecular Thermodynamics Of Fluid Phase Equilibria written by John M. Prausnitz and has been published by Pearson Education this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998-10-22 with Science categories.


The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.



Thermophysical Properties Of Fluids


Thermophysical Properties Of Fluids
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Author : Marc J. Assael
language : en
Publisher: World Scientific
Release Date : 1996

Thermophysical Properties Of Fluids written by Marc J. Assael and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996 with Technology & Engineering categories.


This book is concerned with the prediction of thermodynamic and transport properties of gases and liquids. The prediction of such properties is essential for the solution of many problems encountered in chemical and process engineering as well as in other areas of science and technology. The book aims to present the best of those modern methods which are capable of practical application. It begins with basic scientific principles and formal results which are subsequently developed into practical methods of prediction. Numerous examples, supported by a suite of computer programmes, illustrate applications of the methods. The book is aimed primarily at the student market (for both undergraduate and taught postgraduate courses) but it will also be useful for those engaged in research and for chemical and process engineering professionals.



High Pressure Fluid Phase Equilibria


High Pressure Fluid Phase Equilibria
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Author : Ulrich K Deiters
language : en
Publisher: Elsevier
Release Date : 2023-12-01

High Pressure Fluid Phase Equilibria written by Ulrich K Deiters and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-12-01 with Science categories.


High pressures play a more and more important role in modern technology. Examples are the supercritical fluid extraction of medical drugs and dyes from biological material, the handling of compressed or liquefied gases (including natural gas or hydrogen), the operation of modern thermal power plants, or various technical processes for controlled particle formation. High-Pressure Fluid Phase Equilibria, Second Edition enables understanding of the complicated phase behaviour that fluid or fluid mixtures (liquids, gases, or supercritical phases) can exhibit at elevated pressures. The underlying thermodynamic equations are explained, and robust algorithms for the computation of such equilibria (including solid–fluid equilibria) are proposed. Since the publication of the first edition of this book there have been many new developments, for instance differential equation methods for the computation of phase equilibria, accurate numerical differentiation, high-precision equations of state (e.g., the GERG model). Moreover, more detail and explanation has been added on important topics that were only briefly examined in the original book to better assist the reader, such as expansion processes and chemical reactions). The book remains invaluable as a single resource for grasping the intricacies of fluid phase behaviour. It enables readers to write or improve their own computer programs for the calculation of phase equilibria. It will appeal to graduate students of chemical engineering and university research staff involved in chemical engineering of supercritical fluids or the physical chemistry of fluids; the book can also serve as the basis of lectures or advanced students’ seminars. Comprehensively presents the complex world of phase equilibria (binary and ternary) and the various methods for computing phase equilibria, whilst carefully considering the relevant pressure and temperature ranges Introduces phase diagram classes, how to recognize them, and how to identify their characteristic features Presents rational nomenclature of binary fluid phase diagrams Includes problems and solutions for self-testing, exercises, or seminars New to this Edition: Presentation of the phase equilibria models is extended and expanded There are now more descriptions on more equations of state, especially the PCSAFT EoS Features new chapter on nonisothermal applications and chemically reactive systems and extensive updates and additions to all existing chapters



Phase Equilibrium In Mixtures


Phase Equilibrium In Mixtures
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Author : M. B. King
language : en
Publisher: Elsevier
Release Date : 2013-10-22

Phase Equilibrium In Mixtures written by M. B. King and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Technology & Engineering categories.


Phase Equilibrium in Mixtures deals with phase equilibrium and the methods of correlating, checking, and predicting phase data. Topics covered range from latent heat and vapor pressure to dilute solutions, ideal and near-ideal solutions, and consistency tests. Molecular considerations and their use for the prediction and correlation of data are also discussed. Comprised of nine chapters, this volume begins with an introduction to the role of thermodynamics and the criteria for equilibrium between phases, along with fugacity and the thermodynamic functions of mixing. The discussion then turns to some of the phase phenomena which may be encountered in chemical engineering practice; methods of correlating and extending vapor pressure data and practical techniques for calculating latent heats from these data; the behavior of dilute solutions both at low and high pressures for reacting and non-reacting systems; and the behavior of ideal and near-ideal solutions. The remaining chapters explore non-ideal solutions at normal pressures; practical methods for testing the thermodynamic consistency of phase data; and the extent to which the broad aspects of phase behavior may be interpreted in the light of simple molecular considerations. This book is intended primarily for graduate chemical engineers but should also be of interest to those graduates in physics or chemistry who need to use phase equilibrium data.



Molecular Thermodynamics Of Fluid Phase Equilibria


Molecular Thermodynamics Of Fluid Phase Equilibria
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Author : J. M. Prausnitz
language : en
Publisher: Prentice Hall
Release Date : 1969

Molecular Thermodynamics Of Fluid Phase Equilibria written by J. M. Prausnitz and has been published by Prentice Hall this book supported file pdf, txt, epub, kindle and other format this book has been release on 1969 with Science categories.


97774-4 The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics ofFluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and oth



Phase Equilibrium Engineering


Phase Equilibrium Engineering
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Author : Esteban Brignole
language : en
Publisher: Elsevier Inc. Chapters
Release Date : 2013-04-02

Phase Equilibrium Engineering written by Esteban Brignole and has been published by Elsevier Inc. Chapters this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-04-02 with Science categories.


In previous chapters, we have seen the fundamental criteria for phase equilibria and how the phenomenological phase behavior and separation technology of real mixtures are determined by their constituent molecular interactions. Our purpose in this chapter is to present the properties of fluids and the models for the prediction of thermodynamic properties and phase equilibria. These models are classified as predictive models using only pure component properties and semiempirical models based on a molecular thermodynamic approach. Finally, the chapter highlights the importance of the class of mixture and molecular interactions of its components in the selection of thermodynamic models for phase equilibrium calculations.



Applied Thermodynamics Of Fluids


Applied Thermodynamics Of Fluids
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Author : A. R. H. Goodwin
language : en
Publisher: Royal Society of Chemistry
Release Date : 2010

Applied Thermodynamics Of Fluids written by A. R. H. Goodwin and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2010 with Science categories.


Published under the asspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the need of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydroncarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commericial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.



Equations Of State For Fluids And Fluid Mixtures


Equations Of State For Fluids And Fluid Mixtures
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Author : J.V. Sengers
language : en
Publisher: Elsevier
Release Date : 2000-10-30

Equations Of State For Fluids And Fluid Mixtures written by J.V. Sengers and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-10-30 with Science categories.


This book has been prepared under the auspices of Commission I.2 on Thermodynamics of the International Union of Pure and Applied Chemistry (IUPAC). The authors of the 18 chapters are all recognized experts in the field. The book gives an up-to-date presentation of equations of state for fluids and fluid mixtures. All principal approaches for developing equations of state are covered. The theoretical basis and practical use of each type of equation is discussed and the strength and weaknesses of each is addressed. Topics addressed include the virial equation of state, cubic equations and generalized van der Waals equations, perturbation theory, integral equations, corresponding stated and mixing rules. Special attention is also devoted to associating fluids, polydisperse fluids, polymer systems, self-assembled systems, ionic fluids and fluids near critical points.



Thermodynamic Properties Of Nonelectrolyte Solutions


Thermodynamic Properties Of Nonelectrolyte Solutions
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Author : William Acree
language : en
Publisher: Academic Press
Release Date : 2012-12-02

Thermodynamic Properties Of Nonelectrolyte Solutions written by William Acree and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.


Thermodynamic Properties of Nonelectrolyte Solutions reviews several of the more classical theories on the thermodynamics of nonelectrolyte solutions. Basic thermodynamic principles are discussed, along with predictive methods and molecular thermodynamics. This book is comprised of 12 chapters; the first of which introduces the reader to mathematical relationships, such as concentration variables, homogeneous functions, Euler’s theorem, exact differentials, and method of least squares. The discussion then turns to partial molar quantities, ideal and nonideal solutions, and empirical expressions for predicting the thermodynamic properties of multicomponent mixtures from binary data. The chapters that follow explore binary and ternary mixtures containing only nonspecific interactions; the thermodynamic excess properties of liquid mixtures and ternary alcohol-hydrocarbon systems; and solubility behavior of nonelectrolytes. This book concludes with a chapter describing the use of gas-liquid chromatography in determining the activity coefficients of liquid mixtures and mixed virial coefficients of gaseous mixtures. This text is intended primarily for professional chemists and researchers, and is invaluable to students in chemistry or chemical engineering who have background in physical chemistry and classical thermodynamics.