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Thermodynamic Properties Of Nonelectrolyte Solutions


Thermodynamic Properties Of Nonelectrolyte Solutions
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Thermodynamic Properties Of Nonelectrolyte Solutions


Thermodynamic Properties Of Nonelectrolyte Solutions
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Author : William Acree
language : en
Publisher: Academic Press
Release Date : 2012-12-02

Thermodynamic Properties Of Nonelectrolyte Solutions written by William Acree and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.


Thermodynamic Properties of Nonelectrolyte Solutions reviews several of the more classical theories on the thermodynamics of nonelectrolyte solutions. Basic thermodynamic principles are discussed, along with predictive methods and molecular thermodynamics. This book is comprised of 12 chapters; the first of which introduces the reader to mathematical relationships, such as concentration variables, homogeneous functions, Euler's theorem, exact differentials, and method of least squares. The discussion then turns to partial molar quantities, ideal and nonideal solutions, and empirical expressions for predicting the thermodynamic properties of multicomponent mixtures from binary data. The chapters that follow explore binary and ternary mixtures containing only nonspecific interactions; the thermodynamic excess properties of liquid mixtures and ternary alcohol-hydrocarbon systems; and solubility behavior of nonelectrolytes. This book concludes with a chapter describing the use of gas-liquid chromatography in determining the activity coefficients of liquid mixtures and mixed virial coefficients of gaseous mixtures. This text is intended primarily for professional chemists and researchers, and is invaluable to students in chemistry or chemical engineering who have background in physical chemistry and classical thermodynamics.



Classical Thermodynamics Of Non Electrolyte Solutions


Classical Thermodynamics Of Non Electrolyte Solutions
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Author : H. C. Van Ness
language : en
Publisher: Elsevier
Release Date : 2013-10-22

Classical Thermodynamics Of Non Electrolyte Solutions written by H. C. Van Ness and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-22 with Science categories.


Classical Thermodynamics of Non-Electrolyte Solutions covers the historical development of classical thermodynamics that concerns the properties of vapor and liquid solutions of non-electrolytes. Classical thermodynamics is a network of equations, developed through the formal logic of mathematics from a very few fundamental postulates and leading to a great variety of useful deductions. This book is composed of seven chapters and begins with discussions on the fundamentals of thermodynamics and the thermodynamic properties of fluids. The succeeding chapter presents the equations of state for the calculation of the thermodynamic behavior of constant-composition fluids, both liquid and gaseous. These topics are followed by surveys of the mixing of pure materials to form a solution under conditions of constant temperature and pressure. The discussion then shifts to general equations for calculation of partial molal properties of homogeneous binary systems. The last chapter considers the approach to equilibrium of systems within which composition changes are brought about either by mass transfer between phases or by chemical reaction within a phase, or by both.



Thermodynamic Properties Of Nonelectrolyte Solutions


Thermodynamic Properties Of Nonelectrolyte Solutions
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Author : WE Acree (Jr)
language : en
Publisher:
Release Date : 1984

Thermodynamic Properties Of Nonelectrolyte Solutions written by WE Acree (Jr) and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1984 with categories.




Thermodynamics Of Solutions


Thermodynamics Of Solutions
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Author : Eli Ruckenstein
language : en
Publisher: Springer Science & Business Media
Release Date : 2009-06-17

Thermodynamics Of Solutions written by Eli Ruckenstein and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-06-17 with Science categories.


This book consists of a number of papers regarding the thermodynamics and structure of multicomponent systems that we have published during the last decade. Even though they involve different topics and different systems, they have something in common which can be considered as the “signature” of the present book. First, these papers are concerned with “difficult” or very nonideal systems, i. e. systems with very strong interactions (e. g. , hyd- gen bonding) between components or systems with large differences in the partial molar v- umes of the components (e. g. , the aqueous solutions of proteins), or systems that are far from “normal” conditions (e. g. , critical or near-critical mixtures). Second, the conventional th- modynamic methods are not sufficient for the accurate treatment of these mixtures. Last but not least, these systems are of interest for the pharmaceutical, biomedical, and related ind- tries. In order to meet the thermodynamic challenges involved in these complex mixtures, we employed a variety of traditional methods but also new methods, such as the fluctuation t- ory of Kirkwood and Buff and ab initio quantum mechanical techniques. The Kirkwood-Buff (KB) theory is a rigorous formalism which is free of any of the - proximations usually used in the thermodynamic treatment of multicomponent systems. This theory appears to be very fruitful when applied to the above mentioned “difficult” systems.



Chemical Thermodynamics Principles And Applications


Chemical Thermodynamics Principles And Applications
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Author : J. Bevan Ott
language : en
Publisher: Elsevier
Release Date : 2000-06-07

Chemical Thermodynamics Principles And Applications written by J. Bevan Ott and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-06-07 with Science categories.


Chemical Thermodynamics: Principles and Applications presents a thorough development of the principles of thermodynamics--an old science to which the authors include the most modern applications, along with those of importance in developing the science and those of historical interest. The text is written in an informal but rigorous style, including ancedotes about some of the great thermodynamicists (with some of whom the authors have had a personal relationship), and focuses on "real" systems in the discussion and figures, in contrast to the generic examples that are often used in other textbooks. The book provides a basic review of thermodynamic principles, equations, and applications of broad interest. It covers the development of thermodynamics as one of the pre-eminent examples of an exact science. A discussion of the standard state that emphasizes its significance and usefulness is also included, as well as a more rigorous and indepth treatment of thermodynamics and discussions of a wider variety of applications than are found in more broadly based physical chemistry undergraduate textbooks. Combined with its companion book, Chemical Thermodynamics: Advanced Applications, the practicing scientist will have a complete reference set detailing chemical thermodynamics. - Outlines the development of the principles of thermodynamics, including the most modern applications along with those of importance in developing the science and those of historical interest - Provides a basic review of thermodynamic principles, equations, and applications of broad interest - Treats thermodynamics as one of the preeminent examples of an exact science - Provides a more rigorous and indepth treatment of thermodynamics and discussion of a wider variety of applications than are found in more broadly based physical chemistry undergraduate textbooks - Includes examples in the text and exercises and problems at the end of each chapter to assist the student in learning the subject - Provides a complete set of references to all sources of data and to supplementary reading sources



Thermodynamic Data On Oxides And Silicates


Thermodynamic Data On Oxides And Silicates
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Author : Surendra K. Saxena
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06

Thermodynamic Data On Oxides And Silicates written by Surendra K. Saxena and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.


During the last thirty years profound developments in expe- rimental techniques to measure high temperature and pressu- res and thermodynamic properties of minerals have occurred. This technical development has been matched by an increased sophistication in applying theoretical methods to obtain new data or improve the quality of existing data. Using these newtechniques, Assessed Thermodynamic Data on Oxides and Silicates represents the successful attempt of the authors to develop an internally systematized data base which satis- fies the constraints of calorimetric measurements, phase equilibrium data, measured thermophysical properties of a phase, and heat capacities and entropies estimated from lat- tice vibrational models.



Thermodynamic Properties Of Aqueous Solutions Organic Substances


Thermodynamic Properties Of Aqueous Solutions Organic Substances
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Author : V. P. Belousov
language : en
Publisher: Springer
Release Date : 1994

Thermodynamic Properties Of Aqueous Solutions Organic Substances written by V. P. Belousov and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994 with Science categories.


Thermodynamic Properties of Aqueous Solutions of Organic Substances discusses the structure of aqueous solutions of organic substances and the intermolecular reactions in them, presenting experimental data, modern concepts concerning the properties of these solutions, and the results of computer simulation. The book offers an in-depth study of the properties of maximally dilute aqueous solutions of polar and nonpolar organic molecules as well as the specific enthalpies of mixing. The Addendum contains experimental data on the thermodynamic properties of infinitely dilute solutions.



Properties Of Aqueous Solutions Of Electrolytes


Properties Of Aqueous Solutions Of Electrolytes
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Author : Ivan D. Zaytsev
language : en
Publisher: CRC Press
Release Date : 1992-08-24

Properties Of Aqueous Solutions Of Electrolytes written by Ivan D. Zaytsev and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-08-24 with Science categories.


Properties of Aqueous Solutions of Electrolytes is a handbook that systematizes the information on physico-chemical parameters of multicomponent aqueous electrolyte solutions. This important data collection will be invaluable for developing new methods for more efficient chemical technologies, choosing optimal solutions for more effective methods of using raw materials and energy resources, and other such activities. This edition, the first available in English, has been substantially revised and augmented. Many new tables have been added because of a significantly larger list of electrolytes and their properties (electrical conductivity, boiling and freezing points, pressure of saturated vapors, activity and diffusion coefficients). The book is divided into two sections. The first section provides tables that list the properties of binary aqueous solutions of electrolytes, while the second section deals with the methods for calculating their properties in multicomponent systems. All values are given in PSI units or fractional and multiple units. Metrological characteristics of the experimental methods used for the determination of physico-chemical parameters are indicated as a relative error and those of the computational methods as a relative error or a root-mean square deviation.



Novel Approaches To The Structure And Dynamics Of Liquids Experiments Theories And Simulations


Novel Approaches To The Structure And Dynamics Of Liquids Experiments Theories And Simulations
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Author : Jannis Samios
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-11-11

Novel Approaches To The Structure And Dynamics Of Liquids Experiments Theories And Simulations written by Jannis Samios and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-11-11 with Science categories.


The unique behavior of the "liquid state", together with the richness of phenomena that are observed, render liquids particularly interesting for the scientific community. Note that the most important reactions in chemical and biological systems take place in solutions and liquid-like environments. Additionally, liquids are utilized for numerous industrial applications. It is for these reasons that the understanding of their properties at the molecular level is of foremost interest in many fields of science and engineering. What can be said with certainty is that both the experimental and theoretical studies of the liquid state have a long and rich history, so that one might suppose this to be essentially a solved problem. It should be emphasized, however, that although, for more than a century, the overall scientific effort has led to a considerable progress, our understanding of the properties of the liquid systems is still incomplete and there is still more to be explored. Basic reason for this is the "many body" character of the particle interactions in liquids and the lack of long-range order, which introduce in liquid state theory and existing simulation techniques a number of conceptual and technical problems that require specific approaches. Also, many of the elementary processes that take place in liquids, including molecular translational, rotational and vibrational motions (Trans. -Rot. -Vib. coupling), structural relaxation, energy dissipation and especially chemical changes in reactive systems occur at different and/or extremely short timescales.



Chemical Thermodynamics Advanced Applications


Chemical Thermodynamics Advanced Applications
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Author : J. Bevan Ott
language : en
Publisher: Elsevier
Release Date : 2000-06-16

Chemical Thermodynamics Advanced Applications written by J. Bevan Ott and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-06-16 with Science categories.


This book is an excellent companion to Chemical Thermodynamics: Principles and Applications. Together they make a complete reference set for the practicing scientist. This volume extends the range of topics and applications to ones that are not usually covered in a beginning thermodynamics text. In a sense, the book covers a "middle ground" between the basic principles developed in a beginning thermodynamics textbook, and the very specialized applications that are a part of an ongoing research project. As such, it could prove invaluable to the practicing scientist who needs to apply thermodynamic relationships to aid in the understanding of the chemical process under consideration. The writing style in this volume remains informal, but more technical than in Principles and Applications. It starts with Chapter 11, whichsummarizes the thermodynamic relationships developed in this earlier volume. For those who want or need more detail, references are given tothe sections in Principles and Applications where one could go to learn more about the development, limitations, and conditions where these equations apply. This is the only place where Advanced Applications ties back to the previous volume. Chapter 11 can serve as a review of the fundamental thermodynamic equations that are necessary for the more sophisticated applications described in the remainder of this book. This may be all that is necessary for the practicing scientist who has been away from the field for some time and needs some review. The remainder of this book applies thermodynamics to the description of a variety of problems. The topics covered are those that are probably of the most fundamental and broadest interest. Throughout the book, examples of "real" systems are used as much as possible. This is in contrast to many books where "generic" examples are used almost exclusively. A complete set of references to all sources of data and to supplementary reading sources is included. Problems are given at the end of each chapter. This makes the book ideally suited for use as a textbook in an advanced topics course in chemical thermodynamics. - An excellent review of thermodynamic principles and mathematical relationships along with references to the relevant sections in Principles and Applications where these equations are developed - Applications of thermodynamics in a wide variety of chemical processes, including phase equilibria, chemical equilibrium, properties of mixtures, and surface chemistry - Case-study approach to demonstrate the application of thermodynamics to biochemical, geochemical, and industrial processes - Applications at the "cutting edge" of thermodynamics - Examples and problems to assist in learning - Includes a complete set of references to all literature sources