Fluctuation Theory Of Solutions
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Fluctuation Theory Of Solutions
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Author : Paul E. Smith
language : en
Publisher: CRC Press
Release Date : 2016-04-19
Fluctuation Theory Of Solutions written by Paul E. Smith and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-04-19 with Medical categories.
There are essentially two theories of solutions that can be considered exact: the McMillan-Mayer theory and Fluctuation Solution Theory (FST). The first is mostly limited to solutes at low concentrations, while FST has no such issue. It is an exact theory that can be applied to any stable solution regardless of the number of components and their co
Structure Fluctuation And Relaxation In Solutions
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Author : H. Nomura
language : en
Publisher: Elsevier
Release Date : 1995-12-20
Structure Fluctuation And Relaxation In Solutions written by H. Nomura and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1995-12-20 with Science categories.
The results of a special research project carried out for "Molecular Approaches to Non-equilibrium Process in Solution" were presented during The 42nd Yamada Conference on "Structure, Fluctuation and Relaxation in Solution" which was held from 11-15 December, 1994. The following topics were discussed at the conference:1. Solvation Dynamics 2. Relaxation, Fluctuation and Reaction Dynamics 3. Dynamic Structure and Reaction Mechanisms in Solutions. These topics were the main concern of this conference.
Theory Of Solutions
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Author : John G. Kirkwood
language : en
Publisher: CRC Press
Release Date : 2001-12
Theory Of Solutions written by John G. Kirkwood and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001-12 with Science categories.
Thermodynamics Of Solutions
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Author : Eli Ruckenstein
language : en
Publisher: Springer Science & Business Media
Release Date : 2009-06-17
Thermodynamics Of Solutions written by Eli Ruckenstein and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-06-17 with Science categories.
This book consists of a number of papers regarding the thermodynamics and structure of multicomponent systems that we have published during the last decade. Even though they involve different topics and different systems, they have something in common which can be considered as the “signature” of the present book. First, these papers are concerned with “difficult” or very nonideal systems, i. e. systems with very strong interactions (e. g. , hyd- gen bonding) between components or systems with large differences in the partial molar v- umes of the components (e. g. , the aqueous solutions of proteins), or systems that are far from “normal” conditions (e. g. , critical or near-critical mixtures). Second, the conventional th- modynamic methods are not sufficient for the accurate treatment of these mixtures. Last but not least, these systems are of interest for the pharmaceutical, biomedical, and related ind- tries. In order to meet the thermodynamic challenges involved in these complex mixtures, we employed a variety of traditional methods but also new methods, such as the fluctuation t- ory of Kirkwood and Buff and ab initio quantum mechanical techniques. The Kirkwood-Buff (KB) theory is a rigorous formalism which is free of any of the - proximations usually used in the thermodynamic treatment of multicomponent systems. This theory appears to be very fruitful when applied to the above mentioned “difficult” systems.
Advances In Chemical Physics
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Author : Ilya Prigogine
language : en
Publisher: John Wiley & Sons
Release Date : 2009-09-09
Advances In Chemical Physics written by Ilya Prigogine and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2009-09-09 with Science categories.
Volume 109 in the prestigious Advances in Chemical Physics Series, edited by Nobel Prize winner Ilya Prigogine, and renowned authority Stuart A. Rice, continues to report recent advances in every area of the discipline. Significant, up-to-date chapters by internationally recognized researchers present comprehensive analyses of subjects of interest and encourage the expression of individual points of view. This approach to presenting an overview of a subject will both stimulate new research and serve as a personalized learning text for beginners in the field.
Ions In Solution And Their Solvation
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Author : Yizhak Marcus
language : en
Publisher: John Wiley & Sons
Release Date : 2015-06-18
Ions In Solution And Their Solvation written by Yizhak Marcus and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-06-18 with Science categories.
The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the solvent dynamics and structure what happens in cases where the solvent is a mixture selective solvation takes place applications of the concepts expounded previously in fields such as electrochemistry, hydrometallurgy, separation chemistry, biophysics, and synthetic methods
Polymers And Electromagnetic Radiation
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Author : Wolfram Schnabel
language : en
Publisher: John Wiley & Sons
Release Date : 2014-01-10
Polymers And Electromagnetic Radiation written by Wolfram Schnabel and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-01-10 with Technology & Engineering categories.
This first book to cover the interaction of polymers with radiation from the entire electromagnetic spectrum adopts a multidisciplinary approach to bridge polymer chemistry and physics, photochemistry, photophysics and materials science. The text is equally unique in its scope, devoting equal amounts of attention to the three aspects of synthesis, characterization, and applications. The first part deals with the interaction of polymers with non-ionizing radiation in the frequency-range from sub-terahertz via infrared radiation to visible and ultraviolet light, while the second covers interaction with ionizing radiation from the extreme ultraviolet to ?-ray photons. The result is a systematic overview of how both types of radiation can be used for different polymerization approaches, spectroscopy methods and lithography techniques. Authored by a world-renowned researcher and teacher with over 40 years of experience in the field, this is a highly practical and authoritative guide.
Supercritical Fluids
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Author : E. Kiran
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Supercritical Fluids written by E. Kiran and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Supercritical fluids are neither gas nor liquid, but can be compressed gradually from low to high density and they are therefore interesting and important as tunable solvents and reaction media in the chemical process industry. By adjusting the density the properties of these fluids can be customised and manipulated for a given process - physical or chemical transformation. Separation and processing using supercritical solvents such as CO2 are currently on-line commercially in the food, essential oils and polymer industries. Many agencies and industries are considering the use of supercritical water for waste remediation. Supercritical fluid chromatography represents another, major analytical application. Significant advances have recently been made in materials processing, ranging from particle formation to the creation of porous materials. The chapters in this book provide tutorial accounts of topical areas centred around: (1) phase equilibria, thermodynamics and equations of state; (2) critical behaviour, crossover effects; (3) transport and interfacial properties; (4) molecular modelling, computer simulation; (5) reactions, spectroscopy; (6) phase separation kinetics; (7) extractions; (8) applications to polymers, pharmaceuticals, natural materials and chromatography; (9) process scale-up.
Advances In Chemical Physics Volume 153
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Author : Stuart A. Rice
language : en
Publisher: John Wiley & Sons
Release Date : 2013-04-15
Advances In Chemical Physics Volume 153 written by Stuart A. Rice and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-04-15 with Science categories.
Detailed reviews of new and emerging topics in chemical physics presented by leading experts The Advances in Chemical Physics series is dedicated to reviewing new and emerging topics as well as the latest developments in traditional areas of study in the field of chemical physics. Each volume features detailed comprehensive analyses coupled with individual points of view that integrate the many disciplines of science that are needed for a full understanding of chemical physics. Volume 153 of Advances in Chemical Physics features six expertly written contributions: Recent advances of ultrafast X-ray absorption spectroscopy for molecules in solution Scaling perspective on intramolecular vibrational energy flow: analogies, insights, and challenges Longest relaxation time of relaxation processes for classical and quantum Brownian motion in a potential escape rate theory approach Local fluctuations in solution: theory and applications Macroscopic effects of microscopic heterogeneity Ab initio methodology for pseudospin Hamiltonians of anisotropic magnetic centers Reviews published in Advances in Chemical Physics are typically longer than those published in journals, providing the space needed for readers to fully grasp the topic: the fundamentals as well as the latest discoveries, applications, and emerging avenues of research. Extensive cross-referencing enables readers to explore the primary research studies underlying each topic. Advances in Chemical Physics is ideal for introducing novices to topics in chemical physics. Moreover, the series provides the foundation needed for more experienced researchers to advance their own research studies and continue to expand the boundaries of our knowledge in chemical physics.
The Potential Distribution Theorem And Models Of Molecular Solutions
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Author : Tom L. Beck
language : en
Publisher: Cambridge University Press
Release Date : 2006-08-31
The Potential Distribution Theorem And Models Of Molecular Solutions written by Tom L. Beck and has been published by Cambridge University Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-08-31 with Technology & Engineering categories.
An understanding of statistical thermodynamic molecular theory is fundamental to the appreciation of molecular solutions. This complex subject has been simplified by the authors with down-to-earth presentations of molecular theory. Using the potential distribution theorem (PDT) as the basis, the text provides a discussion of practical theories in conjunction with simulation results. The authors discuss the field in a concise and simple manner, illustrating the text with useful models of solution thermodynamics and numerous exercises. Modern quasi-chemical theories that permit statistical thermodynamic properties to be studied on the basis of electronic structure calculations are given extended development, as is the testing of those theoretical results with ab initio molecular dynamics simulations. The book is intended for students taking up research problems of molecular science in chemistry, chemical engineering, biochemistry, pharmaceutical chemistry, nanotechnology and biotechnology.