Frustrated Lewis Pairs
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A Primer In Frustrated Lewis Pair Hydrogenation Concepts To Applications
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Author : Douglas W. Stephan
language : en
Publisher: Royal Society of Chemistry
Release Date : 2021-11-17
A Primer In Frustrated Lewis Pair Hydrogenation Concepts To Applications written by Douglas W. Stephan and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-11-17 with Science categories.
Written for senior undergraduate and graduate students, as well as those chemists unfamiliar with "frustrated Lewis pairs (FLPs)", this text serves as an introduction to the both the concept and application of FLPs in hydrogenation catalysis. The book begins by setting the stage as it was around the turn of the century. While the dramatic impacts of catalysis were undeniable, there was dependence of such technologies on transition metal chemistry. Contrastingly, the chemistry of main group elements was dominated by Lewis acid-base behavior. However, these perceptions were altered with the discovery of the ability of "frustrated Lewis pairs (FLPs)" to activate dihydrogen. The basic features, and mechanisms of action of these unique main group systems are chronicled, while the evolution of the initial findings to applications in catalytic hydrogenation is discussed. A subsequent chapter focuses on the breadth of organic substrates for which borane based FLP hydrogenations are effective. This is furthered with a chapter on the metal-free enantioselective reductions. FLP chemistry is not limited to systems involving boranes and this book also catalogues a range of FLP hydrogenation catalysts involving elements from across the periodic table. The final chapter in the book describes other directions of interest where the application of the concept of FLPs hydrogenation are beginning to emerge. Ideal for course use and self study, this book provides synthetic chemists with a fresh, expert introduction to the field. The reader will be left recognizing that hydrogenation catalysts is a domain no longer limited to transition metals.
Frustrated Lewis Pairs
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Author : J. Chris Slootweg
language : en
Publisher: Springer Nature
Release Date : 2020-11-22
Frustrated Lewis Pairs written by J. Chris Slootweg and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-11-22 with Science categories.
This volume highlights the latest research in frustrated Lewis pair (FLP) chemistry and its applications. The contributions present the recent developments of the use of FLPs in asymmetric catalysis, polymer synthesis, homogeneous and heterogeneous catalysis, as well as demonstrating their use as a pedagogical tool. The book will be of interest to researchers in academia and industry alike.
Frustrated Lewis Pairs I
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Author : Gerhard Erker
language : en
Publisher: Springer
Release Date : 2014-07-08
Frustrated Lewis Pairs I written by Gerhard Erker and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-07-08 with Science categories.
Discovery of Frustrated Lewis Pairs: Intermolecular FLPs for Activation of Small Molecules, by Douglas W. Stephan Intramolecular Frustrated Lewis Pairs: Formation and Chemical Features, by Gerald Kehr, Sina Schwendemann, Gerhard Erker Frustrated Lewis Pair Mediated Hydrogenations, by Douglas W. Stephan, Gerhard Erker Amine-Borane Mediated Metal-Free Hydrogen Activation and Catalytic Hydrogenation, by Victor Sumerin, Konstantin Chernichenko, Felix Schulz, Markku Leskelä, Bernhard Rieger, Timo Repo Hydrogen Activation by Frustrated Lewis Pairs: Insights from Computational Studies, by Tibor András Rokob, Imre Pápai Quantum Chemistry of FLPs and Their Activation of Small Molecules: Methodological Aspects, by Birgitta Schirmer, Stefan Grimme Computational Design of Metal-Free Molecules for Activation of Small Molecules, Hydrogenation, and Hydroamination, by Zhi-Xiang Wang, Lili Zhao, Gang Lu, Haixia Li, Fang Huang Computational Studies of Lewis Acidity and Basicity in Frustrated Lewis Pairs, by Thomas M. Gilbert Solid-State NMR as a Spectroscopic Tool for Characterizing Phosphane - Borane Frustrated Lewis Pairs, by Thomas Wiegand, Hellmut Eckert, Stefan Grimme
Frustrated Lewis Pairs Ii
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Author : Gerhard Erker
language : en
Publisher: Springer
Release Date : 2013-12-12
Frustrated Lewis Pairs Ii written by Gerhard Erker and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-12-12 with Science categories.
Frustrated Lewis Pairs: From Dihydrogen Activation to Asymmetric Catalysis, by Dianjun Chen, Jürgen Klankermayer Coexistence of Lewis Acid and Base Functions: A Generalized View of the Frustrated Lewis Pair Concept with Novel Implications for Reactivity, by Heinz Berke, Yanfeng Jiang, Xianghua Yang, Chunfang Jiang, Subrata Chakraborty, Anne Landwehr New Organoboranes in "Frustrated Lewis Pair" Chemistry, by Zhenpin Lu, Hongyan Ye, Huadong Wang Paracyclophane Derivatives in Frustrated Lewis Pair Chemistry, by Lutz Greb, Jan Paradies Novel Al-Based FLP Systems, by Werner Uhl, Ernst-Ulrich Würthwein N-Heterocyclic Carbenes in FLP Chemistry, by Eugene L. Kolychev, Eileen Theuergarten, Matthias Tamm Carbon-Based Frustrated Lewis Pairs, by Shabana Khan, Manuel Alcarazo Selective C-H Activations Using Frustrated Lewis Pairs. Applications in Organic Synthesis, by Paul Knochel, Konstantin Karaghiosoff, Sophia Manolikakes FLP-Mediated Activations and Reductions of CO2 and CO, by Andrew E. Ashley, Dermot O’Hare Radical Frustrated Lewis Pairs, by Timothy H. Warren and Gerhard Erker Polymerization by Classical and Frustrated Lewis Pairs, by Eugene Y.-X. Chen Frustrated Lewis Pairs Beyond the Main Group: Transition Metal-Containing Systems, by D. Wass Reactions of Phosphine-Boranes and Related Frustrated Lewis Pairs with Transition Metal Complexes, by Abderrahmane Amgoune, Ghenwa Bouhadir, Didier Bourissou
Frustrated Lewis Pairs
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Author : Douglas Stephan
language : en
Publisher:
Release Date :
Frustrated Lewis Pairs written by Douglas Stephan and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on with categories.
Frustrated Lewis Pairs
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Author : Gerhard Erker
language : en
Publisher:
Release Date : 2013
Frustrated Lewis Pairs written by Gerhard Erker and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013 with categories.
Frustrated Lewis Pairs Ii
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Author : Gerhard Erker
language : en
Publisher:
Release Date : 2013-06-30
Frustrated Lewis Pairs Ii written by Gerhard Erker and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-06-30 with categories.
Synthetic Inorganic Chemistry
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Author : Ewan J. M. Hamilton
language : en
Publisher: Elsevier
Release Date : 2021-04-17
Synthetic Inorganic Chemistry written by Ewan J. M. Hamilton and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-04-17 with Science categories.
Synthetic Inorganic Chemistry: New Perspectives presents summaries of the work of some of the most creative researchers in the field. The book highlights the most novel approaches and burgeoning applications of synthetic inorganic chemistry in development. Topics include non-precious metals in catalysis, smart inorganic polymers, new inorganic therapeutics, new photocatalysts for hydrogen production, and more. As the first volume in the Developments in Inorganic Chemistry series, this work is a valuable resource for students and researchers working in inorganic chemistry and material science. Illustrates the scope and vitality of modern synthetic inorganic chemistry Shows the centrality of inorganic chemistry, addressing a variety of global challenges Serves to define the current, important and expanding roles of synthetic inorganic chemistry in interdisciplinary areas such as materials science, synthetic organic chemistry, homogeneous and heterogeneous catalysis
Cooperative Catalysis
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Author : René Peters
language : en
Publisher: John Wiley & Sons
Release Date : 2015-04-27
Cooperative Catalysis written by René Peters and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015-04-27 with Technology & Engineering categories.
Written by experts in the field, this is a much-needed overview of the rapidly emerging field of cooperative catalysis. The authors focus on the design and development of novel high-performance catalysts for applications in organic synthesis (particularly asymmetric synthesis), covering a broad range of topics, from the latest progress in Lewis acid / Br?nsted base catalysis to e.g. metal-assisted organo catalysis, cooperative metal/enzyme catalysis, and cooperative catalysis in polymerization reactions and on solid surfaces. The chapters are classified according to the type of cooperating activating groups, and describe in detail the different strategies of cooperative activation, highlighting their respective advantages and pitfalls. As a result, readers will learn about the different concepts of cooperative catalysis, their corresponding modes of operation and their applications, thus helping to find a solution to a specific synthetic catalysis problem.
Catalysis Without Precious Metals
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Author : R. Morris Bullock
language : en
Publisher: John Wiley & Sons
Release Date : 2011-08-02
Catalysis Without Precious Metals written by R. Morris Bullock and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-08-02 with Science categories.
Written for chemists in industry and academia, this ready reference and handbook summarizes recent progress in the development of new catalysts that do not require precious metals. The research thus presented points the way to how new catalysts may ultimately supplant the use of precious metals in some types of reactions, while highlighting the remaining challenges. An essential copanion for organic and catalytic chemists, as well as those working with/on organometallics and graduate students. From the contents: * Catalysis Involving the H' Transfer Reactions of First-Row Transition Metals * Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum Complexes * Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis * Iron in Catalytic Alkene and Carbonyl Hydrogenation Reactions * Olefin Oligomerizations and Polymerizations Catalyzed by Iron and Cobalt Complexes * Cobalt and Nickel Catalyzed Reactions Involving C-H and C-N Activation Reactions * Development of Molecular Electrocatalysts for H2 Oxidation and Production Based on Inexpensive Metals * Nickel-Catalyzed Reductinve Couplings and Cyclizations * Copper-Catalyzed Ligand Promoted Ullmann-Type Coupling Reactions * Copper-Catalyzed Azide-Alkyne Cycloaddition * "Frustrated Lewis Pairs": A Metal-Free Strategy for Hydrogenation Catalysis