Functionalization And Metallization Of Diamondoids


Functionalization And Metallization Of Diamondoids
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Functionalization And Metallization Of Diamondoids


Functionalization And Metallization Of Diamondoids
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Author : Maria Agatha E. Gunawan
language : en
Publisher:
Release Date : 2015

Functionalization And Metallization Of Diamondoids written by Maria Agatha E. Gunawan and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015 with categories.


The thesis deals with development of synthetic methods for preparation of novel carbon-metal organohybrid based on diamondoid and palladium. The vapor pressure of various diamondoids was measured from a new measurement protocol at solid-vapor thermodynamic equilibrium state. Their volatile tendency opened a possibility to do deposition from gas phase and at various pressure (ambient, primary vacuum, and high vacuum) of diamondoids on silicon or mica substrates. SEM observations have shown that depending on the type of functional groups on the diamondoid, different crystal shapes can be produced (rods, needles, triangles, truncated octahedral form).OMCVD of palladium on functionalized diamantanes showed that Pd deposition occurs preferentially on the oxide native layer on silicon substrates than on diamondoid crystals bearing hydroxyl or fluorine groups. This urged the synthesis new diamondoids with phosphino groups in order to make strong covalent bonding between the modified diamondoid and palladium.A full set of functionalized diamondoid phosphines were synthesized with unexpected air-stability of some primary diamondoid phosphines were observedIt has been shown that the use of P(III) phosphine as anchoring sites allowed the formation of hybrid material Pd@PH2-Diam-OH. Different characterizations (XPS, SEM, TEM, and EDX) indicated that an insulator material Pd@PH2-Diam-OH formed during the CVD deposition with P-Pd interaction.



The Chemistry Of Diamondoids


The Chemistry Of Diamondoids
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Author : Peter R. Schreiner
language : en
Publisher: John Wiley & Sons
Release Date : 2024-06-17

The Chemistry Of Diamondoids written by Peter R. Schreiner and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-06-17 with Technology & Engineering categories.


The Chemistry of Diamondoids Comprehensive resource on an important and fascinating compound class, covering synthesis, properties, functionalization, and applications in organic synthesis, materials science, and more The Chemistry of Diamondoids gives a state-of-the-art overview of all aspects of diamondoid chemistry, covering nomenclature, natural occurrence, chemical and physical properties, along with synthesis and functionalization of diamondoids as well as their applications as molecular building blocks in organic synthesis, polymer and materials science, nanotechnology, and medicinal chemistry. The book concludes with a perspective towards future developments in the field, thereby drawing attention to areas open for discovery. Written by experts in the field, The Chemistry of Diamondoids includes information on: Naturally occurring diamondoids, their formation, and the role they play in the petroleum industry and in geosciences, plus man-made approaches to prepare them on large scale Growing diamond from diamondoids via seeding, preparation and properties of diamondoid oligomers and doped diamondoids C–H-bond functionalization, a precondition for their use in many applications, and fine-tuning of diamondoid properties by precise cage substitution reactions With its all-encompassing approach, The Chemistry of Diamondoids is a valuable guide for newcomers and researchers in organic chemistry and materials science interested in modern synthetic methods and organic functional materials.



Diamondoid Molecules With Applications In Biomedicine Materials Science Nanotechnology Petroleum Science


Diamondoid Molecules With Applications In Biomedicine Materials Science Nanotechnology Petroleum Science
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Author : G Ali Mansoori
language : en
Publisher: World Scientific
Release Date : 2012-09-06

Diamondoid Molecules With Applications In Biomedicine Materials Science Nanotechnology Petroleum Science written by G Ali Mansoori and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-09-06 with Science categories.


Diamondoids are cage-like, ultra stable, saturated ringed hydrocarbons, which have a diamond-like structure consisting of a number of six-member carbon rings fused together. Adamantane is the cage compound prototype and the simplest diamondoid molecule. Diamondoids Molecules aims to present these fascinating substances in a novel fashion. The more intriguing facets of diamondoid molecules are comprehensively exposed and discussed, bringing state-of-the-art information to the reader, along with the history, fundamentals and perspectives of diamondoid science and technology.This groundbreaking book, especially devoted to diamondoid molecules, is of critical importance to the global techno-scientific community, and will be of great interest in many research fields such as chemistry, physics, material science, geology, and biological sciences. Moreover, it will attract readers from industrial, government and environmental agencies as well as scholars.



Diradicaloids


Diradicaloids
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Author : Jishan Wu
language : en
Publisher: CRC Press
Release Date : 2022-04-01

Diradicaloids written by Jishan Wu and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-04-01 with Science categories.


π-Conjugated molecules with an even number of π-electrons usually have a closed-shell ground state. However, recent studies have demonstrated that a certain type of molecules could show open-shell singlet ground state and display diradical-like (diradicaloid) behavior. Their electronic structure can be understood in terms of the “diradical character” and “aromaticity” concepts. They display very different electronic properties from traditional closed-shell π-conjugated molecules and could be used as next-generation molecular materials. This book provides a comprehensive review on the chemistry, physics, and material applications of open-shell singlet diradicaloids. Particularly, it elaborates the fundamental structure–diradical character–electronic property relationships both theoretically and experimentally. The book has been written by leading scientists in the field from Japan, Germany, Spain, Italy, China, and Singapore.



Advanced Healthcare Materials


Advanced Healthcare Materials
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Author : Ashutosh Tiwari
language : en
Publisher: John Wiley & Sons
Release Date : 2014-05-09

Advanced Healthcare Materials written by Ashutosh Tiwari and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-05-09 with Technology & Engineering categories.


Offers a comprehensive and interdisciplinary view of cutting-edge research on advanced materials for healthcare technology and applications Advanced healthcare materials are attracting strong interest in fundamental as well as applied medical science and technology. This book summarizes the current state of knowledge in the field of advanced materials for functional therapeutics, point-of-care diagnostics, translational materials, and up-and-coming bioengineering devices. Advanced Healthcare Materials highlights the key features that enable the design of stimuli-responsive smart nanoparticles, novel biomaterials, and nano/micro devices for either diagnosis or therapy, or both, called theranostics. It also presents the latest advancements in healthcare materials and medical technology. The senior researchers from global knowledge centers have written topics including: State-of-the-art of biomaterials for human health Micro- and nanoparticles and their application in biosensors The role of immunoassays Stimuli-responsive smart nanoparticles Diagnosis and treatment of cancer Advanced materials for biomedical application and drug delivery Nanoparticles for diagnosis and/or treatment of Alzheimers disease Hierarchical modelling of elastic behavior of human dental tissue Biodegradable porous hydrogels Hydrogels in tissue engineering, drug delivery, and wound care Modified natural zeolites Supramolecular hydrogels based on cyclodextrin poly(pseudo)rotaxane Polyhydroxyalkanoate-based biomaterials Biomimetic molecularly imprinted polymers



Molecular Building Blocks For Nanotechnology


Molecular Building Blocks For Nanotechnology
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Author : G.Ali Mansoori
language : en
Publisher: Springer Science & Business Media
Release Date : 2007-09-14

Molecular Building Blocks For Nanotechnology written by G.Ali Mansoori and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-09-14 with Technology & Engineering categories.


This book takes a "bottom-up" approach, beginning with atoms and molecules – molecular building blocks – and assembling them to build nanostructured materials. Coverage includes Carbon Nanotubes, Nanowires, and Diamondoids. The applications presented here will enable practitioners to design and build nanometer-scale systems. These concepts have far-reaching implications: from mechanical to chemical processes, from electronic components to ultra-fine sensors, from medicine to energy, and from pharmaceuticals to agriculture and food.



Nanosystems


Nanosystems
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Author : K. Eric Drexler
language : en
Publisher:
Release Date : 1992

Nanosystems written by K. Eric Drexler and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992 with Computers categories.


By manipulating common molecules at high frequency, molecular manufacturing will make these products quickly, inexpensively, and on a large scale. Molecular manufacturing is the key to implementing molecular nanotechnologies, building systems to complex atomic specifications.".



Polymeric Nanofibers


Polymeric Nanofibers
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Author : Darrell H. Reneker
language : en
Publisher: ACS Symposium
Release Date : 2006

Polymeric Nanofibers written by Darrell H. Reneker and has been published by ACS Symposium this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006 with Science categories.


Polymeric Nanofibers will showcase recent developments in the production, characterization, and emerging use of nanofibers made from different polymers for a variety of purposes. Although it has been difficult to produce polymer fibers in the laboratory, electrospinning now makes it easier. Electrospinning, an electrohydrodynamical process for making thin polymer fibers with diameters in the range from around one nanometer to several thousands of nanometers, is simple and cost effective. Interest in other specialized routes to polymer nanofibers, including chemical synthesis, conventional textile fiber spinning, gas blowing, and other methods has been stimulated by the recent progress in electrospinning. Scientists and engineers in fields such as filtration, biomaterials, biomedical devices, chemical analysis, catalysis, aerospace, fiber reinforced composites, energy conversion, protective clothing, agriculture, and others can produce experimental quantities of nanofibers in their own laboratories, from a wide variety of polymers of interest to them. The number of papers and patents in electrospinning has grown at a rapid rate during the past decade, more than doubling each year since 1999.



Nanofabrication


Nanofabrication
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Author :
language : en
Publisher:
Release Date :

Nanofabrication written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on with categories.




Electrical Engineering And Automation Proceedings Of The International Conference On Electrical Engineering And Automation Eea2016


Electrical Engineering And Automation Proceedings Of The International Conference On Electrical Engineering And Automation Eea2016
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Author : Zhang Xiaoxing
language : en
Publisher: World Scientific
Release Date : 2017-04-12

Electrical Engineering And Automation Proceedings Of The International Conference On Electrical Engineering And Automation Eea2016 written by Zhang Xiaoxing and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-04-12 with Technology & Engineering categories.


2016 International Conference on Electrical Engineering and Automation (EEA2016) was held in Hong Kong, China from June 24th–26th, 2016. EEA2016 has provided a platform for leading academic scientists, researchers, scholars and students around the world, to get together to compare notes, and share their results and findings, in areas of Electronics Engineering and Electrical Engineering, Materials and Mechanical Engineering, Control and Automation Modeling and Simulation, Testing and Imaging, Robotics, Actuating and Sensoring. The conference had received a total of 445 submissions. However, after peer review by the Technical Program Committee only 129 were selected to be included in this conference proceedings; based on their originality, ability to test ideas, and contribution to the understanding and advancement in Electronics and Electrical Engineering.