Gold And Silver Co Operative Catalysis For Carbon Bond Formation
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Gold And Silver Co Operative Catalysis For Carbon Bond Formation
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Author : Pradp Bgle
language : en
Publisher:
Release Date : 2023-09-14
Gold And Silver Co Operative Catalysis For Carbon Bond Formation written by Pradp Bgle and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-09-14 with Technology & Engineering categories.
This book is a comprehensive guidebook that covers the recent advances in gold and silver co-operative catalysis for carbon-carbon and carbon-heteroatom bond formation. The use of gold and silver in catalysis has revolutionized the field of organic synthesis, allowing for the development of new reactions and strategies that were previously inaccessible. The Book provides an in-depth discussion of the various gold and silver co-operative catalysis strategies and their application in the synthesis of a wide range of organic molecules, including pharmaceuticals, natural products, and materials. The author describes the key steps involved in these reactions, including the design of suitable catalysts, optimization of reaction conditions, and purification of the products. Also covers the use of gold and silver co-operative catalysis in the synthesis of other important compounds such as heterocycles, carbenes, and vinylidene complexes. The author discusses the advantages and limitations of gold and silver co-operative catalysis compared to other catalytic systems and provides practical guidance for researchers interested in using these catalysts in their own synthetic projects. Overall, "Gold and Silver Co-Operative Catalysis for Carbon Bond Formation" is an essential reference for synthetic chemists, medicinal chemists, and material scientists who are interested in the development of new catalytic systems for carbon-carbon and carbon-heteroatom bond formation using gold and silver co-operative catalysis.
Catalysis By Gold
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Author : Geoffrey C Bond
language : en
Publisher: World Scientific
Release Date : 2006-08-15
Catalysis By Gold written by Geoffrey C Bond and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2006-08-15 with Science categories.
Gold has traditionally been regarded as inactive as a catalytic metal. However, the advent of nanoparticulate gold on high surface area oxide supports has demonstrated its high catalytic activity in many chemical reactions. Gold is active as a heterogeneous catalyst in both gas and liquid phases, and complexes catalyse reactions homogeneously in solution. Many of the reactions being studied will lead to new application areas for catalysis by gold in pollution control, chemical processing, sensors and fuel cell technology. This book describes the properties of gold, the methods for preparing gold catalysts and ways to characterise and use them effectively in reactions. The reaction mechanisms and reasons for the high activities are discussed and the applications for gold catalysis considered./a
Silver In Organic Chemistry
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Author : Michael Harmata
language : en
Publisher: John Wiley & Sons
Release Date : 2011-01-11
Silver In Organic Chemistry written by Michael Harmata and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-01-11 with Science categories.
The first authoritative book on using silver cations in organic chemistry—for catalysis and more! With more sophisticated catalytic methodologies fueling a resurgence in the study of cation-based chemistry, gold and platinum have stepped to the fore as the unique agents used to create new chemical reactions. Although these metals have become a primary focus of researchers in the field, another coinage metal that is often overlooked—but is as powerful as the others—is silver, a far less costly alternative to gold and platinum in aiding the development of new reactions. Making a strong case for the use of silver as a catalyst and structural element in organometal constructs, this authoritative book is the first to explore the benefits of using silver in organic chemistry by taking a close look at silver’s unique reactivity and structural characteristics for the development of new methods and materials. Silver in Organic Chemistry is: The first book to address catalysis using silver, whose use in organic chemistry is on the verge of exploding A resource for researchers wishing to do chemistry with silver cations, an area that stands in the shadow of gold chemistry, but still glistens, demonstrating that all that glitters is not gold—sometimes it’s silver! A guide for “first attempts” in working with silver cations Edited by a very well-respected, highly visible authority in this field Silver in Organic Chemistry promotes further scientific discussion by offering important new ways to examine the future possibilities of an emerging field. By elevating the importance of silver chemistry, this thought-provoking guide illustrates how this versatile metal can become an increasingly significant player in opening the door to new catalytic organic reactions and new organometal materials.
Transition Metal Catalyzed Couplings In Process Chemistry
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Author : Javier Magano
language : en
Publisher: John Wiley & Sons
Release Date : 2013-07-03
Transition Metal Catalyzed Couplings In Process Chemistry written by Javier Magano and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-07-03 with Science categories.
Transition metal-catalyzed coupling reactions have a rich history that led to the awarding of the 2010 Nobel Prize in Chemistry to Professors Suzuki, Heck, and Negishi for their pioneering contributions to the field. The coming of age of this active area of research is showcased in this book through case studies in which process chemists from the pharmaceutical industry share their personal experiences developing their own transition metal-catalyzed couplings for the large-scale manufacture of active pharmaceutical ingredients. Authors from Pfizer, Merck, Boehringer-Ingelheim, Novartis, Amgen, GSK, AstraZeneca, and other companies describe the evolution of robust coupling processes from inception through early and late development, including commercial routes where applicable. This book covers a wide range of coupling transformations while capturing the lessons learned from each process. Every case study details the optimization of at least one transition metal-catalyzed coupling while elaborating on issues such as design of experiments, scalability and throughput, product purification, process safety, and waste management. The important issue of metal removal and the different technologies available to accomplish this goal are also addressed. Finally, a section covers novel technologies for cross-coupling with high potential for future applications on a large scale, such as microwave and flow chemistry as well as green cross-couplings performed in water. With Forewords by Stephen L. Buchwald, Massachusetts Institute of Technology, Trevor Laird, Editor of Organic Process Research and Development and Neal G. Anderson, Anderson's Process Solutions LLC.
Gold Catalysis
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Author : F Dean Toste
language : en
Publisher: World Scientific
Release Date : 2014-06-20
Gold Catalysis written by F Dean Toste and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-06-20 with Science categories.
Research on designing new catalytic systems has been one of the most important fields in modern organic chemistry. One reason for this is the predominant contribution of catalysis to the concepts of atom economy and green chemistry in the 21st century. Gold, considered catalytically inactive for a long time, is now a fascinating partner of modern chemistry, as scientists such as Bond, Teles, Haruta, Hutchings, Ito and Hayashi opened new perspectives for the whole synthetic chemist community. This book presents the major advances in homogeneous catalysis, emphasizing the methodologies that create carbon–carbon and carbon–heteroatom bonds, the applications that create diversity and synthesize natural products, and the recent advances and challenges in asymmetric catalysis and computational research. It provides readers with in-depth information about homogeneous gold-catalyzed reactions and presents several explanations for the scientific design of a catalyst. Readers will be able to understand the entire gold area and find solutions to problems in catalysis. Gold Catalysis — An Homogeneous Approach is part of the Catalytic Science Series and features prominent authors who are experts in their respective fields. Contents:From Gold in Nature to Gold Catalysts (Søren Kramer and Fabien Gagosz)Homogeneous Gold-Catalyzed Oxidation and Reduction Reactions (Liming Zhang)Gold-Catalyzed Addition of Carbon Nucleophiles to C–C Multiple Bonds, Carbonyls, and other Electrophiles (Bryon L Simmons and Hong C Shen)Gold-Catalyzed Addition of Heteroatom Nucleophile to C–C Multiple Bond (Naoki Asao, Naoya Hatakeyama and Yoshinori Yamamoto)Gold-Catalyzed Synthesis of Heterocycles (Antonio Arcadi)Gold-Catalyzed Multi-Component Reactions (Rachid Skouta and Chao-Jun Li)Gold Catalysis on Tandem and Cascade Reactions (Rai-Shung Liu)Cycloisomerization Reactions of 1, N-Enynes (Núria Huguet and Antonio M Echavarren)Gold-Catalyzed Reactions of Propargylic Esters (Louis Fensterbank, Jean-Philippe Goddard, Max Malacria and Antoine Simonneau)Gold-Catalyzed Cross-Coupling Reactions (Suzanne A Blum)Gold-Catalyzed Reactions: A Computational Approach (Elena Soriano and José Marco-Contelles)Recent Developments in Asymmetric Catalysis (Patrick Y Toullec, Alexandre Pradal and Véronique Michelet)Gold Catalysis in Natural Product Synthesis (Michael R Gesinski and F Dean Toste) Readership: Graduate students and researchers in organic chemistry. Key Features:First book on homogeneous gold catalysisProminent authorsFrom catalysts design to target-oriented applicationsA fascinating partner for modern chemistryKeywords:Gold;Catalysis;Heterocycles;Tandem;Cascade ReactionsReviews: “Gold Catalysis gives an excellent overview of a rapidly growing field. All of the thirteen chapters are written by the best practitioners. This book is certainly a “must” for laboratories working with coinage metals, but also for any organometallic group.” Guy Bertrand Distinguished Professor, University of California, San Diego Director of the UCSD/CNRS Joint Research Chemistry Laboratory (UMI 3555)
Fundamental Research In Homogeneous Catalysis
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Author : M. Tsutsui
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Fundamental Research In Homogeneous Catalysis written by M. Tsutsui and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
During the 70's it has become drastically apparent that our natural resources, including energy, are not in unlimited supply. This realization is strongly felt in the economic turmoil that is occurring, but its effects will penetrate into other areas, even causing moderate social changes. Chemists playa major role in coverting the world's natural resources into products. The public consumes these products and now depends upon them to keep the high standard of living to which they have become accustomed. This topic could easily be expounded into a whole article, but it is sufficent to say that almost everything-from the use of lightweight, strong polymers which are replacing the use of metals in today's automobiles, to the curing of diseases with asymetrically synthesized drugs-is related to the endeavors of chemistry. Catalysts have played a major role in transforming resources to useful products. Since a catalyst lowers the activation energy required for a particular reaction, and often for only one specific pathway where normally many exist, it is not surprising within the extant climate that researchers are now increasing their efforts and focusing their priorities on improving and discovering more efficient and selective catalysts.
Carbon Carbon Bond Formation
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Author : Robert L. Augustine
language : en
Publisher:
Release Date : 1979
Carbon Carbon Bond Formation written by Robert L. Augustine and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1979 with categories.
Metal Catalyzed Reductive C C Bond Formation
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Author : Michael J Krische
language : en
Publisher: Springer Science & Business Media
Release Date : 2007-10-05
Metal Catalyzed Reductive C C Bond Formation written by Michael J Krische and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2007-10-05 with Science categories.
With contributions by numerous experts
Silver Catalysis In Organic Synthesis
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Author : Chao-Jun Li
language : en
Publisher: John Wiley & Sons
Release Date : 2018-12-07
Silver Catalysis In Organic Synthesis written by Chao-Jun Li and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-12-07 with Science categories.
Covers all the aspects of the recent achievements in silver catalyzed reactions Silver catalysis has emerged as a powerful tool in the field of organic synthesis. This comprehensive book systematically explores the unique performance of silver catalysis, introducing all the recent progress of silver catalysis in organic synthesis. It clearly emphasizes the unique features of silver catalysis and provides the reaction mechanism involved. This two-volume book also provides vivid schematics and tables throughout to enhance the accessibility to the relevant theory and mechanisms. Silver Catalysis in Organic Synthesis begins with an introduction to Silver Chemistry before moving on to chapters covering: Silver-Catalyzed Cycloaddition Reactions; Silver-Catalyzed Cyclizations; Silver-Mediated Radical Reactions; Silver-Mediated Fluorination, Perfluoroalkylation and Trifluoromethylthiolation Reactions; Coupling Reactions and C-H Functionalization; Silver-Catalyzed CO2 Incorporation; Silver-Catalyzed Carbene, Nitrene, and Silylene Transfer Reactions; Asymmetric Silver-Catalyzed Reactions; Silver-Catalyzed Reduction and Oxidation of Aldehydes and Their Derivatives; Silver Complexes in Organic Transformations; and Silver Nanoparticles in Organic Transformations. -Covers recently developed organic reactions catalyzed by silver, along with their reaction mechanism -Introduces many new reactions and mechanisms related to silver catalysis -Offers professionals and newcomers in the related fields a survey of new advances in silver catalysis in organic synthesis Silver Catalysis in Organic Synthesis will appeal to a wide readership including chemists, biochemists, pharmaceutical scientists, biomedical researchers, agriculture scientists, and graduate students in the related fields.
Isocyanide Chemistry
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Author : V. Nenajdenko
language : en
Publisher: John Wiley & Sons
Release Date : 2012-06-04
Isocyanide Chemistry written by V. Nenajdenko and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-06-04 with Science categories.
The efficacy of isocyanide reactions in the synthesis of natural or naturallike products has resulted in a renaissance of isocyanide chemistry. Now isocyanides are widely used in different branches of organic, inorganic, coordination, combinatorial and medicinal chemistry. This invaluable reference is the only book to cover the topic in such depth, presenting all aspects of synthetic isonitrile chemistry. The highly experienced and internationally renowned editor has brought together an equally distinguished team of authors who cover multicomponent reactions, isonitriles in total synthesis, isonitriles in polymer chemistry and much more.