Heterogeneous Catalytic Oxidation
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Heterogeneous Catalytic Oxidation
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Author : B. K. Hodnett
language : en
Publisher: John Wiley & Sons
Release Date : 2000-07-13
Heterogeneous Catalytic Oxidation written by B. K. Hodnett and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2000-07-13 with Science categories.
This authoritative and comprehensive volume presents the essence of catalytic chemistry, describing the structure of catalysts, the technology in which they are used and the chemical transformations that occur during reaction. Heterogeneous catalytic oxidation is a key technique used in the large-scale production of organic chemicals. This text uses catalytic oxidation to explain the principles of heterogeneous catalysis and includes descriptions of how reactants and products interact on the molecular scale with the active sites on the surface of these materials. Following an introduction to the principles and chemistry of catalytic oxidation, Professor Hodnett uses detailed case studies which represent and illustrate the fundamentals and technology for specific aspects of heterogeneous catalytic oxidation including: * Propene Oxidation to Acrolein * n-Butane Oxidation to Maleic Anhydride * Epoxidation over Silver Catalysts * Fundamentals and Technologies of the Catalytic Destruction of Volatile Organic Compounds * Ammoxidation for the Insertion of Nitrogen into Organic Structures * Oxidative Insertion of Chlorine into Ethylene and Catalytic Combustion of Chlorinated Hydrocarbons * Liquid Phase Oxidations with Particular Emphasis on the Use of Hydrogen Peroxide as an Oxidizing Agent
Selective Oxidation By Heterogeneous Catalysis
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Author : Gabriele Centi
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Selective Oxidation By Heterogeneous Catalysis written by Gabriele Centi and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Selective Oxidation by Heterogeneous Catalysis covers one of the major areas of industrial petrochemical production, outlining open questions and new opportunities. It gives keys for the interpretation and analysis of data and design of new catalysts and reactions, and provides guidelines for future research. A distinctive feature of this book is the use of concept by example. Rather than reporting an overview of the literature results, the authors have selected some representative examples, the in-depth analysis of which makes it possible to clarify the fundamental, but new concepts necessary for a better understanding of the new opportunities in this field and the design of new catalysts or catalytic reactions. Attention is given not only to the catalyst itself, but also to the use of the catalyst inside the process, thus evidencing the relationship between catalyst design and engineering aspects of the process. This book provides suggestions for new innovative directions of research and indications on how to reconsider the field of selective oxidation from different perspectives, outlining that is not a mature field of research, but that new important breakthroughs can be derived from fundamental and applied research. Suggestions are offered on how to use less conventional approaches in terms of both catalyst design and analysis of the data.
Liquid Phase Oxidation Via Heterogeneous Catalysis
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Author : Mario G. Clerici
language : en
Publisher: John Wiley & Sons
Release Date : 2013-04-26
Liquid Phase Oxidation Via Heterogeneous Catalysis written by Mario G. Clerici and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-04-26 with Science categories.
Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.
New Developments In Selective Oxidation By Heterogeneous Catalysis
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Author : P. Ruiz
language : en
Publisher: Elsevier
Release Date : 1992-02-06
New Developments In Selective Oxidation By Heterogeneous Catalysis written by P. Ruiz and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 1992-02-06 with Technology & Engineering categories.
This volume contains invited papers and communications presented at the Third European Workshop Meeting on Selective Oxidation by Heterogeneous Catalysis. The purpose of the meeting was to present recent results and to discuss new aspects of partial oxidation by heterogeneous catalysis. The following topics were discussed: Novel processes for obtaining new fine chemicals by catalytic partial oxidation; selective oxidation and oxidative dehydrogenation of alkanes; new catalysts and advances in preparation methods of oxidation catalysts; new phenomena in partial oxidation and new aspects of surface chemistry in oxide catalysts; new applications of physicochemical methods for characterization of oxide catalysts; oxidation with other agents than oxygen and catalytic oxidation of carbohydrates. This book will provide a valuable set of data on reactions of selective oxidation which will be extremely useful to catalyst and related practitioners, whether fundamentalists or highly applied, and to process engineers who wish to evaluate current findings in this field. The wide-range approach to reactions of selective oxidation will disseminate knowledge in specialized areas of selective oxidation and encourage innovation and creativity.
Heterogeneous Catalytic Redox Reactions
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Author : Vladislav Sadykov
language : en
Publisher: Walter de Gruyter GmbH & Co KG
Release Date : 2019-10-21
Heterogeneous Catalytic Redox Reactions written by Vladislav Sadykov and has been published by Walter de Gruyter GmbH & Co KG this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-10-21 with Science categories.
The current book brings together cutting-edge research in the area of heterogeneous catalytic redox processes. The first part of the book covers the catalytic properties of transition metal oxides and the techniques for catalysts preparation, such as mechanochemistry, plasmochemistry, hydrothermal treatment, etc. Further the authors focus on mechanisms of heterogeneous redox reactions followed by the overview of industrial applications.
Heterogeneous Catalysis Of Mixed Oxides
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Author : Makoto Misono
language : en
Publisher: Elsevier Inc. Chapters
Release Date : 2013-02-28
Heterogeneous Catalysis Of Mixed Oxides written by Makoto Misono and has been published by Elsevier Inc. Chapters this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-02-28 with Science categories.
The chemistry of metal oxides, both single and mixed metal oxides, relevant to heterogeneous catalysis such as relationships among the composition, structure, and chemical properties of mixed oxides, is provided in perspective. The important chemical properties in heterogeneous catalysis are acid–base and reduction–oxidation (redox) properties, where ionic radii, electronegativity, valency, and tendency to form covalent bond of constituent elements are most influential. Structural factors such as lattice defects and nonstoichiometry are also relevant. Although the surface of metal oxides is different from the solid bulk and changes depending on various factors, the surface reflects more or less the solid bulk and the knowledge of bulk properties is useful to understand the catalysis of mixed oxides. In some cases, the solid bulk actually takes part in catalysis. Other fundamental features of metal oxide catalysis like synergistic effects of more than two different active sites (acid and base, acid and oxidation, etc.) are also discussed.
Catalytic Oxidation Principles And Applications A Course Of The Netherlands Institute For Catalysis Research Niok
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Author : R A Sheldon
language : en
Publisher: World Scientific
Release Date : 1995-10-30
Catalytic Oxidation Principles And Applications A Course Of The Netherlands Institute For Catalysis Research Niok written by R A Sheldon and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 1995-10-30 with categories.
This book consists of lectures presented by international authorities in the field, at a course on Oxidation Catalysis organized by the Dutch Research School in Catalysis at Rolduc in June 1994.The material covered spans the whole range of the subject from the fundamental principles of gas and liquid phase oxidations to reactor engineering for industrial processing. The use of catalytic oxidation in both bulk and fine chemicals manufacture and the different types of catalysis — heterogeneous-gas phase, homogeneous-liquid phase and heterogeneous-liquid phase — are discussed. In addition, a few special topics, such as electrocatalytic and high-temperature oxidation are dealt with.The book is intended for graduate students or industrial researchers who wish to acquaint themselves with the underlying principles of catalytic oxidations and the numerous applications of this important technology.
Heterogeneous Catalytic Reactions Involving Molecular Oxygen
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Author : G.I. Golodets
language : en
Publisher: Elsevier Health Sciences
Release Date : 1983
Heterogeneous Catalytic Reactions Involving Molecular Oxygen written by G.I. Golodets and has been published by Elsevier Health Sciences this book supported file pdf, txt, epub, kindle and other format this book has been release on 1983 with Science categories.
Preparation of Catalysts II.
Mechanisms In Heterogeneous Catalysis
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Author : Rutger A Van Santen
language : en
Publisher: World Scientific
Release Date : 2023-06-28
Mechanisms In Heterogeneous Catalysis written by Rutger A Van Santen and has been published by World Scientific this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023-06-28 with Science categories.
Heterogeneous catalysis has developed over the past two centuries as a technology driven by the needs of society, and is part of Nobel Prize-winning science. This book describes the spectacular increase in molecular understanding of heterogenous catalytic reactions in important industrial processes. Reaction mechanism and kinetics are discussed with a unique focus on their relation with the inorganic chemistry of the catalyst material. An introductory chapter presents the development of catalysis science and catalyst discovery from a historical perspective. Five chapters that form the thrust of the book are organized by type of reaction, reactivity principles, and mechanistic theories, which provide the scientific basis to structure-function relationships of catalyst performance. Present-day challenges to catalysis are sketched in a final chapter. Written by one of the world's leading experts on the topic, this definitive text is an essential reference for students, researchers and engineers working in this multibillion-dollar field.
Heterogeneous Catalysis In Organic Chemistry
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Author : Gerard V. Smith
language : en
Publisher: Academic Press
Release Date : 1999-06-30
Heterogeneous Catalysis In Organic Chemistry written by Gerard V. Smith and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1999-06-30 with Science categories.
The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can supplement advanced chemistry courses. Most synthetic organic chemists use a variety of "protecting groups" which they attach to functional groups (reactive groups of atoms) while some reaction is being conducted on another part of the molecule. These protecting groups prevent reactions of the functional groups during other reactions and are removed later by a heterogeneous catalytic method called hydrogenolysis. One unique feature of this book, not found in other books on catalysis, is an exhaustive chapter (Chapter 4) on hydrogenolysis, which is dredged from the recent synthetic literature published by modern organic chemists. Academic organic chemists should find this chapter extremely useful and may wish to adopt the book as a supplement for advanced organic chemistry courses designed for seniors and for graduate students. It will also be useful for professors and their research groups engaged in synthetic organic chemistry. Many academic organic chemists are not aware of recent advances in heterogeneous enantioselective catalysis (Chapter 3) or in selective low temperature, liquid phase heterogeneous catalytic oxidations by hydrogen peroxide (Chapter 6). These specialty topics are timely and may be new to academic organic chemists and can be used to supplement their advanced courses. Several features of this book will also be of special interest to industrial chemists who are unfamiliar with heterogeneous catalysis. Many good organic chemists are hire by industry. They synthesize a new compound using standard organic synthetic techniques but are informed by their supervisor that they must convert some of their synthetic steps into heterogeneous catalytic steps. They may not have been exposed to heterogeneous catalysis and have few places to turn. This book offers them a crash course in heterogeneous catalysis as well as many examples of reactions and conditions with which they can start their search. Those industrial organic chemists already familiar with heterogeneous catalysis will find this book useful as a reference to many examples in the recent literature. They will find recent surface science discoveries correlated with heterogeneous catalysis or organic reactions and mechanistic suggestions designed to stimulate innovative nontraditional thinking about organic reactions on surfaces. Written by organic chemists for organic chemists Introduces heterogeneous catalysis concepts and language Presents a comprehensive compilation of protecting group removal procedures Covers liquid-phase hydrogenations, hydrogenolysis, and oxidations Addresses heterogeneous methods for producing pure enantiomers of chiral products Examines the emerging field of heterogenized homogeneous catalysts Mixes practical applications with mechanistic interpretations