Highlights In Solute Solvent Interactions
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Highlights In Solute Solvent Interactions
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Author : Wolfgang Linert
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Highlights In Solute Solvent Interactions written by Wolfgang Linert and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the "outer sphere" kind, the choice of solvent can be critical to the successful outcome of an operation or preparation. Solubilities of reactants and products must be taken into account, and even if the organic principals in the reactions retain their integrity, many of the reagents are electrolytes, and their state of aggregation will affect their reactivity. In testifying to the importance of understanding solute-solvent interactions I draw attention to a large class of inorganic species for which the involvement in the chemical and physical properties by the solvent is even more deeply seated. It is comprised by the large body of metal atoms in low oxidation states for which solvent molecules intervene as reagents. At the same time, because the ions carry charges, the effects arising from outer sphere interactions are usually greater than they are for neutral molecules. To cite an example: when FeCb(s) is dissolved in water to form a dilute - say O. OlO- solution there is a complete reorganization of the coordination sphere of the cation. Whereas in the solid each cation is surrounded by six chloride ions, in the solution the dominant form is [Fe(H20)6]3+ followed by [Fe(H20)sCI]2+, [Fe(H20)4CI2]+, etc. in rapidly decreasing abundance.
Solute Solvent Interactions
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Author : Johannes Francois Coetzee
language : en
Publisher:
Release Date : 1969
Solute Solvent Interactions written by Johannes Francois Coetzee and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1969 with Solution (Chemistry) categories.
Molecular Magnets Recent Highlights
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Author : Wolfgang Linert
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Molecular Magnets Recent Highlights written by Wolfgang Linert and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The book deals with recent scientific highlights on molecular magnetism in Europe. Molecular magnetism is a new interdisciplinary discipline gathering together chemists and physicists, theoreticians and experimentalists. The book intends to provide the reader with documented answers to many current questions: How can chemists use soft conditions to transform molecules in light and transparent magnets. How does a molecular system can behave as a single molecule magnet. How to combine several functions in the same molecular system. How light can be used to switch molecular magnetic properties. How can molecules be used for ultimate high density information storage or in quantum computing. What kind of methods do physicists develop and use to explore these new properties of matter. What kind of concepts and calculations can be provided for theoreticians to design new objects and to better understand the field and to enlarge its exciting developments.
Solute Solvent Interactions 1969
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Author : Johannes François Coetzee
language : en
Publisher:
Release Date : 1969
Solute Solvent Interactions 1969 written by Johannes François Coetzee and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1969 with categories.
Quantitative Treatments Of Solute Solvent Interactions
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Author : P. Politzer
language : en
Publisher:
Release Date : 1994-12-07
Quantitative Treatments Of Solute Solvent Interactions written by P. Politzer and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994-12-07 with Science categories.
The primary objective of this volume, the first in a new series entitled Theoretical and Computational Chemistry, is to survey some effective approaches to understanding, describing and predicting ways in which solutes and solvents interact and the effects they have upon each other. The treatment of solute/solvent interactions that is presented emphasizes a synergism between theory and experiment. Data obtained experimentally are used as a basis for developing quantitative theoretical models that permit the correlation and interpretation of the data, and also provide a predictive capability. The latter being of course a key motivation for these efforts. Linear solvation energy relationships have been quite successful in this respect and accordingly receive considerable attention. Other effective approaches, including computational ones, are also being pursued, and are discussed in several chapters. This is an area that is continually evolving, and it is hoped that the present volume will convey a sense of its dynamic nature.
Annual Reports On Nmr Spectroscopy
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Author : Graham A. Webb
language : en
Publisher: Academic Press
Release Date : 2008-11-20
Annual Reports On Nmr Spectroscopy written by Graham A. Webb and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-11-20 with Science categories.
The great importance of NMR in many areas of scientific research is once again highlighted in this volume of Annual Reports on NMR Spectroscopy. Provides updates on the latest developments in NMR spectroscopy Includes comprehensive review articles Highlights the increasing importance of NMR spectroscopy as a technique for structural determination
Solvents And Solvent Effects In Organic Chemistry
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Author : Christian Reichardt
language : en
Publisher: John Wiley & Sons
Release Date : 2011-08-04
Solvents And Solvent Effects In Organic Chemistry written by Christian Reichardt and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2011-08-04 with Science categories.
Now in its 4th edition, this book remains the ultimate reference for all questions regarding solvents and solvent effects in organic chemistry. Retaining its proven concept, there is no other book which covers the subject in so much depth, the handbook is completely updated and contains 15% more content, including new chapters on "Solvents and Green chemistry", "Classification of Solvents by their Environmental Impact", and "Ionic Liquids". An essential part of every organic chemist's library.
Nanostructured Materials
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Author : Heinrich Hofmann
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Nanostructured Materials written by Heinrich Hofmann and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
The articles in this book summarize the work presented at the mid-term workshop of the COST (European Cooperation in the Fields of Scientific and Technical Research) action on Nanostructured Materials, which was held in October 2001 in Limerick, Ireland. The collection gives an excellent overview of the state-of-the-art, topical research areas in this field, and the progress made by the coordinated research projects. The articles cover synthesis, physical properties and characterization of nanostructured materials, such as magnetic and ferroelectric nanoparticles, nanoparticles in biological systems, metallic nanoparticles, nanocomposites, particle-reinforced polymers, semiconductor nanoparticles and thin films.
Handbook Of Solvents Volume 1
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Author : George Wypych
language : en
Publisher: Elsevier
Release Date : 2024-02-07
Handbook Of Solvents Volume 1 written by George Wypych and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2024-02-07 with Technology & Engineering categories.
This 4th edition of Handbook of Solvents, Volume 1, contains the most recent findings and trends in solvent applications. It is a comprehensive survey of the science of solvents and their properties, covering all aspects of solvent behavior that are relevant to their use in chemical and related industries including agricultural and technical processes, inorganic synthesis and materials chemistry, and more. Divided into two volumes, this first volume covers high-level information on the physical chemical properties of the most relevant solvent systems. Each chapter is focused on a specific aspect of solvent properties that determine its selection, such as the effect on properties of solutes and solutions, properties of different groups of solvents, and the summary of their applications’ effect on health and the environment (given in tabulated form). Also covered is swelling of solids in solvents, solvent diffusion and drying processes, nature of the interaction of solvent and solute in solutions, acid-base interactions, the effect of solvents on spectral and other electronic properties of solutions, the effect of solvents on the rheology of the solution, aggregation of solutes, permeability, molecular structure, crystallinity, configuration, conformation of dissolved high molecular weight compounds, and the effect of solvents on chemical reactions and reactivity of dissolved substances. With insight from specialists in a broad array of different areas and written with an interdisciplinary audience in mind, this thoroughly revised 4th edition provides readers with a complete overview of all the organic solvents available for industrial applications today. The book contains numerous references to key sources of more detailed information, and together with Handbook of Solvents Volume 2: Use, Health, and Environment; Databook of Green Solvents; and Databook of Solvents, represents the most comprehensive and up-to-date information ever published on solvents. Provides key insights that will help engineers and scientists select the best solvent for the job Includes practical information and ideas on how to improve existing processes involving solvents Presents the latest advances in solvent technology and their applications
Molecular Basics Of Liquids And Liquid Based Materials
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Author : Katsura Nishiyama
language : en
Publisher: Springer Nature
Release Date : 2022-01-03
Molecular Basics Of Liquids And Liquid Based Materials written by Katsura Nishiyama and has been published by Springer Nature this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-01-03 with Science categories.
This book sheds light on the molecular aspects of liquids and liquid-based materials such as organic or inorganic liquids, ionic liquids, proteins, biomaterials, and soft materials including gels. The reader discovers how the molecular basics of such systems are connected with their properties, dynamics, and functions. Once the use and application of liquids and liquid-based materials are understood, the book becomes a source of the latest, detailed knowledge of their structures, dynamics, and functions emerging from molecularity. The systems discussed in the book have structural dimensions varying from nanometers to millimeters, thus the precise estimation of structures and dynamics from experimental, theoretical, and simulation methods is of crucial importance. Outlines of the practical knowledge needed in research and development are helpfully included in the book.