Hypervalent Iodine In Organic Synthesis
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Hypervalent Iodine In Organic Synthesis
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Author : A. Varvoglis
language : en
Publisher: Academic Press
Release Date : 1996-11-14
Hypervalent Iodine In Organic Synthesis written by A. Varvoglis and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-11-14 with Science categories.
This book describes the fascinating chemistry of the many kinds of organic compounds of hypervalent iodine. Each chapter deals with a particular iodine compound or families of compounds which have been used as reagents in a plethora of useful transformations. These include assorted oxidation, such as with the precious Dess-Martin reagent as well as with a wide range of further reactions. Prominent features of hypervalent iodine reagents derived from iodobenzene are: ready availability, operational simplicity, mild reaction conditions, and high efficiency. They are environmentally safe and can be recycled. New species may be easily prepared by introducing substituents in the benzene ring or changing the ligand attached to iodine. Their combination with other reagents broadens considerably their synthetic potential. Today, no synthetic chemist can afford to ignore the valuable hypervalentiodine reagents. - Features up-to-date coverage of a wide range of topics - Includes many tables featuring a diversity of reactivity, and a comprehensive index - Acts as a comprehensive, up-to-date reference on all aspects of hypervalent iodine chemistry - Contains a section on unusual efficiency of hypervalent iodine reactions
Iodine Catalysis In Organic Synthesis
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Author : Kazuaki Ishihara
language : en
Publisher: John Wiley & Sons
Release Date : 2022-05-16
Iodine Catalysis In Organic Synthesis written by Kazuaki Ishihara and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-05-16 with Technology & Engineering categories.
Iodine Catalysis in Organic Synthesis The first book of its kind to highlight iodine as a sustainable alternative to conventional transition metal catalysis Iodine Catalysis in Organic Synthesis provides detailed coverage of recent advances in iodine chemistry and catalysis, focusing on the utilization of various iodine-containing compounds as oxidative catalysts. Featuring contributions by an international panel of leading research chemists, this authoritative volume explores the development of environmentally benign organic reactions and summarizes catalytic transformations of molecular iodine and iodine compounds such as hypervalent organoiodine and inorganic iodine salts. Readers are first introduced to the history of iodine chemistry, the conceptual background of homogeneous catalysis, and the benefits of iodine catalysis in comparison with transition metals. Next, chapters organized by reaction type examine enantioselective transformations, catalytic reactions involving iodine, catalyst states, oxidation in iodine and iodine catalyses, and catalytic reactions based on halogen bonding. Practical case studies and real-world examples of different applications in organic synthesis and industry are incorporated throughout the text. An invaluable guide for synthetic chemists in both academic and industrial laboratories, Iodine Catalysis in Organic Synthesis: Provides a thorough overview of typical iodine-catalyzed reactions, catalyst systems, structures, and reactivity Explores promising industrial applications of iodine-based reagents for organic synthesis Highlights the advantages iodine catalysis has over classical metal-catalyzed reactions Discusses sustainable and eco-friendly methods in hypervalent iodine chemistry Edited by two world authorities on the catalytic applications of organoiodine compounds, Iodine Catalysis in Organic Synthesis is required reading for catalytic, organic, and organometallic chemists, medicinal and pharmaceutical chemists, industrial chemists, and academic researchers and advanced students in relevant fields.
Hypervalent Iodine Chemistry
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Author : Thomas Wirth
language : en
Publisher: Springer
Release Date : 2003-07-01
Hypervalent Iodine Chemistry written by Thomas Wirth and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-07-01 with Science categories.
Annotation The pioneers of hypervalent iodine chemistry have already realized that the chemistry of iodine(iii) and iodine(v) containing compounds offers multiple advantages over established methods. A wide range of reactions is possible. Hypervalent Iodine Chemistry presents a comprehensive overview of the various facets, scope, and limitations of organic chemistry with hypervalent iodine compounds.
Chemistry Of Hypervalent Compounds
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Author : Kin-ya Akiba
language : en
Publisher: John Wiley & Sons
Release Date : 1998-12-18
Chemistry Of Hypervalent Compounds written by Kin-ya Akiba and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 1998-12-18 with Science categories.
Broad, comparative coverage of hypervalent compounds -a much-needed foundation in a rapidly growing field of chemistry. Although hypervalency is already a mature field in chemistry, it has seen a new surge of interest in recent years due to the discovery of compounds useful in organic synthesis, as well as others with significant applications for materials science. Now, this comprehensive book-written by a group of twenty leading experts in the field-provides an authoritative blueprint on the subject. Instead of focusing on compounds specific to one element, it presents a review of structure and reactivity among an extensive array of main group, organic, and organometallic hypervalent compounds. In so doing, the book offers essential information on underlying principles that unify seemingly unrelated families of main group element compounds. An invaluable resource for both organic and inorganic chemists, Chemistry of Hypervalent Compounds includes: * An overview of general aspects of structure and reactivity common among hypervalent compounds * Information on such recently characterized organic compounds as silicon, phosphorus, sulfur, iodine, and xenon * A review of new organometallic compounds with synthetic applications * Solid background material on compounds important in advanced materials science, such as semiconductors * A systematic approach using the N-X-L designation, where N represents the valence electrons of the central atom X, and L the ligands that bond the compound.
Iodine Chemistry And Applications
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Author : Tatsuo Kaiho
language : en
Publisher: John Wiley & Sons
Release Date : 2014-10-09
Iodine Chemistry And Applications written by Tatsuo Kaiho and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-10-09 with Science categories.
This book comprehensively covers iodine, its chemistry, and its role in functional materials, reagents, and compounds. • Provides an up-to-date, detailed overview of iodine chemistry with discussion on elemental aspects: characteristics, properties, iodides, and halogen bonding • Acts as a useful guide for readers to learn how to synthesize complex compounds using iodine reagents or intermediates • Describes traditional and modern processing techniques, such as starch, cupper, blowing out, and ion exchange resin methods • Includes seven detailed sections devoted to the applications of iodine: Characteristics, Production, Synthesis, Biological Applications, Industrial Applications, Bioorganic Chemistry and Environmental Chemistry, and Radioisotopes • Features hot topics in the field, such as hypervalent iodine-mediated cross coupling reactions, agrochemicals, dye sensitized solar cells, and therapeutic agents
Organoselenium Chemistry
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Author : Thomas Wirth
language : en
Publisher: John Wiley & Sons
Release Date : 2012-01-09
Organoselenium Chemistry written by Thomas Wirth and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-01-09 with Science categories.
Selenium-based methods in synthetic chemistry have developed rapidly over the past years and are now offering highly useful tools for organic synthesis. Filling the gap for a comprehensive handbook and ready reference, this book covers all modern developments within the field, including biochemical aspects. The chemistry chapters are organized according to the different reactivities of various selenium compounds and reagents, with each chapter dealing with a special reaction type. Also includes a table with 77Se NMR shifts to aid in practical problems. From the Contents: * Electrophilic and Nucleophilic Selenium * Selenium Compounds in Radical Reactions * Selenium-Stabilized Carbanions * Selenium Compounds with Valency Higher than Two * Selenocarbonyls * Selenoxide Elimination and [2,3]-Sigmatropic Rearrangement * Selenium Compounds as Ligands and Catalysts * Biological and Biochemical Aspects of Selenium Compounds
The Chemistry Of Hypervalent Halogen Compounds 2 Volume Set
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Author : Berit Olofsson
language : de
Publisher: John Wiley & Sons
Release Date : 2019-04-29
The Chemistry Of Hypervalent Halogen Compounds 2 Volume Set written by Berit Olofsson and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-04-29 with Science categories.
Für das Verständnis der organischen Chemie muss man wissen, worum es sich bei funktionalen Gruppen handelt. Dieses Fachbuch steht ganz in der Tradition der Reihe Patai's Chemistry of Functional Groups. Jeder Band deckt sämtliche Aspekte funktionaler Gruppen ab und behandelt dabei theoretische, analytische, synthetische, biologische Aspekte sowie Belange der Industrie. Hypervalente Halogenverbindungen, insbesondere Jodverbindungen, sind überaus effiziente und selektive Oxidantien für eine Vielzahl funktionaler Gruppen. Die elektrophilen Eigenschaften dieser Reagenzien können auch für die Einführung anderer Funktionalisierungen verwendet werden. Dieser Band ist der erste in der Reihe, die die Eigenschaften und das chemische Verhalten von hypervalentem Jod und Brom, deren Einsatz in der organischen Synthese sowie deren industrielle Anwendung untersucht. Wie bei allen neuen Bänden, werden die Kapitel zunächst online in Patai's Chemistry of Functional Groups veröffentlicht. Wenn ein Band online vervollständigt ist, erfolgt die Herausgabe als Printversion. Die Printfassung entspricht der Qualität, die man von der Patai-Reihe kennt, und bietet auch einen umfassenden Index.
Green Oxidation In Organic Synthesis
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Author : Ning Jiao
language : en
Publisher: John Wiley & Sons
Release Date : 2019-09-30
Green Oxidation In Organic Synthesis written by Ning Jiao and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-09-30 with Science categories.
A valuable introduction to green oxidation for organic chemists interested in discovering new strategies and new reactions for oxidative synthesis Green Oxidation in Organic Synthesis provides a comprehensive introduction and overview of chemical preparation by green oxidative processes, an entry point to the growing journal literature on green oxidation in organic synthesis. It discusses both experimental and theoretical approaches for the study of new catalysts and methods for catalytic oxidation and selective oxidation. The book highlights the discovery of new reactions and catalysts in recent years, discussing mechanistic insights into the green oxidative processes, as well as applications in organic synthesis with significant potential to have a major impact in academia and industry. Chapters are organized according to the functional groups generated in the reactions, presenting interesting achievements for functional group formation by green oxidative processes with O2, H2O2, photocatalytic oxidation, electrochemical oxidation, and enzymatic oxidation. The mechanisms of these novel transformations clearly illustrated. Green Oxidation in Organic Synthesis will serve as an excellent reference for organic chemists interested in discovering new strategies for oxidative synthesis which address the priorities of green and sustainable chemistry.
Strategies And Tactics In Organic Synthesis
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Author :
language : en
Publisher: Elsevier
Release Date : 2004-08-13
Strategies And Tactics In Organic Synthesis written by and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-08-13 with Science categories.
A classic in the area of organic synthesis, Strategies and Tactics in Organic Synthesis provides a forum for investigators to discuss their approach to the science and art of organic synthesis. Rather than a simple presentation of data or a second-hand analysis, we are given stories that vividly demonstrate the power of the human endeavour known as organic synthesis and the creativity and tenacity of its practitioners. First hand accounts of each project tell of the excitement of conception, the frustration of failure and the joy experienced when either rational thought and/or good fortune give rise to successful completion of a project. In this book we learn how synthesis is really done and are educated, challenged and inspired by these stories, which portray the idea that triumphs do not come without challenges. We also learn that we can meet challenges to further advance the science and art of organic synthesis, driving it forward to meet the demands of society, in discovering new reactions, creating new designs and building molecules with atom and step economies that provide solutions through function to create a better world.- Personal accounts of research in organic chemistry. - Written by internationally renowned scientists. - Details state of the art organic synthesis.