Hypervalent Iodine In Organic Synthesis
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Hypervalent Iodine In Organic Synthesis
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Author : A. Varvoglis
language : en
Publisher: Academic Press
Release Date : 1996-11-14
Hypervalent Iodine In Organic Synthesis written by A. Varvoglis and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-11-14 with Science categories.
This book describes the fascinating chemistry of the many kinds of organic compounds of hypervalent iodine. Each chapter deals with a particular iodine compound or families of compounds which have been used as reagents in a plethora of useful transformations. These include assorted oxidation, such as with the precious Dess-Martin reagent as well as with a wide range of further reactions. Prominent features of hypervalent iodine reagents derived from iodobenzene are: ready availability, operational simplicity, mild reaction conditions, and high efficiency. They are environmentally safe and can be recycled. New species may be easily prepared by introducing substituents in the benzene ring or changing the ligand attached to iodine. Their combination with other reagents broadens considerably their synthetic potential. Today, no synthetic chemist can afford to ignore the valuable hypervalentiodine reagents. Key Features * Features up-to-date coverage of a wide range of topics * Includes many tables featuring a diversity of reactivity, and a comprehensive index * Acts as a comprehensive, up-to-date reference on all aspects of hypervalent iodine chemistry * Contains a section on unusual efficiency of hypervalent iodine reactions
Hypervalent Iodine Chemistry
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Author : Thomas Wirth
language : en
Publisher: Springer
Release Date : 2003-07-01
Hypervalent Iodine Chemistry written by Thomas Wirth and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-07-01 with Science categories.
Annotation The pioneers of hypervalent iodine chemistry have already realized that the chemistry of iodine(iii) and iodine(v) containing compounds offers multiple advantages over established methods. A wide range of reactions is possible. Hypervalent Iodine Chemistry presents a comprehensive overview of the various facets, scope, and limitations of organic chemistry with hypervalent iodine compounds.
Hypervalent Iodine In Organic Chemistry
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Author : Robert M. Moriarty
language : en
Publisher: Wiley
Release Date : 2020-01-28
Hypervalent Iodine In Organic Chemistry written by Robert M. Moriarty and has been published by Wiley this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-01-28 with Science categories.
This title provides the only comprehensive review and analysis ofthe use of hypervalent iodine in organic synthesis. Detailed coverage includes: synthetic transformations such asaddition reactions to carbon-carbon double bonds, formation ofcarbon-carbon double bonds, intramolecular insertion at unactivatedC-H bonds, cyclopropanation creation of the nitrogen, creation ofelectron deficient carbon, simple oxidation of sulfides and amines,Dess-Martin reagent and Koser's reagent. This title aims to be practical to the reader, with a focus onsynthesis, particularly in natural products and commercialapplications.
Hypervalent Iodine Chemistry
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Author : Viktor V. Zhdankin
language : en
Publisher: John Wiley & Sons
Release Date : 2013-10-01
Hypervalent Iodine Chemistry written by Viktor V. Zhdankin and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-10-01 with Science categories.
Hypervalent Iodine Chemistry is the first comprehensive text covering all of the main aspects of the chemistry of organic and inorganic polyvalent iodine compounds, including applications in chemical research, medicine, and industry. Providing a comprehensive overview of the preparation, properties, and synthetic applications of this important class of reagents, the text is presented in the following way: The introductory chapter provides a historical background and describes the general classification of iodine compounds, nomenclature, hypervalent bonding, structural features, and the principles of reactivity of polyvalent iodine compounds. Chapter 2 gives a detailed description of the preparative methods and structural features of all known classes of organic and inorganic derivatives of polyvalent iodine. Chapter 3, the key chapter of the book, deals with the many applications of hypervalent iodine reagents in organic synthesis. Chapter 4 describes the most recent achievements in hypervalent iodine catalysis. Chapter 5 deals with recyclable polymer-supported and nonpolymeric hypervalent iodine reagents. Chapter 6 covers the "green" reactions of hypervalent iodine reagents under solvent-free conditions or in aqueous solutions. The final chapter provides an overview of the important practical applications of polyvalent iodine compounds in medicine and industry. This book is aimed at all chemists interested in iodine compounds, including academic and industrial researchers in inorganic, organic, physical, medicinal, and biological chemistry. It will be particularly useful to synthetic organic and inorganic chemists, including graduate and advanced undergraduate students. It comprehensively covers the green chemistry aspects of hypervalent iodine chemistry, making it especially useful for industrial chemists.
Iodine Catalysis In Organic Synthesis
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Author : Kazuaki Ishihara
language : en
Publisher: John Wiley & Sons
Release Date : 2022-05-16
Iodine Catalysis In Organic Synthesis written by Kazuaki Ishihara and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-05-16 with Technology & Engineering categories.
Iodine Catalysis in Organic Synthesis The first book of its kind to highlight iodine as a sustainable alternative to conventional transition metal catalysis Iodine Catalysis in Organic Synthesis provides detailed coverage of recent advances in iodine chemistry and catalysis, focusing on the utilization of various iodine-containing compounds as oxidative catalysts. Featuring contributions by an international panel of leading research chemists, this authoritative volume explores the development of environmentally benign organic reactions and summarizes catalytic transformations of molecular iodine and iodine compounds such as hypervalent organoiodine and inorganic iodine salts. Readers are first introduced to the history of iodine chemistry, the conceptual background of homogeneous catalysis, and the benefits of iodine catalysis in comparison with transition metals. Next, chapters organized by reaction type examine enantioselective transformations, catalytic reactions involving iodine, catalyst states, oxidation in iodine and iodine catalyses, and catalytic reactions based on halogen bonding. Practical case studies and real-world examples of different applications in organic synthesis and industry are incorporated throughout the text. An invaluable guide for synthetic chemists in both academic and industrial laboratories, Iodine Catalysis in Organic Synthesis: Provides a thorough overview of typical iodine-catalyzed reactions, catalyst systems, structures, and reactivity Explores promising industrial applications of iodine-based reagents for organic synthesis Highlights the advantages iodine catalysis has over classical metal-catalyzed reactions Discusses sustainable and eco-friendly methods in hypervalent iodine chemistry Edited by two world authorities on the catalytic applications of organoiodine compounds, Iodine Catalysis in Organic Synthesis is required reading for catalytic, organic, and organometallic chemists, medicinal and pharmaceutical chemists, industrial chemists, and academic researchers and advanced students in relevant fields.
Iodine Catalysis In Organic Synthesis
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Author : Kazuaki Ishihara
language : en
Publisher: John Wiley & Sons
Release Date : 2022-05-16
Iodine Catalysis In Organic Synthesis written by Kazuaki Ishihara and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-05-16 with Technology & Engineering categories.
Iodine Catalysis in Organic Synthesis The first book of its kind to highlight iodine as a sustainable alternative to conventional transition metal catalysis Iodine Catalysis in Organic Synthesis provides detailed coverage of recent advances in iodine chemistry and catalysis, focusing on the utilization of various iodine-containing compounds as oxidative catalysts. Featuring contributions by an international panel of leading research chemists, this authoritative volume explores the development of environmentally benign organic reactions and summarizes catalytic transformations of molecular iodine and iodine compounds such as hypervalent organoiodine and inorganic iodine salts. Readers are first introduced to the history of iodine chemistry, the conceptual background of homogeneous catalysis, and the benefits of iodine catalysis in comparison with transition metals. Next, chapters organized by reaction type examine enantioselective transformations, catalytic reactions involving iodine, catalyst states, oxidation in iodine and iodine catalyses, and catalytic reactions based on halogen bonding. Practical case studies and real-world examples of different applications in organic synthesis and industry are incorporated throughout the text. An invaluable guide for synthetic chemists in both academic and industrial laboratories, Iodine Catalysis in Organic Synthesis: Provides a thorough overview of typical iodine-catalyzed reactions, catalyst systems, structures, and reactivity Explores promising industrial applications of iodine-based reagents for organic synthesis Highlights the advantages iodine catalysis has over classical metal-catalyzed reactions Discusses sustainable and eco-friendly methods in hypervalent iodine chemistry Edited by two world authorities on the catalytic applications of organoiodine compounds, Iodine Catalysis in Organic Synthesis is required reading for catalytic, organic, and organometallic chemists, medicinal and pharmaceutical chemists, industrial chemists, and academic researchers and advanced students in relevant fields.
Hypervalent Iodine Chemistry
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Author : Thomas Wirth
language : en
Publisher: Springer
Release Date : 2014-03-12
Hypervalent Iodine Chemistry written by Thomas Wirth and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-03-12 with Science categories.
New Hypervalent Iodine Reagents For Oxidative Coupling
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Author : Toshifumi Dohi
language : en
Publisher: Frontiers Media SA
Release Date : 2021-03-30
New Hypervalent Iodine Reagents For Oxidative Coupling written by Toshifumi Dohi and has been published by Frontiers Media SA this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-03-30 with Science categories.
The Chemistry Of Hypervalent Halogen Compounds 2 Volume Set
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Author : Berit Olofsson
language : en
Publisher: John Wiley & Sons
Release Date : 2019-04-29
The Chemistry Of Hypervalent Halogen Compounds 2 Volume Set written by Berit Olofsson and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-04-29 with Science categories.
The understanding of functional groups is the key to understanding organic chemistry. In the tradition of Patai's Chemistry of Functional Groups each volume treats all aspects of functional groups, touching on theoretical, analytical, synthetic, biological, and industrial aspects. Hypervalent halogen compounds, in particular iodine compounds, are very efficient and selective oxidants which tolerate a wide range of functional groups. The electrophilic properties of these reagents can also be used to introduce other functionalizations. The present volume is the first in the series to survey the properties and chemical behaviour of hypervalent iodine and bromine, their use in organic synthesis, as well as their industrial application. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.
Iodine Chemistry And Applications
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Author : Tatsuo Kaiho
language : en
Publisher: John Wiley & Sons
Release Date : 2014-10-09
Iodine Chemistry And Applications written by Tatsuo Kaiho and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-10-09 with Science categories.
This book comprehensively covers iodine, its chemistry, and itsrole in functional materials, reagents, and compounds. • Provides an up-to-date, detailed overview of iodinechemistry with discussion on elemental aspects: characteristics,properties, iodides, and halogen bonding • Acts as a useful guide for readers to learn how tosynthesize complex compounds using iodine reagents orintermediates • Describes traditional and modern processingtechniques, such as starch, cupper, blowing out, and ion exchangeresin methods • Includes seven detailed sections devoted to theapplications of iodine: Characteristics, Production, Synthesis,Biological Applications, Industrial Applications, BioorganicChemistry and Environmental Chemistry, and Radioisotopes • Features hot topics in the field, such as hypervalentiodine-mediated cross coupling reactions, agrochemicals, dyesensitized solar cells, and therapeutic agents