Introduction To Theoretical Stereochemistry
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Introduction To Theoretical Stereochemistry
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Author : Vi͡acheslav Ivanovich Sokolov
language : en
Publisher: Taylor & Francis
Release Date : 1991
Introduction To Theoretical Stereochemistry written by Vi͡acheslav Ivanovich Sokolov and has been published by Taylor & Francis this book supported file pdf, txt, epub, kindle and other format this book has been release on 1991 with Science categories.
First published in 1991. Routledge is an imprint of Taylor & Francis, an informa company.
Introduction To Stereochemistry
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Author : Kurt Mislow
language : en
Publisher: Courier Corporation
Release Date : 2012-06-11
Introduction To Stereochemistry written by Kurt Mislow and has been published by Courier Corporation this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-06-11 with Science categories.
Molecular shape, form, and symmetry play a central role in organic chemistry, and this text presents a brief introduction to the conceptual basis of stereochemistry. Its focus lies in the fundamentals of structural stereochemistry, rather than the dynamic aspects that are more relevant to reaction mechanisms. The three-part treatment deals with structure and symmetry, stereoisomerism, and the separation and configuration of stereoisomers. The first section reviews molecular architecture, relating empirical bonding geometries to the hybridization of the central carbon atom. Students receive a nonrigorous treatment of symmetry elements and point groups, with particular focus on the presence or absence of reflection symmetry. The second section classifies stereoisomers according to symmetry properties and to the nature of their barriers; it also discusses the dependence of optical activity on structure and concludes with an examination of topological isomerism. The third and final section explores the conceptual basis of asymmetric syntheses and kinetic resolutions. Each of the major sections features a series of exercises that reinforce and extend the preceding material, and answers are provided. Preface to the Dover edition. Answers to Exercises. Bibliography. Index.
Theory Of Orientation And Stereoselection
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Author : K. Fukui
language : en
Publisher: Springer Science & Business Media
Release Date : 2013-04-17
Theory Of Orientation And Stereoselection written by K. Fukui and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2013-04-17 with Science categories.
Many organic chemists will agree with me that the old "electronic theory" has for a long time been inadequate for the interpretation of various new findings in chemistry, particularly for those of reactivity. Considering the outstanding progress which has been made during the past 20 years in the interpretation of these facts, aided by the molecular orbital theory, the time has finally come for a new book showing what is within and what is beyond the reach of quantum-chemical methods. It was therefore highly suitable that Dr. F. L. Boschke of the Springer Verlag suggested to me to make a contribution to a volume in the series "Topics in Current Chemistry" in February 1969. The article was published as Vol. 15, No 1 in June 1970. This new book is an expanded version of the article written in 1970. In this present volume several of the most up-to-date findings which have been gained in organic chemistry since then have been added. It is highly probable that a certain "theoretical" design in the experimenta lists' mind may have been the reason for these developments, whether they themselves are aware of it or not. Theory produces new experimental ideas and conversely, a host of experimental data add another vista to new theories. Due to the mutual beneficial effect of theory and experiment this book will always retain its value, although the quantum-chemical approach to the theory of reactivity is, of course, still in the develop mental stage.
Perspectives In Theoretical Stereochemistry
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Author : I. Ugi
language : en
Publisher: Springer Science & Business Media
Release Date : 2012-12-06
Perspectives In Theoretical Stereochemistry written by I. Ugi and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-06 with Science categories.
Stereochemistry is the part of chemistry that relates observable prop erties of chemical compounds to the structure of their molecules, i. e. the relative spatial arrangement of their constituent atoms. In classical stereochemistry, the spatial arrangements relevant for interpreting and predicting a given chemical property are customarily described by geometric features/ symmetries in some suitably chosen rigid model of the molecule The solution of stereochemical problems involving single molecular species is the danain of the geometry based approaches, such as the methods of classical stereochemistry, molecular mechanics and quantum chemistry. The molecules of a pure chemical compound form generally an ensemble of molecular individuals that differ in geometry and energy. Thus it is generally impossible to represent a chemical compund adequately by the geo metry of a rigid molecular model. In modern stereochemistry it is often necessary to analyze molecular relation within ensembles and families of stereoisomers and permutation isomers, including molecules whose geometric features are changing with time. Accordingly, there is definitely a need for new types of ideas, concepts, theories and techniques that are usable beyond the scope of customary methodology. This is why the present text was written.
An Introduction To Transition Metal Chemistry
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Author : Leslie E. Orgel
language : en
Publisher:
Release Date : 1970
An Introduction To Transition Metal Chemistry written by Leslie E. Orgel and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1970 with Ligand field theory categories.
An Introduction To Transition Metal Chemistry
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Author : Leslie E. Orgel
language : en
Publisher:
Release Date : 1965
An Introduction To Transition Metal Chemistry written by Leslie E. Orgel and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1965 with categories.
Mathematical Stereochemistry
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Author : Shinsaku Fujita
language : en
Publisher: Walter de Gruyter
Release Date : 2015
Mathematical Stereochemistry written by Shinsaku Fujita and has been published by Walter de Gruyter this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015 with Science categories.
Chirality and stereogenicity are closely related concepts and their differentiation and description is still a challenge in chemoinformatics. A new stereoisogram approach, developed by the author, is introduced in this book, providing a theoretical framework for mathematical aspects of modern stereochemistry. The discussion covers point-groups and permutation symmetry and exemplifies the concepts using organic molecules and inorganic complexes.
Stereochemistry
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Author : David G. Morris
language : en
Publisher: Royal Society of Chemistry
Release Date : 2001
Stereochemistry written by David G. Morris and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2001 with Education categories.
This text for undergraduate students presents an introduction to stereochemistry--the study of the three-dimensional structure of molecules--with a focus on organic chemistry. In eight chapters, Morris (U. of Glasgow) discusses topics such as the hybridization, conformation, and configuration of simple molecules; chiral molecules; molecules with two or more stereogenic centers; stereoisomerism in cyclic structures; and substitution reactions at saturated carbon. Coverage extends to the use of NMR spectroscopy in stereochemistry. c. Book News Inc.
Introduction To Stereochemistry
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Author : Kurt Martin Mislow
language : en
Publisher:
Release Date : 1972
Introduction To Stereochemistry written by Kurt Martin Mislow and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1972 with categories.
Chemical Graph Theory
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Author : D Bonchev
language : en
Publisher: Routledge
Release Date : 2018-05-11
Chemical Graph Theory written by D Bonchev and has been published by Routledge this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-05-11 with Science categories.
This volume presents the fundamentals of graph theory and then goes on to discuss specific chemical applications. Chapter 1 provides a historical setting for the current upsurge of interest in chemical graph theory. Chapter 2 gives a full background of the basic ideas and mathematical formalism of graph theory and includes such chemically relevant notions as connectedness, graph matrix representations, metric properties, symmetry and operations on graphs. This is followed by a discussion on chemical nomenclature and the trends in its rationalization by using graph theory, which has important implications for the storage and retrieval of chemical information. This volume also contains a detailed discussion of the relevance of graph-theoretical polynomials; it describes methodologies for the enumeration of isomers, incorporating the classical Polya method, as well as more recent approaches.