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Inward Lithium Ion Breathing Of Hierarchically Porous Silicon Anodes


Inward Lithium Ion Breathing Of Hierarchically Porous Silicon Anodes
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Inward Lithium Ion Breathing Of Hierarchically Porous Silicon Anodes


Inward Lithium Ion Breathing Of Hierarchically Porous Silicon Anodes
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Author :
language : en
Publisher:
Release Date : 2015

Inward Lithium Ion Breathing Of Hierarchically Porous Silicon Anodes written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015 with categories.


Silicon has been identified as one of the most promising candidates as anode for high performance lithium-ion batteries. The key challenge for Si anodes is the large volume change induced chemomechanical fracture and subsequent rapid capacity fading upon cyclic charge and discharge. Improving capacity retention thus critically relies on smart accommodation of the volume changes through nanoscale structural design. In this work, we report a novel fabrication method for hierarchically porous Si nanospheres (hp-SiNSs), which consist of a porous shell and a hollow core. Upon charge/discharge cycling, the hp-SiNSs accommodate the volume change through reversible inward expansion/contraction with negligible particle-level outward expansion. Our mechanics analysis revealed that such a unique volume-change accommodation mechanism is enabled by the much stiffer modulus of the lithiated layer than the unlithiated porous layer and the low flow stress of the porous structure. Such inward expansion shields the hp-SiNSs from fracture, opposite to the outward expansion in solid Si during lithiation. Lithium ion battery assembled with this new nanoporous material exhibits high capacity, high power, long cycle life and high coulombic efficiency, which is superior to the current commercial Si-based anode materials. We find the low cost synthesis approach reported here provides a new avenue for the rational design of hierarchically porous structures with unique materials properties.



Innovations In Engineered Porous Materials For Energy Generation And Storage Applications


Innovations In Engineered Porous Materials For Energy Generation And Storage Applications
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Author : Ranjusha Rajagopalan
language : en
Publisher: CRC Press
Release Date : 2018-04-27

Innovations In Engineered Porous Materials For Energy Generation And Storage Applications written by Ranjusha Rajagopalan and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-04-27 with Science categories.


Making innovative products for energy generation that decrease carbon footprints are the need of the hour. This book describes innovations in porous materials for energy generation and storage applications that can have applications in developed as well as developing countries. It provides a comprehensive account of porous materials for potential new applications, such as catalysts for gas storage and energy efficient transformations, which engineers and scientists working in the areas of solar cells, batteries, supercapacitors, fuel cells, etc. will find to be of immense interest.



Advanced Battery Materials


Advanced Battery Materials
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Author : Chunwen Sun
language : en
Publisher: John Wiley & Sons
Release Date : 2019-03-26

Advanced Battery Materials written by Chunwen Sun and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019-03-26 with Technology & Engineering categories.


This book details the latest R&D in electrochemical energy storage technologies for portable electronics and electric vehicle applications. During the past three decades, great progress has been made in R & D of various batteries in terms of energy density increase and cost reduction. One of the biggest challenges is increasing the energy density to achieve longer endurance time. In this book, recent research and development in advanced electrode materials for electrochemical energy storage devices is covered. Topics covered in this important book include: Carbon anode materials for sodium-ion batteries Lithium titanate-based lithium-ion batteries Rational material design and performance optimization of transition metal oxide-based lithium ion battery anodes Effects of graphene on the electrochemical properties of the electrode of lithium ion batteries Silicon-based lithium-ion battery anodes Mo-based anode materials for alkali metal ion batteries Lithium-sulfur batteries Graphene in Lithium-Ion/Lithium-Sulfur Batteries Graphene-ionic liquid supercapacitors Battery electrodes based on carbon species and conducting polymers Doped graphene for electrochemical energy storage systems Processing of graphene oxide for enhanced electrical properties



Synthesis And Characterization Of Porous Silicon Anode Materials For Lithium Ion Batteries


Synthesis And Characterization Of Porous Silicon Anode Materials For Lithium Ion Batteries
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Author : 林均潔
language : en
Publisher:
Release Date : 2008

Synthesis And Characterization Of Porous Silicon Anode Materials For Lithium Ion Batteries written by 林均潔 and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008 with categories.




Silicon Anode Systems For Lithium Ion Batteries


Silicon Anode Systems For Lithium Ion Batteries
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Author : Prashant N. Kumta
language : en
Publisher: Elsevier
Release Date : 2021-09-10

Silicon Anode Systems For Lithium Ion Batteries written by Prashant N. Kumta and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021-09-10 with Technology & Engineering categories.


Silicon Anode Systems for Lithium-Ion Batteries is an introduction to silicon anodes as an alternative to traditional graphite-based anodes. The book provides a comprehensive overview including abundance, system voltage, and capacity. It provides key insights into the basic challenges faced by the materials system such as new configurations and concepts for overcoming the expansion and contraction related problems. This book has been written for the practitioner, researcher or developer of commercial technologies. - Provides a thorough explanation of the advantages, challenge, materials science, and commercial prospects of silicon and related anode materials for lithium-ion batteries - Provides insights into practical issues including processing and performance of advanced Si-based materials in battery-relevant materials systems - Discusses suppressants in electrolytes to minimize adverse effects of solid electrolyte interphase (SEI) formation and safety limitations associated with this technology



The Economically Feasible Synthesis Of Porous Silicon For Lithium Ion Battery Anodes Via The Magnesiothermic Reduction Of Silica At Ultra Low Temperatures


The Economically Feasible Synthesis Of Porous Silicon For Lithium Ion Battery Anodes Via The Magnesiothermic Reduction Of Silica At Ultra Low Temperatures
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Author : Maximilian Yan
language : en
Publisher:
Release Date : 2022

The Economically Feasible Synthesis Of Porous Silicon For Lithium Ion Battery Anodes Via The Magnesiothermic Reduction Of Silica At Ultra Low Temperatures written by Maximilian Yan and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022 with categories.




Porous Silicon Based Anode Material Formed Using Metal Reduction


Porous Silicon Based Anode Material Formed Using Metal Reduction
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Author :
language : en
Publisher:
Release Date : 2015

Porous Silicon Based Anode Material Formed Using Metal Reduction written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2015 with categories.


A porous silicon based material comprising porous crystalline elemental silicon formed by reducing silicon dioxide with a reducing metal in a heating process followed by acid etching is used to construct negative electrode used in lithium ion batteries. Gradual temperature heating ramp(s) with optional temperature steps can be used to perform the heating process. The porous silicon formed has a high surface area from about 10 m.sup. 2/g to about 200 m.sup. 2/g and is substantially free of carbon. The negative electrode formed can have a discharge specific capacity of at least 1800 mAh/g at rate of C/3 discharged from 1.5V to 0.005V against lithium with in some embodiments loading levels ranging from about 1.4 mg/cm.sup. 2 to about 3.5 mg/cm.sup. 2. In some embodiments, the porous silicon can be coated with a carbon coating or blended with carbon nanofibers or other conductive carbon material.



Silicon Anodes For The Next Generation Ultrahigh Capacity Lithium Ion Batteries


Silicon Anodes For The Next Generation Ultrahigh Capacity Lithium Ion Batteries
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Author : Hatem Amli
language : en
Publisher:
Release Date : 2021

Silicon Anodes For The Next Generation Ultrahigh Capacity Lithium Ion Batteries written by Hatem Amli and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2021 with categories.




Electrochemical Synthesis Of Silicion Based Materials And Their Evaluation As Anodes For Lithium Ion Batteries Libs


Electrochemical Synthesis Of Silicion Based Materials And Their Evaluation As Anodes For Lithium Ion Batteries Libs
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Author : Adel Elsayed
language : en
Publisher:
Release Date : 2019

Electrochemical Synthesis Of Silicion Based Materials And Their Evaluation As Anodes For Lithium Ion Batteries Libs written by Adel Elsayed and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019 with categories.




Silicon Anode In Lithium Ion Batteries


Silicon Anode In Lithium Ion Batteries
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Author : Ian Paul Edward Roper
language : en
Publisher:
Release Date : 2019

Silicon Anode In Lithium Ion Batteries written by Ian Paul Edward Roper and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2019 with categories.