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Long Lived Nuclear Spin Order


Long Lived Nuclear Spin Order
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Long Lived Nuclear Spin Order


Long Lived Nuclear Spin Order
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Author : Giuseppe Pileio
language : en
Publisher: Royal Society of Chemistry
Release Date : 2020-04-07

Long Lived Nuclear Spin Order written by Giuseppe Pileio and has been published by Royal Society of Chemistry this book supported file pdf, txt, epub, kindle and other format this book has been release on 2020-04-07 with Science categories.


The idea that a long-lived form of spin order, namely singlet order, can be prepared from nuclear spin magnetisation first emerged in 2004. The unusual properties of singlet order–its long lifetime and the fact that it is NMR silent but interconvertible into other forms of NMR active order—make it a ‘smart tag’ that can be used to store information for a long time or through distant space points. It is not unexpected then, that since its first appearance, this idea has caught the attention of research groups interested in exploiting this form of order in different fields of research spanning from biology to materials science and from hyperpolarisation to quantum computing. This first book on the subject gives a thorough description of the various aspects that affect the development of the topic and details the interdisciplinary applications. The book starts with a section dedicated to the basic theories of long-lived spin order and then proceeds with a description of the state-of-the-art experimental techniques developed to manipulate singlet order. It then concludes by covering the generalization of the concept of singlet order by introducing and discussing other forms of long-lived spin order.



Generalized Methodology For Control Of Long Lived Nuclear Spin Order In Magnetic Resonance


Generalized Methodology For Control Of Long Lived Nuclear Spin Order In Magnetic Resonance
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Author : Mohamed Sabba
language : en
Publisher:
Release Date : 2023

Generalized Methodology For Control Of Long Lived Nuclear Spin Order In Magnetic Resonance written by Mohamed Sabba and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2023 with categories.




Nuclear Spin Relaxation In Liquids


Nuclear Spin Relaxation In Liquids
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Author : Jozef Kowalewski
language : en
Publisher: CRC Press
Release Date : 2017-12-14

Nuclear Spin Relaxation In Liquids written by Jozef Kowalewski and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-12-14 with Science categories.


Nuclear magnetic resonance (NMR) is widely used across many fields of science because of the rich data it produces, and some of the most valuable data come from studies of nuclear spin relaxation in solution. The first edition of this book, published more than a decade ago, provided an accessible and cohesive treatment of the field. The present second edition is a significant update, covering important new developments in recent years. Collecting relaxation theory, experimental techniques, and illustrative applications into a single volume, this book clarifies the nature of the phenomenon, shows how to study it and explains why such studies are worthwhile. Coverage ranges from basic to rigorous theory and from simple to sophisticated experimental methods. Topics include cross-relaxation, multispin phenomena, relaxation studies of molecular dynamics and structure and special topics such as relaxation in systems with quadrupolar nuclei, in paramagnetic systems and in long-living spin states. Avoiding overly demanding mathematics, the authors explain spin relaxation in a manner that anyone with a familiarity with NMR can follow. The focus is on illustrating and explaining the physical nature of relaxation phenomena. Nuclear Spin Relaxation in Liquids: Theory, Experiments and Applications, 2nd edition, provides useful supplementary reading for graduate students and is a valuable reference for NMR spectroscopists, whether in chemistry, physics or biochemistry.



Long Lived Nuclear Spin States Of Magnetically Equivalent Protons By Means Of Dissolution Dynamic Nuclear Polarization


Long Lived Nuclear Spin States Of Magnetically Equivalent Protons By Means Of Dissolution Dynamic Nuclear Polarization
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Author : Daniele Mammoli
language : en
Publisher:
Release Date : 2016

Long Lived Nuclear Spin States Of Magnetically Equivalent Protons By Means Of Dissolution Dynamic Nuclear Polarization written by Daniele Mammoli and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016 with categories.


Mots-clés de l'auteur: Nuclear Magnetic Resonance (NMR) ; Dynamic Nuclear Polarization (DNP) ; Dissolution DNP (D-DNP) ; Long-Lived States (LLS) ; para ; ortho ; singlet ; triplet ; Triplet-Singlet Imbalance (TSI) ; water ; spin isomers ; proton exchange ; NMR relaxation ; gas-phase NMR.



Nuclear Isomers


Nuclear Isomers
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Author : Ashok Kumar Jain
language : en
Publisher: Springer
Release Date : 2022-07-12

Nuclear Isomers written by Ashok Kumar Jain and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-07-12 with Science categories.


Nuclear isomers are the long-lived excited states of nuclei. Therefore, they constitute the meta-stable landscape of nuclei. The first isomer was probably identified as early as 1921. Since then, the number of isomers has been growing steadily picking up pace in recent times. Interest in nuclear isomers has grown in recent years for many reasons. The experimental capabilities to observe isomers have been expanding to cover a wider time scale. This has opened up new windows to observe and decipher the underlying nuclear structure and interactions. Further, the isomers are beginning to be seen as potential energy storage devices and nuclear clocks with a host of applications. Possible discovery of a gamma ray laser has also ignited many researches in this area. Isomers now cover the full nuclear landscape with structural peculiarities specific to each region of the nuclear chart. Exploring the nuclear isomers, therefore, provides a novel insight into the nuclear structure properties of that region. There could be many different reasons for the long lives of excited nuclear states, which lead to the classification of isomers. Isomers are broadly classified in to four classes: Spin isomers, shape isomers, fission isomers and K-isomers. Seniority isomers have also been identified which are often clubbed with the spin isomers. We discuss this classification and the underlying causes in detail. Many examples are considered to highlight the large variety of isomers. The range of half-lives covered by the isomers varies from billions of years to nano-seconds and even small. To understand this vast variation is a fascinating endeavor in itself. The angular momentum couplings, nuclear shapes, pairing etc. conspire together to give this vast range of half-lives. We go through these aspects in detail, highlighting the various selection rules at work. It is interesting that the nuclear shapes play an important role in many types of isomers. The spin isomers, which occur in spherical or, near-spherical nuclei, are generally confined to the magic numbers. Seniority isomers are largely found in semi-magic nuclei and should be explored in conjunction with the spin isomers. New developments in seniority and generalized seniority isomers are discussed in detail. As the nuclei deform; the nature of isomers changes. We take a close look into the decay properties of isomers in deformed nuclei, particularly the K isomers, the shape isomers and the fission isomers. While doing so, the theoretical and experimental developments of isomers are also addressed. A number of open questions are posed for possible new experiments and better understanding of the isomers.



Spin Dynamics


Spin Dynamics
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Author : Malcolm H. Levitt
language : en
Publisher: Wiley
Release Date : 2008-07-31

Spin Dynamics written by Malcolm H. Levitt and has been published by Wiley this book supported file pdf, txt, epub, kindle and other format this book has been release on 2008-07-31 with Science categories.


Spin Dynamics: Basics of Nuclear Magnetic Resonance, Second Edition is a comprehensive and modern introduction which focuses on those essential principles and concepts needed for a thorough understanding of the subject, rather than the practical aspects. The quantum theory of nuclear magnets is presented within a strong physical framework, supported by figures. The book assumes only a basic knowledge of complex numbers and matrices, and provides the reader with numerous worked examples and exercises to encourage understanding. With the explicit aim of carefully developing the subject from the beginning, the text starts with coverage of quarks and nucleons and progresses through to a detailed explanation of several important NMR experiments, including NMR imaging, COSY, NOESY and TROSY. Completely revised and updated, the Second Edition features new material on the properties and distributions of isotopes, chemical shift anisotropy and quadrupolar interactions, Pake patterns, spin echoes, slice selection in NMR imaging, and a complete new chapter on the NMR spectroscopy of quadrupolar nuclei. New appendices have been included on Euler angles, and coherence selection by field gradients. As in the first edition, all material is heavily supported by graphics, much of which is new to this edition. Written for undergraduates and postgraduate students taking a first course in NMR spectroscopy and for those needing an up-to-date account of the subject, this multi-disciplinary book will appeal to chemical, physical, material, life, medical, earth and environmental scientists. The detailed physical insights will also make the book of interest for experienced spectroscopists and NMR researchers. • An accessible and carefully written introduction, designed to help students to fully understand this complex and dynamic subject • Takes a multi-disciplinary approach, focusing on basic principles and concepts rather than the more practical aspects • Presents a strong pedagogical approach throughout, with emphasis placed on individual spins to aid understanding • Includes numerous worked examples, problems, further reading and additional notes Praise from the reviews of the First Edition: "This is an excellent book... that many teachers of NMR spectroscopy will cherish... It deserves to be a ‘classic’ among NMR spectroscopy texts." NMR IN BIOMEDICINE "I strongly recommend this book to everyone…it is probably the best modern comprehensive description of the subject." ANGEWANDTE CHEMIE, INTERNATIONAL EDITION



The Nuclear Many Body Problem


The Nuclear Many Body Problem
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Author : Peter Ring
language : en
Publisher: Springer Science & Business Media
Release Date : 2004-03-25

The Nuclear Many Body Problem written by Peter Ring and has been published by Springer Science & Business Media this book supported file pdf, txt, epub, kindle and other format this book has been release on 2004-03-25 with Health & Fitness categories.


Study Edition



Neutron Scattering From Magnetic Materials


Neutron Scattering From Magnetic Materials
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Author : Tapan Chatterji
language : en
Publisher: Elsevier
Release Date : 2005-11-29

Neutron Scattering From Magnetic Materials written by Tapan Chatterji and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2005-11-29 with Science categories.


Neutron Scattering from Magnetic Materials is a comprehensive account of the present state of the art in the use of the neutron scattering for the study of magnetic materials. The chapters have been written by well-known researchers who are at the forefront of this field and have contributed directly to the development of the techniques described. Neutron scattering probes magnetic phenomena directly. The generalized magnetic susceptibility, which can be expressed as a function of wave vector and energy, contains all the information there is to know about the statics and dynamics of a magnetic system and this quantity is directly related to the neutron scattering cross section. Polarized neutron scattering techniques raise the sophistication of measurements to even greater levels and gives additional information in many cases. The present book is largely devoted to the application of polarized neutron scattering to the study of magnetic materials. It will be of particular interest to graduate students and researchers who plan to investigate magnetic materials using neutron scattering. · Written by a group of scientist who have contributed directly in developing the techniques described.· A complete treatment of the polarized neutron scattering not available in literature.· Gives practical hits to solve magnetic structure and determine exchange interactions in magnetic solids.· Application of neutron scattering to the study of the novel electronic materials.



Molecular Symmetry And Spectroscopy


Molecular Symmetry And Spectroscopy
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Author : Philip Bunker
language : en
Publisher: Elsevier
Release Date : 2012-12-02

Molecular Symmetry And Spectroscopy written by Philip Bunker and has been published by Elsevier this book supported file pdf, txt, epub, kindle and other format this book has been release on 2012-12-02 with Science categories.


Molecular Symmetry and Spectroscopy deals with the use of group theory in quantum mechanics in relation to problems in molecular spectroscopy. It discusses the use of the molecular symmetry group, whose elements consist of permutations of identical nuclei with or without inversion. After reviewing the permutation groups, inversion operation, point groups, and representation of groups, the book describes the use of representations for labeling molecular energy. The text explains an approximate time independent Schrödinger equation for a molecule, as well as the effect of a nuclear permutation or the inversion of E* on such equation. The book also examines the expression for the complete molecular Hamiltonian and the several groups of operations commuting with the Hamiltonian. The energy levels of the Hamiltonian can then be symmetrically labeled by the investigator using the irreducible representations of these groups. The text explains the two techniques to change coordinates in a Schrödinger equation, namely, (1) by using a diatomic molecule in the rovibronic Schrödinger equation, and (2) by a rigid nonlinear polyatomic molecule. The book also explains that using true symmetry, basis symmetry, near symmetry, and near quantum numbers, the investigator can label molecular energy levels. The text can benefit students of molecular spectroscopy, academicians, and investigators of molecular chemistry or quantum mechanics.



Experimental Approaches Of Nmr Spectroscopy


Experimental Approaches Of Nmr Spectroscopy
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Author : The Nuclear Magnetic Resonance Society of Japan
language : en
Publisher: Springer
Release Date : 2017-11-23

Experimental Approaches Of Nmr Spectroscopy written by The Nuclear Magnetic Resonance Society of Japan and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2017-11-23 with Science categories.


This book describes the advanced developments in methodology and applications of NMR spectroscopy to life science and materials science. Experts who are leaders in the development of new methods and applications of life and material sciences have contributed an exciting range of topics that cover recent advances in structural determination of biological and material molecules, dynamic aspects of biological and material molecules, and development of novel NMR techniques, including resolution and sensitivity enhancement. First, this book particularly emphasizes the experimental details for new researchers to use NMR spectroscopy and pick up the potentials of NMR spectroscopy. Second, the book is designed for those who are involved in either developing the technique or expanding the NMR application fields by applying them to specific samples. Third, the Nuclear Magnetic Resonance Society of Japan has organized this book not only for NMR members of Japan but also for readers worldwide who are interested in using NMR spectroscopy extensively.